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Table 15-1, p. 612

Table 15-1, p. 612. Common Names of Carboxylic Acids. Table 15.1. Common Names of Dicarboxylic Acids. Table 15.1. p. 614. p. 615. Fig. 15-1, p. 616. p. 616. Table 15-2, p. 615. p. 618. p. 618. Electrophilic Aromatic Substitution. Fig. 9-16, p. 338.

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Table 15-1, p. 612

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  1. Table 15-1, p. 612

  2. Common Names of Carboxylic Acids Table 15.1

  3. Common Names of Dicarboxylic Acids Table 15.1

  4. p. 614

  5. p. 615

  6. Fig. 15-1, p. 616

  7. p. 616

  8. Table 15-2, p. 615

  9. p. 618

  10. p. 618

  11. Electrophilic Aromatic Substitution Fig. 9-16, p. 338

  12. pKa’s of Substituted Benzoic Acids Lower pKa Higher pKa Fig. 9-16, p. 338

  13. Preparation of Carboxylic Acids : Review • Oxidation of 1 alcohols: • a. • b. p. 620

  14. a Preparation of Carboxylic Acids : Review • Oxidation of 1 alcohols: • a. CrO3, H2SO4 • b. K2Cr2O7, H3O+ • Oxidation of 1 alcohols: p. 620

  15. Preparation of Carboxylic Acids : Review • 2. Oxidation of aldehydes: • a. • b. • Oxidation of 1 alcohols: p. 620

  16. Preparation of Carboxylic Acids : Review • 2. Oxidation of aldehydes: • a. CrO3, H2SO4 • b. K2Cr2O7, H3O+ • Oxidation of 1 alcohols: p. 620

  17. Preparation of Carboxylic Acids : Review • 3. Oxidative cleavage • a.of aryl benzenes (sect 9.10): • b.carbon-carbon double bonds : • i. • ii. Methyl, 1° , 2° p. 620

  18. Preparation of Carboxylic Acids : Review • 3. Oxidative cleavage • a.of aryl benzenes (sect 9.10): KMnO4 • b.carbon-carbon double bonds : • i. • ii. Methyl, 1° , 2° p. 620

  19. Preparation of Carboxylic Acids : Review • 3. Oxidative cleavage • a.of aryl benzenes (sect 9.10): KMnO4 • b.carbon-carbon double bonds : • i. (sect 8.8) KMnO4 • ii. Methyl, 1° , 2° p. 620

  20. Preparation of Carboxylic Acids : Review • 3. Oxidative cleavage • a.of aryl benzenes (sect 9.10): KMnO4 • b.carbon-carbon double bonds : • i. (sect 8.8) KMnO4 • ii. O3, H2O2 Methyl, 1° , 2° p. 620

  21. Preparation of Carboxylic Acids : Review • 3. Oxidative cleavage • a.of aryl benzenes (sect 9.10): KMnO4 • b.carbon-carbon double bonds : • i. (sect 8.8) KMnO4 • ii. O3, H2O2 Methyl, 1° , 2° p. 620

  22. Preparation of Carboxylic Acids : • Oxidative Cleavage: • a. O3, H2O2 • 2. Reduction of Carbon Dioxide: • a. Examples • b. Mechanism • c. Limitations p. 620

  23. Preparation of Carboxylic Acids : • 3. Hydrolysis of Nitriles • Examples • Limitations • Mechanisms • Acid catalyzed • Base catalyzed p. 620

  24. Preparation of Nitriles • From Alkyl Halides • 2. From Amides p. 620

  25. Reactions of Nitriles with Reducing Agents • Lithium Aluminum Hydride • 2. Grignard Reagents p. 620

  26. Fig. 15-4, p. 627

  27. p. 628

  28. Fig. 15-5, p. 628

  29. End

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