Breakthrough Technologies For Downstream Oil Industry

1. Breakthrough Technologies For Downstream Oil Industry

2. IndianOil R&D Breakthrough Technologies Contents

3. Alternative Energy Biofuels Hydrogen-CNG CTL / Gasification Shale Oil IndianOil-R&D • Refinery Technology • FCC/HD • Catalyst • Pipelines (iPIG) • Lubricant • Technology Biotechnology Nanotechnology • Fuel Additives Polymers & Petrochemicals Technical Services

4. 52Pilot Plants 61Research and Technology Partners 332 Patents filed till date 200Effective Patents 231Scientists IndianOil-R&D At a Glance

5. NCCR IITM IITD BARC IISc DCE IndianOil-R&DCOLLABORATIVE RESEARCH

6. IndianOil R&D Breakthrough Technologies Contents

7. NeedleCoke FoodGradeHexane Sweetening Process CFC IndianOil R&D Indmax • Indadept • Kero HDT • DHDT • Isom • Delayed Coking • Indalin Catalyst TECHNOLOGY BASKET

8. Technology demonstrated in 2003 Can process wide variety of feedstocks including Atmospheric Residue and Vacuum Residue with CCR upto 11 wt% High flexibility to produce LPG, Gasoline and diesel. Employs proprietary catalyst formulation Typical product yields LPG 35-50 wt% (Propylene 45-50wt% in LPG) Gasoline 20-40 wt% (High octane 98+) Diesel 15-25 wt% Indmax Technology- Resid to LPG, Light Olefins & High Octane Gasoline INDMAX unit at GR (100,000 TPA)

9. INDMAX Digboi (0.1) BRPL (0.74) Guwahati (0.1) Paradip (4.0) • Worldwide licensing through Lummus Technology Inc., USA • Proposals submitted to various refineries globally– Takreer, Ras Tanura, Idemitsu, Japan, OMV, Austria (Aug’08), PTTAR, Thailand (Sep’08)

10. Polymer Grade Hexane (PGH) /Food Grade Hexane (FGH) PGH and FGH from paraffinic Naphtha and raffinate from Aromatic Extraction Unit Benzene Reduction Feed : 1.3-4 % Product : < 100 ppm • Joint Technology Licensing with EIL • 28,000 TPA Unit operational at Gujarat Refinery • 1 Unit (20,000 TPA) licensed to Bhatinda Refinery

11. DHDT Technology • Can upgrade straight run as well as cracked diesel streams • Sulphur reduction from ~1.8% to less than 50/ 10 ppm • Cetane improvement by 7-10 units • Proprietary catalyst • Joint licensing with Engineers India Ltd. • 1.2 MMTPA unit under construction at Bongaigaon Refinery. Commissioning in Mar, 2010 • 5.0 MMTPA unit under implementation at Paradip Refinery based on process data input from IOC R&D 11

12. INDAdept Process Adsorptive Deep desulphurisation • Only novel adsorptive, low cost, efficient deep desulphurisation technology for both Gasoline and Diesel • Proprietary adsorbent in hydrogen environment • Two reactors operated in swing mode of adsorption and regeneration H2 N2 Air Diesel 1 2 Adsorption Regeneration

13. INDAdept Process INDAdeptD • S reduction from 500 to < 10 ppm • No change in cetane & other properties • H2 consumption 0.1 wt% only INDAdeptG • S reduction from 1000 to < 10 ppm • RON reduction of ~ 2 units • H2 consumption 0.2 wt% • Suitable for treating Coker/ FCC gasoline • Employs single reaction step

14. World Petroleum Congress Award Category – Technical Development “Hydro-Processing Technology for Green Fuels Chairman, IOCL Receiving the Award from King of Spain: WPC 2008

15. INDALIN+Value addition from Naphtha/Condensate 50-55% LPG with <3% olefins meeting Auto Grade spec. 17-34% High Octane Gasoline (95+) with 95% Sulphur reduction 25-30% BTX in gasoline Can also handle gas oil range feed stocks No external hydrogen supply and feed desulfurization Proprietary catalyst Process developed for upgrading condensate to Propylene/ Ethylene / LPG for Saudi Aramco. Propylene yield ~18% on feed.

