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Ch. 13 Solutions. What is a solution? A homogeneous mixture of 2 or more substances in a single phase. What is a substance that is capable of being dissolved? Soluble. What is the substance being dissolved called? Solute The substance that dissolves the solute is called what? Solvent.
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Ch. 13 Solutions • What is a solution? • A homogeneous mixture of 2 or more substances in a single phase. • What is a substance that is capable of being dissolved? • Soluble
What is the substance being dissolved called? • Solute • The substance that dissolves the solute is called what? • Solvent
Homogenous mixture – can’t distinguish the difference in substances • Ex. Tomato juice, pop, vanilla ice cream • Heterogenous mixture – can distinguish the substances in the mixture. • Ex. Stew, salad, chocolate chip ice cream • Video
What is an electrolyte? • A substance that conducts electricity in a solution. • Ex. NaCl in water • A nonelectrolyte is a substance that doesn’t conduct electricity in a solution. • Ex. Sugar in water
What is an alloy? • A solid solution with 2 or more metals mixed together. • Ex. Cu + Sn = Bronze • Ex. Cu + Zn = Brass • Ex. 50% Au + 50% Cu = 12 karat Au • Video
Suspension – is a heterogeneous mixture of a solvent-like substance with particles that slowly settle out. • Ex. Muddy water (separate by a filter) • Video • Colloids – have particles that are intermediate in size between those in solutions & suspension. Don’t settle. • Ex. Milk (Tyndall Effect) • Video
Factors that affect the rate of dissolving • 1. Heat the solvent • 2. Stir/mix the solution • 3. Crush/grind the solution • What is solubility? • The rate at which the solvent dissolves the solute at a given temp. • Video
Solutions • What is a saturated solution? • A solution that can’t take on any more solute and dissolve it. • What is a unsaturated solution? • A solution that can take on more solute. • What is supersaturated solution? • A solution with more solute than a saturated solution. (over saturated) • Video
Polar vs. Nonpolar • “Likes dissolve alike” • A polar molecule dissolves a polar molecule. • Ex. Water and salt (both polar) • Ex. Gasoline and benzene (non polar) • Ex. Water and gasoline don’t mix • Polar & nonpolar
Immiscible are substances that is not soluble in each other. • Ex. Gas & water, oil & water • Miscible are substances that are soluble in each other. • Ex. NaCl & water, gas & benzene
Ethanol & ether both have polar and nonpolar ends on their molecules, thus they are able to dissolve both polar and nonpolar substances. • The solubility of a gas in a liquid is directly proportional to the partial pressure of that gas on the surface of the liquid. Henry’s Law
Example of Henry’s Law • Gas is released in a carbonated pop bottle when opened because the pressure is less. • What is effervescence? • The rapid escape of a gas from a liquid in which it was dissolved in.
Table 13-4 Solubility vs. Temperature • Concentration of a solution is the measurement of the amount of solute in a given amount of solvent or solution. • Ex. Concentrated O.J. or Conc. HCl • A concentration of a solution can be diluted by adding H2O.
Percent by mass is the number of grams of solute dissolved in 100 g of solution. Sample Problem 13-1 • Ex. 10 g of NaOH in 90 g of H2O • 10 g of NaOH / 10 g of NaOH + 90 g of H2O X 100% = 10% NaOH (by mass)
Molarity • Molarity is the number of moles of solute in 1 liter of solution. • To find the molarity of a solution you must know the molar mass of the solute. • Molarity (M) = # of moles of solute / # of liters of solution • Example Problem 13-2
Molality • Molality is the concentration of a solution expressed in moles of solute per kilogram of solvent. • Molality (m) = # of moles of solute / mass of solvent (kg) Sample Problem 13-4
Nonvolatile is a substance with little tendency to become a gas under the existing condition. • Ex. A lower freezing point & higher boiling point than water. • Colligative property is a property that depends on the # of solute particles, but is independent of their nature. • Ex. antifreeze