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Explore the diffusion bonding of high-temperature alloys at 900-1250°C under 3-10 MPa pressure, including directionally solidified nickel superalloys and single-crystal repairs. Learn about bonding techniques, such as Transient Liquid-Phase (TLP) and Inertia Welding, for joining dissimilar metals. Discover the impact of alloy compositions on microstructures and mechanical properties.
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Microstructure & Performance of Joints in High Temperature Alloys
Microstructure & Performance of Joints in Superalloys www.msm.cam.ac.uk/phase-trans
Diffusion Bonding Pure aluminium Minimal gallium Shirzadi, Saindrenan & Wallach, 2003
Diffusion Bonding of Gallium -Treated Superalloy Surfaces 3-10 MPa pressure 900-1250 oC 1 h 10-7 bar 1 mg cm-2 gallium
100 µm Co-23Cr-10 Ni-7W 0.2Ti-0.6C-0.5Zr wt% Shirzadi & Wallach
50 µm Ni-15Cr-10Co-9.5Mo 4.2Al-3.6Ti-0.006B wt% Shirzadi & Wallach
Directionally solidified nickel superalloy Single-crystal nickel superalloy Shirzadi & Wallach
Bonding completed in 1 hour Shirzadi & Wallach
Single-Crystal Repair Melt shallow layer of SX substrate using laser. Feed melt pool with alloy powder. Epitaxial columnar growth. Repeat to build thicker layers. Kurz
Single-Crystal Surface Engineering Lowering Cr improves properties. Polycrystalline coatings such as NiCrAlY. Ni is anisotropic.
Sieborger et al. E100 = 125 GPa E111 = 310 GPa
Dendrites grow along <100>. Variant selected is closest to heat flux. Kurz
high aluminium MCrAlY primary b low aluminium MCrAlY primary g
MCrAlY CMSX-4
Al-Li TLP TG-TLP Shirzadi & Wallach, 1999
TG-TLP Alloy 6082 Large gradient Small gradient Shirzadi & Wallach, 1999
Inertia Welding Process No liquid phase Can join dissimilar metals Powder metallurgical alloy RR1000 Residual stress Baxter, Preuss, Withers
Rolls-Royce Nottingham
Mechanically Alloyed Oxide Dispersion Strengthened Metals
screw shoulder termination
2D Mixing Animation Colegrove & Shercliff, 2002
Microstructure & Performance of Joints in Superalloys www.msm.cam.ac.uk/phase-trans