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Resources Chapter Presentation Bellringer Transparencies Sample Problems Visual Concepts Standardized Test Prep
Chemical Equations and Reactions Chapter 8 Table of Contents Section 1Describing Chemical Reactions Section 2Balancing Chemical Equations Section 3Classifying Chemical Reactions Section 4Writing Net Ionic Equations
Section1 Describing Chemical Reactions Chapter 8 Objectives • List evidence that suggests that a chemical reaction has occurred and evidence that proves that a chemical reaction has occurred. • Describe a chemical reaction by using a word equation and a formula equation. • Interpret notations in formula equations, such as those relating to states of matter or reaction conditions.
Section1 Describing Chemical Reactions Chapter 8 Chemical Reaction • A chemical reaction is the process by which one or more substances change into one or more new substances. • Reactants are the original substances in a chemical reaction. • Products are the substances that are created in a chemical reaction.
Visual Concepts Chapter 8 Chemical Reaction
Section1 Describing Chemical Reactions Chapter 8 Evidence of a Chemical Reaction
Section1 Describing Chemical Reactions Chapter 8 Reactions and Energy Changes • Energy can be released in a chemical reaction. • methane + oxygen carbon dioxide + water + energy • Energy is a product. • Energy can be absorbed in a chemical reaction. • dinitrogen tetroxide +energy nitrogen dioxide • Energy is a reactant.
Section1 Describing Chemical Reactions Chapter 8 Constructing a Chemical Equation • A chemical equation shows the chemical formulas and relative amounts of all reactants and products. • A word equation contains the names of the reactants and products. • Equations must be balanced.
Section1 Describing Chemical Reactions Chapter 8 Writing a Word Equation or Formula Equation methane + oxygen carbon dioxide + water ?CH4 + ?O2 ?CO2 + ?H2O
Section1 Describing Chemical Reactions Chapter 8 Equations and Reaction Information
Section2 Balancing Chemical Equations Chapter 8 Objectives • Write and interpret a balanced chemical equation for a reaction, and relate conservation of mass to the balanced equation.
Section2 Balancing Chemical Equations Chapter 8 Reactions Conserve Mass • Mass cannot be created or destroyed by a chemical or physical change • Equations must be balanced. • ?Na + ?H2O ?NaOH + ?H2
Section2 Balancing Chemical Equations Chapter 8 Balancing Equations • The number of atoms for each element must be the same on the reactants’ side and on the products’ side. • Acoefficient multiplies the number of atoms of each element in the formula that follows. • H2O: ( ) hydrogen atoms, ( ) oxygen atom • 2H2O: ( ) hydrogen atoms, ( ) oxygen atoms
Section2 Balancing Chemical Equations Chapter 8 Balancing Equations Sample Problem A Balance the equation for the reaction of iron(III) oxide with hydrogen to form iron and water.
Balancing Equations • Sample Problem A Solution • Identify reactants and products. • reactants products • Fe2O3 + H2 Fe + H2O • Count atoms • Insert coefficients.
Section2 Balancing Chemical Equations Chapter 8 Balancing Equations • Sample Problem A Solution • Identify reactants and products. • reactants products • Fe2O3 + H2 Fe + H2O • Count atoms 3 2 3 • Insert coefficients.
Section2 Balancing Chemical Equations Chapter 8 Reactions Conserve Mass • Balanced equations show mass conservation • ?Na + ?H2O ?NaOH + ?H2 • Na + H2O NaOH + H2 • Never change subscripts to balance equations • Unbalanced: H2 + O2 H2O • Incorrect: H2 + O2 H2O2 • H2O H2O2 • Correct: 2H2 + O2 2H2O
Section2 Balancing Chemical Equations Chapter 8 Polyatomic Ions can be balanced as a group
Section2 Balancing Chemical Equations Chapter 8 Balancing Equations Sample Problem C Aluminum reacts with arsenic acid, HAsO3, to form H2 and aluminum arsenate. Write a balanced equation for this reaction.
Section2 Balancing Chemical Equations Chapter 8 Balancing Equations Sample Problem C Solution 1. Identify reactants and products. reactants products ( )Al + ( ) HAsO3 ( )H2 + ( ) Al(AsO3)3 2. Count Atoms 3. Insert coefficients
Section3 Classifying Chemical Reactions Chapter 8 Bellringer • Describe the following terms. • Synthesis • Combustion • decomposition • displacement
Section3 Classifying Chemical Reactions Chapter 8 Objectives • Identify combustion reactions, and write chemical equations that predict the products. • Identify synthesis reactions, and write chemical equations that predict the products. • Identify decomposition reactions, and write chemical equations that predict the products.
Section3 Classifying Chemical Reactions Chapter 8 Objectives, continued • Identify displacement reactions, and use the activity series to write chemical equations that predict the products. • Identify double-displacement reactions, and write chemical equations that predict the products.
