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RMgX and Rli Bond Type

RMgX and Rli Bond Type. Metal-Carbon Bond. Hydride Reagents. Bimolecular Elimination (E2) Steps. Nucleophilic Addition. Nucleophile Elimination Steps. Importance of Nucleophilic Addition and Nucleophile Elimination.

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RMgX and Rli Bond Type

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  1. RMgX and Rli Bond Type

  2. Metal-Carbon Bond

  3. Hydride Reagents

  4. Bimolecular Elimination (E2) Steps

  5. Nucleophilic Addition

  6. Nucleophile Elimination Steps

  7. Importance of Nucleophilic Addition and Nucleophile Elimination • They can cause the number of bonds between two atoms of significantly different polarity to change, thus leading to reduction and oxidation reactions. Chapter 17 • They allow two relatively large organic species to be joined to make one even larger organic species. Chapters 18 & 21 • When nucleophilic addition and nucleophile elimination steps occur sequentially, substitution can take place at a polar π bond. Chapter 20 and 21

  8. Hyperconjugation secondary can do 2x, tertiary can do 3x

  9. Keto–Enol Tautomerization

  10. Relative Percentages of Ketoand Enol Forms

  11. Keto–Enol Tautomerizationcontinued…

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