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Learn about molecular shapes using the VSEPR model and bonding orbitals. Understand how to draw Lewis dot diagrams, determine electron domains, and predict molecular geometries. Explore how lone pairs and double bonds affect bond angles. Discover the role of hybridized bonding orbitals in forming σ and π bonds.
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Molecular shapes Chapter 9
VSEPR model • Bonding pair = electrons in a bond = electron domain (~orbital/orbitals) • Non-bonding pair = electron domain (~orbital)
Molecular geometry • Draw Lewis dot diagram • Determine number of electron domains domain geometry • Non-bonding electron pairs must have maximum separation • Determine molecular geometry
Bond angles • Lone pairs and double bonds take up more space • push other bonds closer together • Bond angles become smaller • e.x. H2O bond angle is about 104° • (instead of 109.5°)