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Physical Principles of Respiratory Care. Egan Chapter 6. Physical Principles of Respiratory Care. States of Matter Change of State Gas Behavior Under Changing Conditions Fluid Dynamics. II. Change of State. Liquid-Solid Phase Changes Melting Freezing Properties of Liquids
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Physical Principles of Respiratory Care Egan Chapter 6
Physical Principles of Respiratory Care • States of Matter • Change of State • Gas Behavior Under Changing Conditions • Fluid Dynamics
II. Change of State • Liquid-Solid Phase Changes • Melting • Freezing • Properties of Liquids • Pressure in Liquids • Buoyancy (Archimedes’ Principle) • Viscosity • Cohesion and Adhesion • Surface Tension • Capillary Action • Liquid-Vapor Phase Changes • Boiling • Evaporation, Vapor Pressure, and Humidity • Properties of Gases • Kinetic Activity of Gases • Molar Volume and Gas Density • Gaseous Diffusion • Gas Pressure • Partial Pressure (Dalton’s Law) • Solubility of Gases in Liquids (Henry’s Law)
II. Change of State • Liquid-Solid Phase Changes • Melting • Freezing http://www.youtube.com/watch?v=j2KZmRIKea8 Start at 3:15
A. Liquid-Solid Phase Changes • Melting ?When a solid is heated, what happens to its kinetic energy? • What happens to its intermolecular forces?
A. Liquid-Solid Phase Changes 2. Freezing ? When a liquid is cooled, what happens to its kinetic energy? • What happens to its intermolecular forces?
A. Liquid-Solid Phase Changes Intermolecular forces
A. Liquid-Solid Phase Changes • Melting and Boiling • Melting Point: • The temperature at which a solid converts to a liquid • Boiling Point • The temperature at which a liquid converts to the gaseous state
A. Liquid-Solid Phase Changes • Melting and Boiling • Latent Heat: • The amount of heat needed for a substance to change its state of matter • Latent heat of fusion: • The amount of heat needed to change a solid to a liquid • Latent heat of vaporization • The amount of heat needed to change a liquid to a gas
A. Liquid-Solid Phase Changes Latent heat of vaporization Steam Latent heat of fusion Water Ice
II. Change of State • Properties of Liquids • Pressure in Liquids • Buoyancy (Archimedes’ Principle) • Viscosity • Cohesion and Adhesion • Surface Tension • Capillary Action
B. Properties of Liquids • Liquid Oxygen • http://www.youtube.com/watch?v=ndtmfDoI8PM
B. Properties of Liquids • Liquid molecules also possess attractive forces • but these forces are much weaker in liquids than in solids • Liquid molecules have greater freedom of movement and possess more KE than solids • This is why liquids take the shape of their container • And are capable of flow • Liquids cannot be easily compressed
1. Pressure in Liquids Is the same at any specific depth, regardless of the container’s shape Is exerted equally in all directions B. Properties of Liquids
B. Properties of Liquids 1. Pressure in Liquids • Pascal’s Principle: • A confined liquid transmits pressure equally in all directions
B. Properties of Liquids 1. Pressure in Liquids • Pascal’s Principle • Downward
B. Properties of Liquids 1. Pressure in Liquids • Liquids are capable of flow • Pascal’s Principle • Sideways
B. Properties of Liquids 1. Pressure in Liquids • Pascal’s Principle • Upward http://www.youtube.com/watch?v=iD55ynlUH8g http://www.youtube.com/watch?v=UpwLwP0pmwk
B. Properties of Liquids • Pressure in Liquids • Clinical Application • Heart Failure
B. Properties of Liquids • Pressure in Liquids • Clinical Application • Using an air or water mattress to prevent the development of bed soars
B. Pressure in Liquids 2. Buoyancy (Archimedes’ Principle) • Buoyancy occurs because the pressure below a submerged object always exceeds the pressure above it
B. Pressure in Liquids 2. Buoyancy (Archimedes’ Principle) • According to Archimedes • This buoyant force must equal the weight of the fluid displaced buy the object http://www.youtube.com/watch?v=mhJ5Ybt7L2k http://www.youtube.com/watch?v=vJ36urazDu4&list=PLB76160897CFFC3F4&index=8&feature=plpp_video
B. Pressure in Liquids 2. Buoyancy (Archimedes’ Principle) • Gases also exert buoyant force • Buoyancy helps keep solid particles suspended in gases • These suspensions, called aerosols, play an important role in respiratory care.
