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Chemical Reactions and Equations. Chapter 8. Chemical reactions…. Process by which one or more substances are described by a. 4 Signs of a Chemical Reaction:. Evolution of _________ and ________________ 2. Production of ______________
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Chemical Reactions and Equations Chapter 8
Chemical reactions…. • Process by which one or more substances are • described by a
4 Signs of a Chemical Reaction: • Evolution of _________ and ________________ 2. Production of ______________ 3. Formation of a _____________________(solid produced as a result of a chem rxn in a sol’n) 4. _____________________change
Chemical equation • Represents the identities and relative amounts of the reactants and products in a chemical reaction • (NH4)2Cr2O7(s) ---> N2(g) + Cr2O3(s) + 4H2O(g) Characteristics: • represents the _______________________________ • contains correct _________________ for the reactants & products • satisfies the law of ____________________________ (same # and kind of atoms on both sides of the equation)
(NH4)2Cr2O7(s)---> N2(g) + Cr2O3(s) + 4H2O(g) • Formula equation: uses symbols/formulas to represent the reactants and products • Reactants • products • coefficient (understood to be “1” if no # appears • symbols (p.246)
ammonium dichromate --> nitrogen + chromium(III) oxide + water • Word equation: (previous ex.) • only fulfills ONE characteristic of a chem eq (____________________________________) • 1st step in writing a balanced chemical equation
Steps to write a balanced chemical equation: 1. Write the word equation. 2. Convert the word equation into a formula equation. 3. Include symbols, where known. 4. Balance the equation. NEVER CHANGE A SUBCRIPT IN BALANCING EQUATIONS!
Cu + H2SO4 CuSO4 + SO2 + H2O Cu H S O Cu + H2SO4 CuSO4 + SO2 + H2O
SiF4 + H2O H2SiF6 + H2SiO3 Si F H O SiF4 + H2O H2SiF6 + H2SiO3
Solutions of lead(II) nitrate and sodium hydroxide react to produce a lead(II) hydroxide precipitate and an aqueous solution of sodium nitrate.
Solid rubidium oxide reacts with water to produce an aqueous solution of rubidium hydroxide.
Lithium reacts with a hydrochloric acid solution to produce an aqueous solution of lithium chloride and hydrogen.
In the presence of an electrical current, sodium hydroxide can be produced from the reaction of a sodium chloride solution with water. Hydrogen and chlorine gases are the other products.
Aluminum sulfate is produced when aluminum hydroxide reacts with sulfuric acid. Water is the other product.
5 types of chemical reactions: • synthesis (composition) • decomposition • single-replacement (displacement) • double-replacement (displacement) • combustion
Synthesis Reactions • 2 or more substances combine to form a new compound • 2 H2 + O2 2H2O
Reactions of metals with oxygen and sulfur • magnesium metal + oxygen • barium + sulfur (S8)
Some metals can form oxides of varying oxidation #: • iron + oxygen iron(II) oxide • iron + oxygen iron(III) oxide
Nonmetals can also form oxides • S8(s) + 8O2(g) 8SO2(g) • C(s) + O2(g) CO2(g) • 2C(s) + O2(g) 2CO(g)
Reactions of metals with halogens • potassium + iodine • strontium + bromine • cobalt + fluorine [cobalt(III) ion forms]
Synthesis reactions with metal oxides • activemetals* oxides + water hydroxides • calcium oxide + water • *(see p. 266)
Synthesis reactions with nonmetal oxides • nonmetal oxides + water oxyacids • sulfur dioxide + water
Synthesis reaction of metal oxide & nonmetal oxide • calcium oxide + sulfur dioxide
Decomposition • a single cmpd undergoes a rxn that produces 2 or more simpler substances • H2CO3 H2O + CO2
Decomposition of… • binary cmpds • metal carbonates • metal hydroxide • metal chlorates • acid
Decomposition of binary cmpds • simplest decomposition rxn • decomposition into elements • ELECTROLYSIS: decomp by an electric current • 2 H2O(l)electricity--->
Decomposition of Metal Carbonates • when heated (∆), produce a metal oxide and carbon dioxide gas • CaCO3(s) -∆
Decomposition of Metal Hydroxides • all metals except Gp 1 decomp when heated to produce metal oxides and water • Ca(OH)2(s) -∆ CaO(s) + H2O(g)
Decomposition of Metal Chlorates • when heated, decompose to produce a metal chloride and oxygen • KClO3(s) -∆ 2KCl(s) + 3O2(g)
Decomposition of Acids • Many acids decompose into nonmetaloxides and water • H2SO4(aq) -∆ • H2CO3(aq)
Single Replacement Reaction • one element replaces a similar element in a cmpd • 2 Al + Fe2O3 Al2O3 + 2 Fe
Single Replacement Reaction of… • a metal in a cmpd by another metal • hydrogen in water by a metal • hydrogen in an acid by a metal • replacement of halogens
Replacement of a metal in a cmpd by another metal • aluminum + lead(II) nitrate • (p. 266 Al is more reactive than Pb so a spontaneous reaction will occur)
Replacement of H in water by a metal (active) very active metals (i.e. Gp 1) pulls one H from the water • sodium + water
Replacement of H in water by a metal (less-active) less- active metals reacts with steam and pulls-off both hydrogens from the water • iron + water
Replacement of H in an acid by a metal more-active metals reacts with some acidic soln’s • magnesium + hydrochloric acid
Replacement of Halogens • a more reactive halogen will replace a less-active halogen • the higher up in the Gp 17 family, the MORE reactive the halogen • Reactivity: F>Cl>Br>I • chlorine gas + potassium bromide sol’n
fluorine gas + sodium chloride sol’n • bromine liquid + potassium chloride sol’n
Double replacement reactions • ions of 2 cmpds exchange places in an aqueous solution to form 2 new cmpds • ZnBr2 + 2 AgNO3 Zn(NO3)2 + 2 AgBr
Double displacement reactions….. • formation of a precipitate • formation of a gas • formation of water
Formation of a precipitate • one product is insoluble (or just slightly soluble) …see page 427 • potassium iodide + lead (II) nitrate
Formation of a gas • one product is an insoluble gas and bubbles out • iron(II) sulfide + hydrochloric acid sol’n
Formation of Water • one of the products yields the molecular cmpd water • hydrochloric acid + sodium hydroxide
Combustion Reactions • substance reacts with oxygen and releases a large amount of energy (light and heat) • hydrogen + oxygen water vapor • hydrocarbon + oxygen carbon dioxide + water
Combustion (burning) of propane: • C3H8(g) + O2
Will cobalt react with sodium chloride? Co(s) + NaCl(aq) ?
Activity Series • list of elements organized according to the ease with which the elements undergo certain chemical reactions • are at the TOP and can replace a metal in a cmpd found below it in single displacement reactions
Will the following react? IF so, write an equation. • Mn + H2O --30C ? • Cd + O2 • Ag + HCl