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The History of the Atom. Part 1 – The concept of the Atom. A long time ago, in a galaxy country far, far away. There were two philosophers. One was Democritus. Lived in Ancient Greece on the island of Sicily First to use the term atom ( atomos meaning indivisible)
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The History of the Atom Part 1 – The concept of the Atom
A long time ago, in a galaxy country far, far away There were two philosophers
One was Democritus • Lived in Ancient Greece on the island of Sicily • First to use the term atom (atomos meaning indivisible) • Described the atom by mathematics of the day (His peer was Pythagoras) • Atom was described as the smallest part of a material • There were rock atoms, hair atoms, etc.
Democritus’s atom would have looked like this: • Solid and Indestructible • No electrons • No nucleus • No protons • No neutrons • No Experiments to support his ideas
The other was Aristotle • He lived in the heart of Greece (Athens) • Defined matter as composed of hot, cold, wet and dry • These properties related to fire, air, water, and earth • Everything differed by the percentages of each that composed the object
And the winner was: • Aristotle • And set chemistry back about 2000 years • Chemistry didn’t make a come back until the Renaissance
Antoine Lavoisier • Frenchman in the late 1700s • Was working with gases • He discovered that the amount of mass that one started with was equal to the amount of mass that one ended with – Law of conservation of mass. • Also discovered that oxygen caused things to burn • Some call him the Father of Chemistry
Joseph Proust • Another Frenchman a few years after Lavoisier • Proposed Law of Definite Proportions • Roughly stated: a chemical could have only one ratio of atoms within it. • In other words, a compound will always have the same elements in the same ratio • Water has to be H2O and not HO or HO2
John Dalton • Took his own experiments and those of others to write a paper, which later became known as the Modern Atomic Theory • It gave a compilation of the information at the time and allowed other scientist to test his ideas.
Dalton's Atomic Theory • All matter is composed of extremely small particles called atoms, which cannot be subdivided, created, or destroyed. • Atoms of a given element are identical in their physical and chemical properties. • Atoms of different elements differ in their physical and chemical properties. • Atoms of different elements combine in simple, whole-number ratios to form compounds • In chemical reactions, atoms are combined, separated, or rearranged but are never created, destroyed, or changed.
An Analogy for Dalton’s atom An atom is small, spherical and the same throughout. • A small atomic fireball
Dalton also gave us the Law of Multiple Proportions • Elements could combine in different ratios to produce different compounds • For Example, nitrogen and oxygen can form N2O, NO, NO2,N2O3, N2O4, and N2O5.
His ideas weren’t 100% correct, but they gave scientist a good start
Definite and Multiple Proportions – The Math Involved Types of problems that can be asked at this point in time.
Type One – The Easy Type • Table salt is composed of sodium and chlorine. Chlorine comprises 60.66% of the compound, what percentage is sodium? • 39.34% • C, H, and O combine to make C2H6O2. Hydrogen is 9.74% and carbon is 38.70%. What percent is oxygen? • 51.56%
Type 2 – You will need a periodic table for this type • The formula of ethylene glycol is C2H6O2, what percentage by weight do you have of each of the elements? • Step 1 – Calculate the mass of C2H6O2, by adding the mass of each element: • C = 12.01 g x 2 • H = 1.01 g x 6 • O = 16.00 g x 2 = 24.02 g = 6.06 g = 32.00 g 62.08 g
Type 2 – You will need a periodic table for this type • Step 2 – Divide each elemental mass by the mass of the compound • C = 12.01 g x 2 • H = 1.01 g x 6 • O = 16.00 g x 2 • Step 3 – Multiply by 100 • C = 38.69%; H = 9.76%; O = 51.55% = 24.02 g 62.08 g = 0.3869 = 6.06 g 62.08 g = 0.0976 = 32.00 g 62.08 g = 0.5155 62.08 g
Let’s try this one together What percentage by weight do you have of each of the elements if you have the formula Al2O3?
Answers • 42.9% C and 57.1% O • 77.7% Fe and 22.3% O • 2.7% H and 97.3% Cl • 52.2% C, 13.0 % H, and 34.8% O • 32.4% Na, 22.6% S, and 45.0% O