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Explore the foundational concepts in quantum mechanics, including eigenstates, statistical interpretation, uncertainty principles, Dirac notation, and Heisenberg's equations of motion. Learn how to calculate and interpret observables and wave functions.
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Physics 451 Quantum mechanics I Fall 2012 Oct 19, 2012 Karine Chesnel
Phys 451 • Next homework assignments: • HW # 14 due Friday Oct 19 by 7pm • Pb 3.7, 3.9, 3.10, 3.11, A26 • HW #15 due Tuesday Oct 23 • Pb 3.13, 3.14, 3.17, 3.18, 3.22, 3.23 Practice test 2 M Oct 22 Work with your group! Test 2: Tu Oct 23 – Fri Oct 26
We measure an observable (Hermitian operator) • Operator’s eigenstates: Discrete spectrum Continuous spectrum eigenvector eigenvalue Phys 451 Generalized statistical interpretation • Particle in a given state Eigenvectors are complete:
Phys 451 Generalized statistical interpretation Particle in a given state Fourier’s trick to find Cn • Normalization: • Expectation value
Phys 451 Quiz 18 If you measure an observable Q on a particle in a certain state , what result will you get? • the expectation value • one of the eigenvalues of Q • the average of all eigenvalues • A combination of eigenvalues • with their respective probabilities
Phys 451 Generalized statistical interpretation Operator ‘position’: Probability of finding the particle at x=y:
Phys 451 Generalized statistical interpretation Operator ‘momentum’: Probability of measuring momentum p: Pb 3.11: probability of measuring p in a given range
Phys 451 The Dirac notation Different notations to express the wave function: • Projection on the position eigenstates • Projection on the momentum eigenstates • Projection on the energy eigenstates
Quantum mechanics The uncertainty principle Finding a relationship between standard deviations for a pair of observables Uncertainty applies only for incompatible observables
Quantum mechanics The uncertainty principle Position - momentum
Quantum mechanics The uncertainty principle Position - Energy Pb 3.14
Quantum mechanics The uncertainty principle Energy - time Special meaning of Dt
Quantum mechanics Quiz 19 An excited particle emits a certain radiation of energy E with a band width DE. What can we say about the characteristic lifetime of excited state? • Lifetime is a least • Lifetime is a most • Lifetime is a least • Lifetime is a most
constant Ehrenfest’s theorem Quantum mechanics Heisenberg equation of motion Pb 3.17
when Definition for Dt: To evaluate Dt: • choose an appropriate operator • calculate and Quantum mechanics Heisenberg equation of motion Pb 3.18 Application: use Q = x, in the case of the infinite square well
“bra” “ket” Inner product: Operator: Projection operator: for orthonormal basis Quantum mechanics The Dirac notation Pb 3.22 Pb 3.23 or