B. Properties of Liquids 3. Viscosity • Internal force that opposes flow of a fluid, either liquids or gases • Fluid’s viscosity is directly proportional to cohesive forces between its molecules • The stronger the cohesive forces, the greater the fluid viscosity • Heart must use more energy when blood viscosity increases, as occurs in polycythemia
B. Properties of Liquids 3. Viscosity • Clinical Application • The greater the viscosity of a fluid, the more energy is needed to make it flow • The heart must perform more work when blood viscosity increases • Polycythemia: an increase in red blood cells • Polycythemia is common in patients with chronic bronchitis
B. Properties of Liquids 4. Cohesion and adhesion • The attractive force between like molecules is cohesion. • The attractive force between unlike molecules is adhesion.
Cohesion and Adhesion Water Concave meniscus • Adhesion > Cohesion
Cohesion and Adhesion Mercury Convex meniscus • Cohesion > Adhesion
B. Properties of Liquids 5. Surface Tension • a force exerted by like molecules at a liquid’s surface • The cohesive forces between liquid molecules are responsible for this phenomenon
B. Properties of Liquids 5. Surface Tension
B. Properties of Liquids 5. Surface Tension
B. Properties of Liquids 5. Surface Tension • Explains why liquid droplets and bubbles retain a spherical shape
B. Properties of Liquids 5. Surface Tension • In bubbles
B. Properties of Liquids 5. Surface Tension • Laplace’s Law • The pressure within a sphere • Varies directly with the surface tension of the liquid • As the surface tension of the liquid increases, the internal pressure increases • Varies inversely with its radius • As the droplet becomes smaller and the radius decreases, the internal pressure increases • P = 4ST r
B. Properties of Liquids 5. Surface Tension • Laplace’s Law http://www.youtube.com/watch?v=RAmx4_G9XsQ
B. Properties of Liquids 5. Surface Tension in alveoli
Surface Tension • Surface tension in alveoli • Alveoli with increased surface tension • Have a greater tendency to collapse • Require greater distending pressure to maintain their volume
B. Properties of Liquids 5. Surface Tension in alveoli • Clinical Application: • Atelectasis
B. Properties of Liquids 5. Surface Tension • Normal CXR after the application of Continuous Positive Airway Pressure (CPAP)
B. Properties of Liquids 5. Surface Tension • The lung reduces surface tension of alveoli by the production of a complex surface tension reducing chemical mixture called SURFACTANT http://www.youtube.com/watch?v=Gpcbetob4p4
B. Properties of Liquids 5. Surface Tension • Clinical Application • The first breath of life
B. Properties of Liquids 5. Surface Tension • Artificial surfactant administration in Infant Respiratory Distress Syndrome
B. Properties of Liquids 5. Surface Tension • Clinical Application • Liquid Ventilation http://www.youtube.com/watch?v=2OxstD2jN08
B. Properties of Liquids 6. Capillary Action • A phenomenon in which a liquid in a small tube moves upward, against gravity
B. Properties of Liquids 6. Capillary Action http://www.youtube.com/watch?v=mdkeZbm0cCI
B. Properties of Liquids 6. Capillary Action • Clinical Examples • Capillary blood stick http://www.youtube.com/watch?v=q5J1cCyrASs
B. Properties of Liquids 6. Capillary Action • Clinical Examples • Absorbent wick humidifiers
C. Liquid-Vapor Phase Changes • Boiling • Evaporation, Vapor Pressure, and Humidity
C. Liquid-Vapor Phase Changes • Liquid to vapor phase changes (vaporization) • 2 types of vaporization • Boilingheating liquid to temperature at which its vapor pressure exceeds atmospheric pressure • Boiling point of most liquefied gases is very low • Liquid oxygen boils at -183°C • Evaporationwhen liquid changes into gas at temperature below its boiling point • Evaporation requires heat. The heat energy required for evaporation comes from the air next to the water surface. As the surrounding air loses heat energy, it cools. This is the principle of evaporative cooling, which was previously described. • Water enters atmosphere via evaporation when at temperature lower than its boiling point (water vapor) • Molecular water exerts pressure called water vapor pressure • Temperature influences evaporation most • The warmer the air, the more vapor it can hold
C. Liquid-Vapor Phase Changes 2. Evaporation, Vapor Pressure and Humidity • Evaporation: the change in state of substance from a liquid to a gaseous state below its boiling point. • Molecular water exerts a pressure called the water vapor pressure