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Designing and Optimizing a Multistage Hydrogen Pump. Stephanie Noble Advisor: Professor Benziger REU Partner: Chelsea Bonetti. Goals and Motivation. Optimizing a Hydrogen Pump to Conserve Energy. WHAT:. Confirm theoretical performance of previous Multi-Stage Pump.
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Designing and Optimizing a Multistage Hydrogen Pump Stephanie Noble Advisor: Professor Benziger REU Partner: Chelsea Bonetti
Goals and Motivation Optimizing a Hydrogen Pump to Conserve Energy WHAT: • Confirm theoretical performance of previous Multi-Stage Pump. • Design and optimize our own Multi-Stage Pump. • Efficient/Effective • Portable • Minimal Energy Loss WHY: • Obtainun-polluted fuel (H2) andpure waste (CO2) • Prove theoretical high energy efficiencies with multi-stage design.
How a Hydrogen Pump Works A Chemical Perspective 3H2/ CO2 Polymer Electrolyte Polymer Electrolyte H+ H+ • Process • Gases Enter • Hydrogen/Carbon Mix • Protons Cross Membrane • Electrochemical Pumping Process • Leftover Gas Exits • In a Multi-Stagepump, these pass to the nextstage. • New CO2/H2 Ratio. Anode Anode Cathode Cathode (3-x) - y H2/ CO2 y H2 x H2 e- e- (3-x)H2/ CO2
Why a Hydrogen Pump? It’s Customizable! A Comparison with the Conventional System Hydrogen Pump • Single-Stage • Advantages • High Degree of Separation • Low Temperature Operation • Acts as a Pump • Disadvantages • Lower Efficiency • Serpentine flow • (previous models) • BUT!... Multi-Stage • Same Advantages • Higher Theoretical Efficiency
Assembly of a Hydrogen Pump Brief Procedure
Linear Hydrogen Pump Design Challenges and Final Product • STRENGTHS: • Durable • Thorough Mixing • Ease-of-use • WEAKNESSES: • Difficult Screw Insulators • Weak Luer Locks • Uneven Pressure Distribution
Our Design: Efficiency Efficiency, Extent of Separation vs. Voltage More efficient than Commercial Current @ 0.8 V and Pure H2: Our Design: 1.31 A Commercial: ~0.7 A
Optimization Parameters Customizing a Single Unit Current vs. Voltage (Different C/H Ratios) • Why is there an optimum voltage? • Hydrogen can only cross the membrane so fast • Limiting diffusion to and across the membrane • What controls where the optimum occurs? • Rate at which Hydrogen contacts the Membrane • Feed: C/H Ratio, Flow rate
Data Analysis Analytical Program Set Parameters Analyze Data Set Optimum Values of Each Stage
Data Analysis Optimization Program • Prepare Program Parameters • Determine desired trends. • Feed Condition Optimal Voltage • Fit with parameters determined experimentally. • Design Program • Report Optimal Voltage from Trend • Alter Feed Conditions based on Previous Stages
Conclusion What’s next? Separate-Stage Design • Increased effectiveness, durability, and ease-of use Program for Multi-Stage Analysis • Observe efficiency/operation of both individual stages and Overall Process • Separate Program for Optimizing a Single Stage Confirmation of Theoretical Process • Observed similar trends • However, more Conclusive Results TBD • Our Design and Program facilitate future Confirmation Multi-Stage Hydrogen Pump: The Future of Green Energy Production
Special Thanks to: Professor Jay Benziger May Jean Cheah Eric Gauthier Xuemei Wu PRISM/PCCM PEI Grand Challenges Program