Composite Materials

1. Composite Materials

2. Resistance Welding • Learning Activities • View Slides; • Read Notes, • Listen to lecture • Do on-line workbook • Lesson Objectives • When you finish this lesson you will understand: Keywords

3. Matrix Materials • Magnesium • Lowest density (37% lighter than aluminum) • Aerospace applications • Creeps at low temp • Relatively low strength • Prone to variety of corrosion problems • Aluminum • Easy to process, inexpensive • Density only 35% of Steel • Can be alloyed to fairly high strengths • 57% stiffer than Magnesium • Excellent corrosion resistance • Most widely used material

4. Matrix Materials • Titanium • Twice as strong as aerospace aluminum • 65% heavier than aluminum, but 65% stiffer • Temp & corrosion resistant = use in demanding environments • Copper, Iron, Nickel, Tungsten • Special use alloys • Electronic Circuits • Metal forming dies • Jet engines • Military applications

5. Reinforcements • Other • Graphite (C) • Titanium Diboride (TiB2) • Ceramics • Silicon Carbide (SiC) • Aluminum Oxide (Al2O3) • Titanium Carbide (TiC) • Boron Carbide (B4C) • Metal Filaments • Boron • Steel • Tungsten • Choice of matrix and reinforcement depends on: • Desired properties of composite • Compatibility between matrix and reinforcement • MMC Processing route

6. Rule of Mixtures

7. Designation for MMC Matrix + Reinforcement / Volume % Form • Matrix = metal or alloy designation of matrix • Reinforcement = chemical formula of reinforcement • Volume % = Volume percent without the % sign • Form = Form of the reinforcement • f, fiber or filament • c, chopped fiber • w, whisker • p, particulate Example: 6061 + SiC/20w

8. Welding Handbook, AWS

9. Particulate Composite Short-Fiber Composite Long-Fiber Composite Laminated Composite Manufacturing Processes Welding Handbook, AWS

10. Processing Methods Solid State Semi-solid Liquid

11. Solid State Processing • Bonding of continuous fibers between metal foils to make panels • Aerospace Applications • Ti/Sic; Al/B Laminated Composite • Powder Metallurgy • Mix particles of matrix with reinforcement • Vacuum hot press (near solidus) • Extrude or roll • Al/B4C; Al/SiC

12. Semi-Solid Processing Spray Deposition Chilled Plate ……….. MMC Build Up Flame Spray Matrix Flame Spray Reinforcement • Rheocasting • Mix reinforcement into matrix held between solidus and liquidus x

13. Liquid Processing • Infiltration • Interfacial reactions can be a problem

14. Applications - From Ukraine Krivov, Optimization of design-production…, Welding in the World, Nov-Dec 1994

15. Applications Krivov, Optimization of design-production…, Welding in the World, Nov-Dec 1994

16. Krivov, Optimization of design-production…, Welding in the World, Nov-Dec 1994

17. Welding Handbook, AWS

18. Detrimental Weld Pool Chemical Reactions [l] indicates liquid phase [s] indicates solid phase [All] indicates in solution with liquid aluminum

19. Time-Temp Effect of Chem Reaction Arc Welding Resistance Welding Welding Handbook, AWS

20. Capacitor Discharge • Stud Welding • Solid State • Fusion Weld • Brazing

21. Capacitor Discharge Stud Welding • MMC Materials Welded • 6061, 2024, 6061/SiC/40p, 6061/SiC/48f, 6061/B4C/30p, AZ61/B4C/40p • Studs = 0.25 in; Sheet=0.13 in • Time = 0.4 ms • Solidification rate = 106 C/s

22. Stud Welding Welding Handbook, AWS

23. Welding Handbook, AWS

24. Welding Handbook, AWS

25. Capacitor Discharge - Solid State Welding • Ti-6Al-4V/SiC Sheets • Ti-6Al-4V/SCS-6 SCS-6 is a complex fiber with SiC vapor deposited onto a graphite carbon core Diffusion (solid state) Bond No Melting Failure Occurred Upon Loading Remote from Weld Interface Baeslack & Froes, Joining Similar & Dissimilar……, JOM March 1995

26. Increase in Welding Current (Voltage) Causes Change From Solid State to Fusion Weld Cox et al, Capacitor Discharge RSW of SiC Fiber… Welding Journal, Oct 1993

27. SCS-6 Fiber Capacitor Discharge Solid State Weld No liquid - Weld Strength 80% of Monolithic Cox et al, Capacitor Discharge RSW of SiC Fiber… Welding Journal, Oct 1993

28. Solid State Weld with no Fiber degradation Cox et al, Capacitor Discharge RSW of SiC Fiber… Welding Journal, Oct 1993

29. Capacitor Discharge - Fusion Welding

30. Partial Melting Fusion Weld Cox et al, Capacitor Discharge RSW of SiC Fiber… Welding Journal, Oct 1993

31. Solidified Liquid around fiber, Property degradation Cox et al, Capacitor Discharge RSW of SiC Fiber… Welding Journal, Oct 1993

32. Spot Brazing Continuous C Fiber MMC Al-7Zn/C BAlSi-4 Brazing Foil Low force = expulsion > 400 lb = fiber packing at weld center (see next slide)

33. Brazing Welding Handbook, AWS

34. Spot Brazing Continuous SiC Fiber MMC Ti-22Al-23Nb/SiC Ti-Cu-Ni Braze Foil Baeslack & Froes, Joining Similar & Dissimilar……, JOM March 1995

35. Baeslack & Froes, Joining Similar & Dissimilar……, JOM March 1995

36. Time-Temp Effect of Chem Reaction Arc Welding Resistance Welding Welding Handbook, AWS

37. Resistance Spot Welding • Solid State • With Melting/Solidification

38. Spot Welding Welding Handbook, AWS

39. Adjusting Welding Force Welding Time To Avoid Fiber Crushing in Al/B MMC (Continuous Fiber) Welding Handbook, AWS

40. Aluminum/Boron Continuous Fiber Hersh, Resistance Spot Weld MMC, Welding Journal, June 1970

41. Aluminum/Boron Continuous Fiber Hersh, Resistance Spot Weld MMC, Welding Journal, June 1970

42. Aluminum/Boron Continuous Fiber Hersh, Resistance Spot Weld MMC, Welding Journal, June 1970

43. Aluminum/Boron Continuous Fiber Hersh, Resistance Spot Weld MMC, Welding Journal, June 1970

44. Aluminum/Boron Continuous Fiber Hersh, Resistance Spot Weld MMC, Welding Journal, June 1970

45. Spot Welding Discontinuous Fibers Segregation of reinforcement (see next slide)

46. Welding Handbook, AWS