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Chapter 8

Chapter 8. Describing Chemical Change Types of Chemical Reactions Reactions in Aqueous Solution. Chapter 8.1 Describing Chemical Change. Word Equations Chemical Equations Balancing Chemical Equations. Word Equations.

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Chapter 8

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  1. Chapter 8 • Describing Chemical Change • Types of Chemical Reactions • Reactions in Aqueous Solution

  2. Chapter 8.1 Describing Chemical Change • Word Equations • Chemical Equations • Balancing Chemical Equations

  3. Word Equations • Reaction – one or more substances (the reactants) change into one or more new substances(the products) • Reactants  Products •  = ? • Yields, gives or reacts

  4. Word Equations • As reactants are converted to products, the bonds holding the atoms together are broken and new bonds are formed. • REMEMBER: The atoms are neither created nor destroyed, just rearranged. (Law of Conservation of Mass)

  5. Word Equations • Rust • Iron reacts with oxygen to produce iron(III) oxide (rust) • Iron + Oxygen  Iron(III) Oxide (reactants) (yields) (products)

  6. Word Equations • Hydrogen peroxide reacts to form water and oxygen gas. • Hydrogen peroxide  water + oxygen MnO2 • H2O2(aq)  H2O(l) + O2(g)

  7. Word Equations • Burning of Methane • Methane + Oxygen  Carbon Dioxide + Water

  8. Chemical Equations • Iron + Oxygen  Iron(III) Oxide • Fe + O2  Fe2O3 • Now add physical states • Fe(s) + O2 (g)  Fe2O3 (s)

  9. Chemical Equations • Reactions with a catalyst • Catalyst – a substance that speeds up the rate of a chemical reaction, but is not used up in the reaction. • A catalyst is written above the arrow

  10. Chemical Equations • Manganese(IV) oxide catalyzes the decomposition of hydrogen peroxide.

  11. Balancing Chemical Reactions • Each side of the equation has the same number of atoms of each element. • C(s) + O2(g) CO 2(g) • 1 carbon, 2 oxygen  1 carbon, 2 oxygen

  12. Balancing Chemical Reactions • H2(g) + O2(g) H2O(l) • 2 hydrogen, 2 oxygen  2 hydrogen, 1 oxygen • Balance • 2 H2(g) + O2(g) 2 H2O(l)

  13. Balancing Chemical Reactions • Rules • 1) Determine the correct formulas • 2) Write the formulas for the reactants on the left and the products on the right. Place a  in between. If there are two or more reactants or products, use a + in between. • 3) Count the number of atoms of each element.

  14. Balancing Chemical Reactions • Rules • 4) Balance the elements one at a time until you have equal numbers of elements on each side • 5) Make sure all numbers are in their smallest whole number ratio.

  15. Chapter 8.2 Types of Chemical Reactions • Classifying Reactions • Combination Reactions • Decomposition Reactions • Single-Replacement Reactions • Double-Replacement Reactions • Combustion Reactions • Predicting Products of Reactions

  16. Classifying Reactions • Identify the five general types or reactions: • Combination Reactions • Decomposition Reactions • Single-Replacement Reactions • Double-Replacement Reactions • Combustion Reactions

  17. Combination Reactions • Two or more substance combine to form a single substance. • General Reaction: • R + S = RS • Example: • 2Mg(s) + O2(g) 2 MgO(s)

  18. Decomposition Reactions • A single compound is broken down into two or more substances. • General Reaction: • RS = R + S • Example: • 2HgO(s) 2 Hg(l) + O2(g)

  19. Single-Replacement Reactions(Single Displacement Reactions) • One element replaces a second element in a compound. • General Reaction: • T + RS = TS + R • Example: • 2K(s) + 2H2O(l) 2KOH(aq) + H2(g)

  20. http://www.kentchemistry.com/links/Kinetics/PredictingSR.htm

  21. Double-Replacement Reactions • Exchange of positive ions between two reacting compounds. • General Reaction: • RS + TU = RU + TS • R+S- + T+U- = R+U- + T+S- • Example: • K2CO3(aq) + BaCl2(aq) 2KCl(aq) + BaCO3(s)

  22. http://www.kentchemistry.com/links/Kinetics/DRFlash.htm

  23. Combustion Reactions • An element or compound reacts with oxygen often producing energy as heat or light. • General Reaction: • CxHy + (x + y/4) O2 xCO2 + (y/2)H2O • Example: • CH4 (g) + 2O2 (g) CO2(g) + 2H2O (g)

  24. Name each type of reaction • 1) 2Mg(s) + O2(g) 2 MgO(s) • 2) 2HgO(s) 2 Hg(l) + O2(g) • 3) CH4 (g) + 2O2 (g) CO2(g) + 2H2O (g) • 4) 2K(s) + 2H2O(l) 2KOH(aq) + H2(g) • 5) K2CO3(aq) + BaCl2(aq) 2KCl(aq) + BaCO3(s)

  25. Name each type of reaction • 1) 2Mg(s) + O2(g) 2 MgO(s) • Combination • 2) 2HgO(s) 2 Hg(l) + O2(g) • Decomposition • 3) CH4 (g) + 2O2 (g) CO2(g) + 2H2O (g) • Combustion • 4) 2K(s) + 2H2O(l) 2KOH(aq) + H2(g) • Single Replacement • 5) K2CO3(aq) + BaCl2(aq) 2KCl(aq) + BaCO3(s) • Double Replacement

  26. Chapter 8.3 Reactions in Aqueous (aq) Solutions • Net Ionic Equations • Predicting the Formation of a Precipitate

  27. Net Ionic Equations • AgNO3(aq) + NaCl (aq) AgCl(s) + NaNO3(aq) • Double Replacement Reaction • Most ionic compounds dissociate (separate) into ions (cations and anions) when they dissolve in water. • When all ions dissociate, we write the equation with the charges on it. = Complete Ionic Equation

  28. Complete Ionic Equation • Ag+(aq) + NO3-(aq) + Na+(aq) Cl-(aq) AgCl(s) + Na+(aq)+ NO3-(aq) • The equation can be simplified by crossing out any ions that do not participate in the reaction. You do this by canceling out ions that appear on both sides. • Ag+(aq) + NO3-(aq) + Na+(aq) Cl-(aq) AgCl(s) + Na+(aq)+ NO3-(aq) • You are left with the Net Ionic Equation: • Ag+(aq) + Cl-(aq) AgCl(s)

  29. Pb(s) + AgNO3(aq) Ag(s) + Pb(NO3)2(aq) • Pb(s) + Ag+(aq)+NO3 -(aq) Ag(s) + Pb2+(aq) +2NO3-(aq) • Pb(s) + Ag+(aq) Ag(s) + Pb2+(aq) • Need to balance charges • Pb(s) + 2Ag+(aq) 2Ag(s) + Pb2+(aq)

  30. Predicting the Formation of a Precipitate • Table F in reference table

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