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6. H*: > 1s 1 ; orkuríkt. H: 1s 1 ; grunnorka. H. l = 0/s. l = 1/p. l = 2/d. l = 3/f. 1x e -. E. : :. : :. : :. : n = 4. n = 3. n = 2. n = 1. A > H. t.d. C (6e - ). l = 0/s. l = 1/p. l = 2/d. l = 3/f. E. : :. : :. : :. : n = 4. n = 3. n = 2.
E N D
H*: > 1s1; orkuríkt H: 1s1; grunnorka H. l = 0/s l = 1/p l = 2/d l = 3/f 1x e- . E : : : : : : : n = 4 n = 3 n = 2 n = 1
A > H. t.d. C (6e-) l = 0/s l = 1/p l = 2/d l = 3/f . E : : : : : : : n = 4 n = 3 n = 2 C*, t.d. : 1s2,2s2,2p13s1 C: 1s2,2s2,2p2 n = 1
A > H. t.d. C (6e-) l = 0/s l = 1/p l = 2/d l = 3/f . E : : : : : : : n = 4 n = 3 n = 2 n = 1
Y2(r) r
n n+1 ....... n+2 ........ n....... S - svigrúm
Y2(r,q) q r
http://mackenzie.chem.ox.ac.uk/teaching/Atomic%20Spectroscopy.pdfhttp://mackenzie.chem.ox.ac.uk/teaching/Atomic%20Spectroscopy.pdf
http://mackenzie.chem.ox.ac.uk/teaching/Atomic%20Spectroscopy.pdfhttp://mackenzie.chem.ox.ac.uk/teaching/Atomic%20Spectroscopy.pdf
http://mackenzie.chem.ox.ac.uk/teaching/Atomic%20Spectroscopy.pdfhttp://mackenzie.chem.ox.ac.uk/teaching/Atomic%20Spectroscopy.pdf
http://mackenzie.chem.ox.ac.uk/teaching/Atomic%20Spectroscopy.pdfhttp://mackenzie.chem.ox.ac.uk/teaching/Atomic%20Spectroscopy.pdf
http://mackenzie.chem.ox.ac.uk/teaching/Atomic%20Spectroscopy.pdfhttp://mackenzie.chem.ox.ac.uk/teaching/Atomic%20Spectroscopy.pdf
Spin-orbitcoupling: http://en.wikipedia.org/wiki/Angular_momentum_coupling
http://mackenzie.chem.ox.ac.uk/teaching/Atomic%20Spectroscopy.pdfhttp://mackenzie.chem.ox.ac.uk/teaching/Atomic%20Spectroscopy.pdf
E „Energies“ in cm-1
Tvískautsvægi óbreytt/ Dipole moment unchanced Tvískautsvægi breytist/ Dipole moment changes Tilfærsla gerist ekki/ No energy transfer Tilfærsla á sér stað/ Energy transfer occurs
http://mackenzie.chem.ox.ac.uk/teaching/Atomic%20Spectroscopy.pdfhttp://mackenzie.chem.ox.ac.uk/teaching/Atomic%20Spectroscopy.pdf
Zeeman effect/ hrif: Zeeman(2)
Zeeman(1) Zeeman effect / hrif: