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MS FARZANA MEHBOOB D.A.NEELUM HIGH SCHOOL. Instructional Lesson on ELECTROCHEMISTRY. Overview. Electrochemistry introduction Cell &Batteries. Electrolysis & its Application. ELECTROCHEMISTRY. FARADAY. DANIELL. F O U N D E R S. From Wikipedia. is a. Branch of Chemistry.
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MS FARZANA MEHBOOB D.A.NEELUM HIGH SCHOOL Instructional Lesson on ELECTROCHEMISTRY
Overview • Electrochemistry • introduction • Cell &Batteries Electrolysis & its Application
ELECTROCHEMISTRY FARADAY DANIELL F O U N D E R S From Wikipedia
is a Branch of Chemistry involves also called Redox reactions generate cause OR
CONCEPT MAP REDOX REACTIONS
A redox reaction can be divided into two Half Reactions: • an oxidation reaction • a reduction reaction. • The loss of electrons is called oxidation, • The gain of electrons is reduction. REDUCING OXIDIZING AGENT AGENT
This can be easily remembered through: OIL, Oxidation Is Loss, RIG, Reduction Is Gain “ An OIL RIG"
Oxidation-Reduction Reactions OXIDATION = loss of electrons Examples: Examples: Na Na+ + e- Al Al3+ + 3e- S2- S + 2e- Na Na+ + e- Al Al3+ + 3e- S2- S + 2e- OXIDATION = increasing the oxidation number (more positive) Example: NO NO2 Oxid. Nos: +2 -2 +4 -2 change = +2 +2 to +4 : N is oxidized
OXIDATION-REDUCTION REACTIONS Direct Redox Reaction Oxidizing and reducing agents in direct contact. Cu(s) + 2 Ag+(aq) ---> Cu2+(aq) + 2 Ag(s)
OXIDATION-REDUCTION REACTIONS Indirect Redox Reaction A battery Oxidizing and reducing agents are not in direct contact
Why do reduction-oxidation reactions occur? It is all about energy. Reduction and = an analogous flow oxidation of electrons. The energy of a chemical system drives the charges to move. E
CONCEPT MAP OF GALVANIC CELL used to convert into are in simplest form in which has also called
Parts of a Galvanic cell • Two electrodes of different metals • Electrolyte • An electrical wire • A salt bridge
Cathode compartment • The compartment in which reduction occurs. • The reaction at the cathode: Cu2+(aq) + 2e- ---> Cu (s) Cathode electrode Cu Electrolyte (CuSO4)
Anode compartment anode electrode Zn Electrolyte (ZnSO4) The compartment in which oxidation occurs The reaction at the anode : • Zn (s) --->Zn2+ (aq) + 2e-
Story ofAn OxRed Cat ANodeOXidation AND NEGATIVE DANIEL ANODE REDuction CAThode
GENERAL TERMS USED IN ELECTROLYSIS Electrolytic cell It has three component parts: • An electrolyte • Two electrodes (a cathode and an anode). • A battery
Industrial Application of electrolysis
Gold plating external power source external power source Au Au Au+(aq) Au+(aq) cathode: Au+(aq) +e-→Au anode: Au→Au+(aq) +e-
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