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Chapter 22 Problem Set 5. 1. Incorrect name and structure. CH 3 CHCH 3 │ CH 3 ▬ CH ▬ CH ▬ CH ▬ CH 3 │ │ CH 3 CHCH 3 CH 2 CH 3. 4-ethyl-2,3-diisopropylpentane. 1. Correct name and structure. CH 3 CHCH 3 │ CH 3 ▬ CH ▬ CH ▬ CH ▬ CH 3 │ │ CH 3 CHCH 3 CH 2 CH 3.
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1. Incorrect name and structure CH3CHCH3│CH3 ▬CH▬CH▬CH▬CH3││CH3CHCH3CH2CH3 4-ethyl-2,3-diisopropylpentane
1. Correct name and structure CH3CHCH3│CH3 ▬CH▬CH▬CH▬CH3││CH3CHCH3 CH2CH3 2,3,5-trimethyl-4-isopropylheptane
2. a. 2,2,4-trimethylhexaneb. 5-methylnonanec. 2,2,4,4-tetramethylpentaned. 3-ethyl-3-methyloctane
3. a. 1-isopropylcyclobutaneb. 1-tertbutyl-3-methylcyclopentanec. 1,3-dimethyl-2-propylcyclohexane
4. a. 1-buteneb. 4-methyl-2-hexenec. 2,5-dimethyl-3-heptene
5. a. 2,3-dimethyl-2-buteneb. 4-methyl-2-hexynec. 2,3-dimethyl-1-pentene
6. a. CH3CH2CH═CHCH2CH3 b. CH3CH═CHCH═CHCH2CH3 CH3CHCH═CHCH2CH2CH2CH3 │ CH3 c.
7. a. CH≡C▬CH2 ▬CH▬CH3│CH3 CH3│CH2═C ▬ C ▬CH2▬CH2▬CH3││CH3CH3 b.
7. c. CH2CH3│CH3CH2CHCH═CHCH2CH2CH2CH2CH3
8. a. CH2CH3 ⁄ CH3│
8. b. CH3│CH3▬C ▬ CH3│ │CH3▬C ▬ CH3│ CH3
8. c. CH2CH3│ \CH2CH3
8. d. CH2CH═CHCH3│
9. isopropylbenzene
10. a. 1,3-dichlorobutaneb. 1,1,1-trichlorobutanec. 2,3-dichloro-2,4-dimethylhexaned. 1,2-difluoroethane
11. a. 3-chloro-1-buteneb. 1-ethyl-3-methylcyclopentenec. 3-chloro-4-propylcyclopentened. 1,2,4-trimethylcyclohexane
11. e. 1-bromo-2-methylbenzeneor2-bromo-1-methylbenzeneorortho-bromotolueneoro-bromotoluene
11. f. 1-bromo-2-methylcyclohexane or2-bromo-1-methylcyclohexaneg. 4-bromo-3-methylcyclohexene