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Journal/Discussion: (you will need your periodic table today! ). 1. What are the four quantum numbers and what do they represent? 2. What do s, p, d and f stand for when we are talking about electrons? 3. How many electrons do the following elements have: C, W, Sc?
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Journal/Discussion:(you will need your periodic table today!) 1. What are the four quantum numbers and what do they represent? 2. What do s, p, d and f stand for when we are talking about electrons? 3. How many electrons do the following elements have: C, W, Sc? 4. How is the maximum (or valence) energy level represented on the periodic table?
Principle Q.N. [Energy levels] ( n ) Angular Momentum QN [shape, sublevels, s p d f] ( L ) Magnetic Q.N. [Orientation, orbitals] (mL) Spin Q.N. [spin of e-] (ms) 5 4 Quantum Numbers
Electron Configurations The arrangement of electrons in atoms
Aufbau (building up) Principle • An electron occupies the lowest energy orbital that can receive it (aufbau principle) Do not try to draw this diagram
following the Aufbau Principle Maximum number of electrons s = 2 (only 1 orbital /sublevel) p = 6 (3 orbitals / sublevel) d = 10 (5 orbitals / sublevel) f = 14 (7 orbitals / sublevel)
Periodic Table – Filling Order – Aufbau Principle 18 1 2 13 14 15 16 17
Methods of Showing Electron Configuration • Electron Configuration Notation • Orbital Notation • Kernel Notation (Noble Gas) Configuration • Electron Dot Notation
Pauli Exclusion Principle • No two electrons in an atom have the same set of four quantum numbers. • Electrons must have opposite spins
Hund’s Rule • Orbitals of equal energy are each occupied by one electron before any orbital is occupied by a second electron, and all electrons in singularly occupied orbitals must have the same spin
Method to show Electron Configuration • Orbital Notation • He = • Phosphorus
Write the orbital notation for: • Carbon (C) #6 • Oxygen (O) #8 • Scandium (Sc) #21
How to write an Electron Configuration? • The first number is the energy level. (1,2,3,4,5…) • The lowercase letter is the sub-level. The sub-levels are named s, p, d and f. The number of available sub-level increases as the energy level increases. • The number in superscript is the number of electrons in a sub-level. • Each sub-level can hold only a certain number of electrons. The s sub-level can hold no more than 2 electrons, the p sub-level can hold 6, the d sub-level can hold 10 and the f sub-level can hold as many as 14.
Method to show Electron Configuration • Electron Configuration Notation • He = 1s2 • P = 1s2 2s2 2p6 3s2 3p3
Write the electron configuration notation for: • Carbon (C) #6 • Oxygen (O) #8 • Scandium (Sc) #21
Kernel Notation • Uses the noble gas (group 18) before the element and then shows the electron configuration notation for everything past the noble gas • P = [Ne] 3s23p3
Write the Kernel notation for: • Carbon (C) #6 • Oxygen (O) #8 • Scandium (Sc) #21
Now do worksheet #1 • Stay tuned… • Later this week… • Lewis Dot Structures
Lewis Dot Structure • Shows only the valence (outer) electrons • Electrons in the outermost (highest) M.E.L. • Only for main group (s and p block) elements • Dots represent the electrons • One on each side (starting at the top and moving clockwise) then double them up • Phosphorus