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植物油加氢脱氧 制燃料 —— 概述

植物油加氢脱氧 制燃料 —— 概述. Vegetable Oil Based Jet Fuels Overview. 报告人：杨昱涵 指导老师：张香文. Contents. Vegetable Oil Biofuel history Research in the world Domestic Research. Theory Basis. Problems & Planning. Introduction. Products & Analysis. Vegetable Oil. Triglyceride. C 76-78%

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植物油加氢脱氧 制燃料 —— 概述

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  1. 植物油加氢脱氧制燃料——概述 Vegetable Oil Based Jet Fuels Overview 报告人：杨昱涵 指导老师：张香文

  2. Contents • Vegetable Oil • Biofuel history • Research in the world • Domestic Research Theory Basis Problems & Planning Introduction Products & Analysis

  3. Vegetable Oil Triglyceride C 76-78% H 11.5-12.5% O 9-11%

  4. Biofuel History Emergency Fuel Biodiesel 1st Generation Green Diesel 2nd Generation 3rd Generation 1940s 1980s 2000s 1990s • Vegetable Oil • Transesterification • Alcoholysis • Hydroprocessing • Deoxygenation • Micro Algae • Cellulose

  5. Research in the world Murzin Finland Kubicka Czech Toba Japan Bezergianni Greece Taufiqurrahmi Malaysia Sahoo India Corma Spain Solazyme USA Lamb USA Savage USA UOP USA Idem Canada Lima Brazil

  6. Domestic Research 1 浙大 上海交大 2 Umich Savage；Hydrothermal M； F； CaO； Catalytic Cracking； quasi-CO/CO2 intermediates; CaCO3 3 北大 Phenolic Bio-Oil; Pd/C; Hydroxygenation; Alkanes 4 湘潭大学 郑大 Phenol/ benzaldehyde/ acetophenone; Amorphous Co-Mo-B; Hydrodeoxygenation; Bronsted Transesterification; KF/ZnO 5

  7. Contents Introduction Problems & Planning • Feasibility Analysis • Raw Material Selection • About Mechanism Theory Basis Products & Analysis

  8. Properties Comparison Srivastava, A.; Prasad, R., Triglycerides-based diesel fuels. Renewable & Sustainable Energy Reviews 2000, 4, (2), 111-133. Dr. James D. Kinder ; Timothy Rahmes, Evaluation of bio-derived synthetic parraffinic kerosene.

  9. 80% 70% 60% 50% 40% 30% 20% Carbon Number Vegetable Oil Parrafin Fatty Acid Jet Fuel C10 C12 C14 C16 C18 C20 Blakey, S.; Rye, L.; Wilson, C. W., Aviation gas turbine alternative fuels: A review. Proceedings of the Combustion Institute 2011, 33, (2), 2863-2885.

  10. Fatty Acid Composition (wt%) Palmitic 16:0 C16H32O2 Stearic 18:0 C18H36O2 Arachidic 20:0 C20H40O2 Oleic 18:1 C18H34O2 Linoleic 18:2 C18H32O2 Linolenic 18:3 C18H30O2 Ricinoleic C18H34O3 12 3 0 23 55 0 0 Soybean 6 3 0 17 74 6 0 Sunflower 3 1 0 64 22 8 0 Rapeseed 12 2 Tr 25 6 Tr 0 Corn 13 4 1 43 35 1 0 Peanut 16 6 0 13 34 0.8 0 Jatropha 10 8 0 24 39 16 0 Rubber seed 1 1 0 3 5 0 88 Castor 5 84 0 21 0 0 0 Olive 26 5 0 21 58 0 0 Cotton seed Taufiqurrahmi, N.; Bhatia, S., Catalytic cracking of edible and non-edible oils for the production of biofuels. Energy & Environmental Science 2011√, 4, (4), 1087-1112. Huber, G. W.; Iborra, S.; Corma, A., Synthesis of transportation fuels from biomass: Chemistry, catalysts, and engineering. Chemical Reviews 2006, 106, (9), 4044-4098.

  11. Mechanism Decarboxylation +H2O Decarbonylation Stearic Acid Hydrodeoxygenation C12-16 Cracking

  12. Thank you！

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