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Indicators. Indicators. Weak acids, HIn, that have different colours in the undissociated form, HIn and the disscociated form In - . HIn (aq) H + (aq) + In - (aq). Methyl Orange. HIn (aq) H + (aq) + In - (aq). Add H + (aq) equilibrium to left red.
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Indicators • Weak acids, HIn, that have different colours in the undissociated form, HIn and the disscociated form In-. • HIn(aq) H+(aq) + In -(aq)
Methyl Orange HIn(aq)H+(aq) +In -(aq) Add H+(aq) equilibrium to left red Add OH-(aq) equilibrium to right yellow
Indicators • Different indicators change colour at different pH values • Investigate the colours of different indicators in different solutions
Choosing Indicators for Titrations • For an indicator to work the colour change must occur within the steep part of the pH curve.
Strong Acid / Strong Base Any indicator in pH range 3 – 11 suitable phenolphthalein Methyl orange
Weak Acid / Strong Base phenolphthalein Methyl orange Any indicator in pH range 7 – 11 suitable phenolphthalein
Strong Acid / Weak Base phenolphthalein Any indicator in pH range 3 – 7 suitable Methyl orange Methyl orange
Weak Acid / Weak Base phenolphthalein No rapid pH change at equivalence – no suitable indicators Methyl orange