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The Chemistry of Acids & Bases. Properties of Acids. Lemons have citric acid!. Vinegar has acetic acid!. Dilute solution have a _____taste Aqueous solutions conduct an electric current What do we call substances that can conduct electric currents?
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Properties of Acids Lemons have citric acid! Vinegar has acetic acid! • Dilute solution have a _____taste • Aqueous solutions conduct an electric current What do we call substances that can conduct electric currents? **The greater the # of ions in solution, the greater the electrical conductivity. • Acids react with bases to form a water & salt _____________________ • Acids react with certain metals to produce H2 gas Table J: _____________________________ • Acids cause acid-base indicators to change color _________________ Strong acid = Weak acid =
Properties of Bases • Bases have a bitter taste. • Bases have a slippery or soapy feeling. • Bases conduct an electric current. • Bases react with acids to form water & salt. • Bases cause acid-based indicators to change color. Strong base= Weak base =
Arrhenius Theory • Arrhenius Acid = ______________________________________ ______________________________________ - Ex: **Some notes on the hydrogen ion!: H+ is really just a _________! In a water solution, the positively charged proton is attracted to an unshared pair of electrons in the water molecules. Proton ends up covalently bonding with water to form _______________________ http://hogan.chem.lsu.edu/matter/chap26/animate3/an26_037.mov
So, acids dissolve in water & react to produce ______________ & ________________. H2SO4 2H3O+ (aq) + SO42- (aq) H3SO4 3H3O+ (aq) + SO42- (aq)
Arrhenius Theory • Arrhenius Base: = _____________________________________________ _____________________________________________ - Remember: hydroxide ion = OH- NaOH Na+(aq) + OH- (aq) KOH K+(aq) + OH- (aq) http://hogan.chem.lsu.edu/matter/chap26/animate3/an26_038.mov
Other Acid/Base Definitions Brønsted – Lowry Acids = _____________ Brønsted – Lowry Bases = _____________ Note: A “proton” is really just a hydrogen atom that has lost it’s electron! Lewis acid = _____________________________ Lewis base = _____________________________
Neutralization Reactions = an Arrhenius acid reacts with an Arrhenius base to produce water & a salt • General reaction: **All neutralization reactions have the same net equation: = http://www.chem.iastate.edu/group/Greenbowe/sections/projectfolder/animations/HClandNaOHtgV8.html
Acid-Base Titration = the process of adding measured volumes of an acid or base of known concentration to an acid or base of unknown concentration until neutralization takes place • Through a titration, it is possible to calculate the concentration of the unknown solution: MAVA = MBVB http://www.chem.iastate.edu/group/Greenbowe/sections/projectfolder/flashfiles/stoichiometry/acid_base.html
Monoprotic Acid: H+ molarity = molarity of acid solution - Ex: 2.5M HCl = 2.5M H+ Diprotic Acid: H+ molarity = 2 x molarity of acid solution - Ex: 2.5M H2SO4 = ___ H+ Triprotic Acid: H+ molarity = 3 x molarity of acid solution - Ex: 2.5M H3SO4 = ___ H+ Monohydroxy Bases: OH- molarity = molarity of base solution - Ex: 3.0M NaOH = ___ OH- Dihydroxy Bases: OH- molarity = 2 x molarity of base solution - Ex: 3.0M Ba(OH)2 = ___ OH-
Acidity vs. Alkalinity ** These terms refer to the relative strength of the acid or base in terms of H+ and OH- concentrations.** • Acidity ___________________________ • Alkalinity _________________________ [H+] > [OH-] :_________ [H+] < [OH-] :_________
pH Scale • The pH scale expresses [H+] as a number from 0 to 14 • Each pH unit represents a tenfold increase or decrease in [H+] and [OH-]. • As [H+] increases, [OH-] decreases (and vice-versa).
Acid-Base Indicators Indicator = ____________________________________ ____________________________________ **REMEMBER: Everything you need to know about acid-base indicators is on Table M in the reference tables!!** http://hogan.chem.lsu.edu/matter/chap27/demos/dm27_010.mov