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Measuring Livestock Odors. Dr. Ron E. Sheffield LSU AgCenter rsheffield@agcenter.lsu.edu 225.205.4533. Olfaction -- Sense of Smell. Complex Evokes a physiological and emotional reaction Humans detect > 10,000 odors Manure over 150 odorous compounds Mixture of gases
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Measuring Livestock Odors Dr. Ron E. Sheffield LSU AgCenter rsheffield@agcenter.lsu.edu 225.205.4533
Olfaction -- Sense of Smell • Complex • Evokes a physiological and emotional reaction • Humans detect > 10,000 odors • Manure over 150 odorous compounds • Mixture of gases • Extremely low concentrations • Health impacts?
Gas vs Odor Measurement • Gas • Identify individual gases • Measure concentrations • Odor--Olfactometry • Analyze mixture • Correlates with odor • Uses human sense of smell
Odor Measurement and Description • Intensity (strength) • Duration / Persistence • Frequency • Offensiveness / Hedonic tone • Character descriptor • Threshold concentrations (D/T) • Detection • Recognition
Odor -- Sound Analogy • Odor . . . Sound • Below Detection . . . “I can’t hear it” • Detection . . . “I hear something” • Recognition . . . “It’s Elvis!” • Intensity . . . “How loud is it?”
Odor Intensity Measurement Table 2. Odor Intensity Reference Scale Based on N - Butanol Equivalent head space Intensity category concentration of N - butanol Mixture of N - butanol in in air (ppm)* water (ppm) 0 No odor 0 0 1 Very Light 25 250 2 Light 75 750 3 Moderate 225 2250 4 Strong 675 6750 5 Very strong 2025 20250 ° * Based on air temperature of 20.3 C
Duration / Persistence 10 Intensity 0 Decreasing Log Concentration (D/T)
Smells like Mint – Musty Earth – Rotten Mold – Sewer Sulfur – Sour Ammonia – Pungent Menthol – Burned Character Descriptor
Odor Measurement • Electronic nose • Correlates gases to odors • Similar to indicator gas • No accepted tool for manure odors • Olfactometer • Measures concentration • ASTM & European Standard • Scentometer
Triangular Forced Choice Olfactometer • Dynamic • Triangular • Forced choice • Standardized procedures • ASTM • European Standard • Trained panelists
IdaNoseÒ Nasal Ranger Field Olfactometer
Fenceline H2S Monitoring OdaLog-LR 0.01 – 2 ppm Jerome 860 0.1 – 10 ppm
Odor Modeling • Correlate mathematical representations to the measured effect during real world situations. • Used for technology evaluation and planning • Not intended for regulatory enforcement • Currently no “ag odor” model incorporates real-world terrain features • Field Sniffers • Model Comparison
Field Sniffers • Trained panelists • Measurements • N-butanol intensity scale • Scentometers • Field olfactometers • Charcoal filter masks • Record intensity • Validate dispersion model
Field Sniffers Wind Direction 5 - 20 Meters 200 Meters 100 Meters 50 Meters Weather Station
Evaluate the differences of odor concentrations determined by the three field olfactometers using trained panelists Variability between field olfactometers Correlation to field and laboratory measured odor intensity (n-butanol) Correlation to laboratory olfactometry panel Correlation to field and laboratory gas analysis Odor Methods Study
Experimental Design Control • Laboratory olfactometry Treatments • Box scentometer • Facial mask field olfactometer • “Nasal Ranger” field olfactometer • Field n-butanol • Laboratory n-butanol • Jerome Meter (H2S/TRS) • Ammonia • GC/MS & GC/SPME
Standard Deviation of logD/T WWPS Food Processor Freestall Dairy Open-Lot Dairy
Emissions from Livestock Farms Methodology • 38 dairy and 15 beef feeding operations • August, 2003 and the April, 2004 • Three measurements • Summer (August & September) • Fall (October & November) • Spring (April) • “Blind” data set • Trained panelists – subset of panelists from Phase 1
Compost – Static Compost – Turning of Fresh Manure Compost - Turning Corn Silage Bunker Corral Cleaning Slurry - Fresh/Vacuumed Manure Broadcast Application Solid Manure - Corral Manure Application Pivot Irrigation – Drag Tube @100% Manure Pivot Irrigation – Spray Nozzles @100% Manure Pivot Irrigation – Rotating Nozzles @100% Manure Pivot Irrigation – “Wobble” Nozzles @100% Manure Separated Solids Broadcast Application Settling Basin Settling Basin – covered Land Application and Manure Management Practices
Wastewater Irrigation Sprinklers • Impact Sprinklers • Drop Nozzles • Sprays • Rotating Heads
Nelson R3000 Rotator Nelson S3000 Spinner Senninger I-Wob
Odor Acceptability Is the odor present acceptable ………. ( -10 ”Unacceptable” … 0 … 10 “great”) as an odor on the farm property? _________ as an odor across the property line? _________ as an odor at a rural residence? _________ as an odor at a public event or private party? _________
Buffer Requirements • Most buffers are targeted on odors (even when states only have authority to minimize risk to water) • New or expanding construction • Distances vary greatly between areas • Most based on arbitrary distances rather than scientific procedures to reduce occurrence
OFFSET: Odor From Feedlots Setback Estimation Tool • Scientific process to establish odor based setbacks • Developed by Univ. of Minnesota, adopted by MN and MI • Develops an Odor Emission Factor for all existing and proposed facilities Values shown are for Midwestern (IA, MN, MI) conditions, and assumes flat terrain
Odor Emission Number x Area (sq.ft) x Odor Control Factor 10,000 Odor Emission Factor Odor Emission Number x Area (sq.ft) x Odor Control Factor Odor Emission Number x Area (sq.ft) x Odor Control Factor 10,000 10,000 10,000 • Determine Odor Emission Factor for each odor source on the farm • Barns • Manure Storage/Stockpiles • Feed Storage
Odor Emission Numbers Values shown are for Midwestern (IA, MN, MI) conditions, and assumes flat terrain
Odor Control Factors Values shown are for Midwestern (IA, MN, MI) conditions, and assumes flat terrain