Section3 Classifying Chemical Reactions Chapter 8 Combustion Reactions • A combustion reaction is a reaction of a carbon-based compound with oxygen. • Combustion of propane: • C3H8 + 5O2 3CO2 + 4H2O • Combustion of ethanol: • CH3CH2OH + 3O2 2CO2 + 3H2O
Section3 Classifying Chemical Reactions Chapter 8 Synthesis Reactions • In a synthesis reaction a single compound forms from two or more reactants. • Two elements form a binary compound • C + O2 CO2 • 2C + O22CO • Two compounds form a ternary compound • CaO(s) + H2O(l) Ca(OH)2(s) • CO2(g) + H2O(l) H2CO3(aq)
Section3 Classifying Chemical Reactions Chapter 8 Decomposition Reactions • In a decomposition reaction a single compound breaks down, often with the input of energy, into two or more elements or simpler compounds. • Decomposition of water electricity 2H2O(l) O2(g)+ 2H2(g) • A metal carbonate decomposes to form a metal oxide and carbon dioxide. heat CaCO3(s) CaO(s) + CO2(g)
Section3 Classifying Chemical Reactions Chapter 8 Decomposition Reactions, continued Sample Problem D Predicting Products Predict the product(s) and write a balanced equation for the reaction of potassium with chlorine.
Section3 Classifying Chemical Reactions Chapter 8 Decomposition Reactions, continued Sample Problem D Solution • Reaction is most likely a synthesis reaction, so the product will be binary • Potassium will lose one electron to become a 1+ ion. • Chlorine will gain one electron to become a 1– ion. • K + Cl2 KCl • Balance the equation. • 2K + Cl2 2KCl
Section3 Classifying Chemical Reactions Chapter 8 Displacement Reactions • In adisplacement reactiona single element reacts with a compound and displaces another element from the compound. • 2Al(s) + 3CuCl2(aq) 2AlCl3(aq) + 3Cu(s) • Aluminum displaces copper.
Visual Concepts Chapter 8 Single Displacement Reaction
Section3 Classifying Chemical Reactions Chapter 8 Displacement Reactions, continued • The activity seriesranks the reactivity of elements
Section3 Classifying Chemical Reactions Chapter 8 Displacement Reactions, continued Sample Problem E Determining Products by Using the Activity SeriesMagnesium is added to a solution of lead(II) nitrate. Will a reaction happen? If so, write the equation and balance it.
Section3 Classifying Chemical Reactions Chapter 8 Displacement Reactions,continued Sample Problem E Solution • Identify the reactants. • Magnesium will attempt to displace lead from lead(II) nitrate. • Check the activity series. • Magnesium is more active than lead and displaces it. • Write the balanced equation. • Mg + Pb(NO3)2 Pb + Mg(NO3)2
Section3 Classifying Chemical Reactions Chapter 8 Double-Displacement Reactions • In adouble-displacement reactiontwo compounds in aqueous solution appear to exchange ions and form two new compounds. • One of the products must be a solid precipitate, a gas, or a molecular compound, such as water. • HCl(aq) + NaOH(aq) HOH(l) + NaCl(aq)
Visual Concepts Chapter 8 Double-Displacement Reaction
Chapter 8 Identifying Reactions and Predicting Products
Section4 Writing Net Ionic Equations Chapter 8 Bellringer • Write a definition for the word spectator in terms of the part spectators play in a sporting event.
Section4 Writing Net Ionic Equations Chapter 8 Objectives • Write total ionic equations for reactions in aqueous solutions. • Identify spectator ions and write net ionic equations for reactions in aqueous solutions.
Section4 Writing Net Ionic Equations Chapter 8 Ionic Equations, continued • Ionic compounds dissolve in water • KI(aq) = K+(aq) + I–(aq) • Pb(NO3)2(aq) = Pb2+(aq) + (aq) • Reaction between KI and Pb(NO3)2 • 2KI(aq) + Pb(NO3)2(aq) PbI2(s) + 2KNO3(aq) • Total Ionic Equation • 2K+(aq) + 2I–(aq) + Pb2+(aq) + (aq) • PbI2(s) + 2K+(aq) + (aq)
Section4 Writing Net Ionic Equations Chapter 8 Ionic Equations, continued • Spectator ions remain unchanged in the solution as aqueous ions. They do not react. • 2K+(aq) + 2I–(aq) + Pb2+(aq) + (aq) • PbI2(s) + 2K+(aq) + (aq) • The net ionic equationis the chemical equation that shows only the net change. • 2I–(aq) + Pb2+(aq) PbI2(s)
Visual Concepts Chapter 8 Net Ionic Equation
Section4 Writing Net Ionic Equations Chapter 8 Ionic Equations, continued • Net Ionic equations can be used for displacement reactions. • Zn(s) + Cu2+(aq) + (aq) Cu(s) + Zn2+(aq) + (aq) • net ionic equation • Zn(s) + Cu2+(aq) Cu(s) + Zn2+(aq)
Section4 Writing Net Ionic Equations Chapter 8 Ionic Equations, continued • Check atoms and charge to balance net ionic equations. • (aq) + Ba2+(aq) BaSO4(s) • Charge: (2–) + (2+) = 0 0 • Zn(s) + Cu2+(aq) Cu(s) + Zn2+(aq) • Charge: 2+ 2+
Chapter 8 Writing a Net Ionic Equation