16. Other Technologies Delayed Coker • Joint Licensing with EIL Needle Coke • Commercialized at GR in 2003 • Licensed to BGR in 2003 & NRL in 2007 • Value addition ~ $700-800 per MT of Needle Coke • Light Naphtha Isomerisation • Joint licensing with EIL • Licensed to Bongaigaon Refinery (0.15 MMTPA). Commissioning by March, 2010

17. Other Technologies • Light Naphtha Isomerisation • Joint licensing with EIL • Licensed to Bongaigaon Refinery (0.15 MMTPA). Commissioning by March, 2010

18. FCC catalyst and additive technology (i-Max series) for LPG & Propylene enhancement ZSM-5 additives (i-MAX, i-MAX Super, i-MAX Supreme and i-MAX Ultra)- Used in IOC and non-IOC refineries in India Propylene selective ZSM-5 additive Metal Passivator additive for RFCC units FCC & RFCC Catalysts & Additives

19. DHDT Catalyst • Commercial demonstration of INDICAT-DH-IV • Demonstrated at CPCL in Jun, 09 • Consistent performance with Diesel meeting Euro-IV/V quality • 88- 90% Desulphurisation in VGO mode • Delta Diesel Cetane (Product- Feed) of 7 units under 55 Kg/cm2g

20. PROCESS SIMULATORS • FCC & RFCC (FCC MOD) • Hydrocracker (HC MOD) • CRU (REF MOD) • Diesel-hydrodesulphurisation (DHDS-MOD) • Delayed Coker • Hydrogen Generation Unit Used for Troubleshooting, Optimization, Process design, catalyst evaluation and Technology development

21. TECHNICAL SOLUTIONS Right Fit Technology Selection & Licensing Revamp of Process Units Catalyst Management FCC/Hydroprocessing Catalyst Selection Catalyst Health Monitoring Remaining Life Prediction Process Optimisation Troubleshooting Static Equipment Inspection Services Unit Turnaround Management

22. SERVO-LI Lubricity improver for diesel Excellent Lubricity Performance Biodegradable source Good Storage Stability SERVO-AO : for gasoline Excellent Oxidation Stability High Storage Life Minimum Treat Cost MFA for diesel High Performance Component in Premium Diesel FUEL ADDITIVES

23. BioremediationOiliVorous-S • Bio-Process for bioremediation of oily sludge using OiliVorous-S bacteria. • In use at refineries, marketing & pipeline installations at both IOC & Non-IOC locations since 1994. • Bioremediation carried out both on sea and on-shore. • Good results obtained on sea using bacteria, especially designed to weather high salt concentration. Oily sludge site before treatment Oily sludge site after treatment

24. BioremediationOiliVorous-S Before treatment After treatment Bioremediation of oil contaminated water at Duliajan (Assam)

25. Automobile Industry Defence Railways Lubricant Technology Steel Chemical Textile Cement Aviation

26. LUBRICANTS The TECHNOLOGY BASKET • SERVO Lubricants Covering: • Automotive oils • Rail Road Oil • Marine Oil • Industrial lubricants • Metal Working oils • Jute Batching Oils • Rubber Process oils • Agro spray oils • High Performance Greases • Synthetic Lubricants More than 4000 formulations accounting for ~ 800 commercial grades About 200 New and Revised formulations every year With strong R&D backup, SERVO holds 38% National Lube Business

27. LUBRICANTS TECHNOLOGY BASKET • High performance engine oils meeting latest API, ACEA, JIS and OEM customized specifications • Gas Engine Oils • Energy efficient, long life industrial lubricants & greases • Synthetic compressor, gear, specialty lubricants • NSF listed food grade lubricants & greases • Biodegradable lubricants

28. Marine Oils

29. LUBRICANTS RAILROAD OIL Servo RR 606MG First ever Multi-grade RR Oil in India Indian Railwayssavedover $ 200 million since 2000

30. AFRICA 2008 Total Energy Consumption: 453 Mmtoe (4% of world consumption) Total Proven Oil Reserves: 125.6 Billion barrels (10% of world reserves) Crude Oil Production: 10.3 million bopd (12.5% of world oil production) Total Oil Consumption: 2.9 million bopd (3.4% of world consumption) Total Refining Capacity: 3.2 million bopd ( 3.65% of world refining capacity)

31. AFRICA 2008 1232 666 ‘000 bpd 554 429

32. AFRICA 2030 Figs in MMTPA Product Deficit Product Surplus 36 71 25 38 11 24 5 3 1 Naphtha LPG Total FO Others MS HSD Total JetKero Net Product Deficit:35 MMTPA

33. Diesel Quality worldwide 33

34. Our Offering Novel Technologies, Technological Solutions & Technical Services for : Refinery Revamp/ Modernization Setting up Green Field Refineries, and Installations, Efficiency , Productivity & Profitability Improvement, Energy Conservation etc Value Addition Product Quality Improvement Reliability Enhancement Product, Crude Oil & Gas Pipleines Environment Protection Collaborative R&D

35. ThankYou