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Physical and Chemical Changes. Definitions. Physical changes: Alters neither the nature nor the characteristic properties of matter. The atoms and molecules of the substance do not change. Physical change.
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Definitions • Physical changes: • Alters neither the nature nor the characteristic properties of matter. The atoms and molecules of the substance do not change.
Physical change • When salts dissolve in water. This is a physical change because this reversible. We can evaporate the water to collect the salt. • When a liquid is boiled or frozen, this is a physical change because it is reversible. We only change the state of the solution (gas, liquid, solid). • Can change the appearance but not the identity of matter.
Definitions • Chemical changes: • Alters the nature and characteristic properties of matter. The bonds between atoms are rearranged, and new molecules are formed. Not reversible.
Chemical changes • Tend to be • exothermic: release heat/energy when they occur (ex.: combustion) • endothermic: absorb heat/energy to occur (ex.: photosynthesis)
Remember Dalton’s atomic theory: Rule #5 Atoms are indivisible in chemical processes. That is, atoms are not created or destroyed in chemical reactions. A chemical reaction changes the way the atoms are grouped together • During a chemical reaction, atoms are neither created nor destroyed. This means the mass of the entire reaction does not change. Everything needs to be accounted for. • http://www.youtube.com/watch?v=J5hM1DxaPLw
Types of chemical changes • Synthesis and decomposition • Precipitation • Acid-base neutralization • Oxidation • Combustion • Cellular respiration • Photosynthesis
1. Synthesis and decomposition • Synthesis: where two or more reactants combine to form a new product. N2 + 2O2 2NO2 • Decomposition: where a compound separates into two or more compounds or elements. • 2H2O 2H2 + O2
What is this type of chemical change? C2H6 + O2 CO2 + H2O
2. Precipitation • When two solutions are combined, an insoluble (or slightly insoluble) substance sometimes forms. • NaCl(aq) + AgNO3(aq)AgCl(s) + NaNO3(aq) • http://www.youtube.com/watch?v=DITY2rXYU-I&feature=related
3. Acid-Base Neutralization • A reaction in which an acid and base react to form a salt and water. • Acid(aq) + Base(aq) salt(aq) + water(l)
Examples • HF(aq) + KOH(aq) KF(aq) + H2O(l) • H2SO4(aq) + Mg(OH)2(aq) MgSO4(aq) + 2H2O(l) • 2HBr(aq) + Ca(OH)2(aq) CaBr2(aq) + 2H2O(l)
4. Oxidation • A chemical change involving oxygen or a substance with properties similar to those of oxygen. These reactions occur faster in light. Ex.: light causes the oxidation of oil, altering their taste. So we can’t eat them.
Corrosion is an example of oxidation. Iron reacts with oxygen to produce rust.
5. Combustion • This is a form of oxidation that releases a lot of energy. • Fossil fuel + oxygen carbon dioxide + water + energy • Excessive burning of fossil fuels releases a lot of carbon dioxide (CO2), which is primarily responsible for the greenhouse effect. • Some fossil fuels contain sulfur. When we burn those we release sulfur dioxide (SO2) which is partially responsible for acid rain.
There are three conditions (triangle) for a combustion reaction to take place: • Fuel • Oxidizing agent (oxygen) • Ignition temperature • http://www.youtube.com/watch?v=GzQtEJboYaw
Types of combustion • Rapid combustion: releases energy in a short period of time. • Ex.: log fire, burning candle, explosion of gasoline. • Spontaneous combustion: occurs with low ignition temperature. • Ex.: forest fires, very hot and dry. • Slow combustion: occurs over a very long time. Small amounts of energy are emitted over longer periods of time. • Ex.: fermentation, cellular respiration, metal corrosion…
6. Cellular respiration • Cellular respiration is an example of slow combustion. • Cellular respiration is a chemical change in which glucose and oxygen are used to generate energy. • This keeps our body temperature at around 37°C.
7. Photosynthesis • It is the opposite reaction to cellular respiration. • Plants consume water and carbon dioxide and energy (light) to form sugar (glucose) and oxygen. • This maintains the level of oxygen in the atmosphere. Why bother replanting plants? Any ideas?
Easy rules… • A number of signs point to the occurrence of a chemical change: • Release of a gas (could also affect the smell) • Emission or absorption of heat • Emission of light • Change in colour • Formation of a precipitate (a solid in a solution)
Sodium http://www.youtube.com/watch?v=Mx5JJWI2aaw&feature=player_embedded • Oscilating reaction: http://www.youtube.com/watch?v=Ch93AKJm9os&feature=player_embedded