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Chapter 9: Stoichiometry. A. Introduction to Stoichiometry: Stoichiometry – the calculation of an unknown quantity of a substance from a known value of a different substance in a chemical reaction
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Chapter 9: Stoichiometry A. Introduction to Stoichiometry: • Stoichiometry – the calculation of an unknown quantity of a substance from a known value of a different substance in a chemical reaction - like mole conversions, except the coefficients in the rxn. matter - coefficients = # of moles - 1 mole = molar mass = 6.02 x 1023 particles = 22.4 L
Stoichiometry is like a recipe: • Reactants = Ingredients • Products = What the recipe makes • Limiting reagent – reactant that determines how much product can be made (used up first) • Excess reagent(s) – reactant(s) not all used up ex. Brownies (makes 24) 2 cups of mix 3 eggs ¼ cup oil
Stoichiometry is like a recipe (cont.): ex. 2 mix + 3 eggs + ¼ oil 24 brownies If you had 2x the ingredients, how many brownies? 48 brownies If you had 96 brownies, how many eggs? 12 eggs If you have 4 cups mix, 4 eggs, ½ cup oil, what is the limiting reagent? the eggs (need 6, only have 4)
B. Mole-Mole Stoichiometry: • Balance equation (if not done) • Start with given (in moles, in this case) • Multiply by mole ratio (coefficients from rxn.) • Include all units and substance in your work! ex. 4Al + 3O22Al2O3 How many moles of aluminum oxide can be produced from 6 moles of oxygen? 6 moles O2 x 2 moles Al2O3 = 3 moles O2 4 moles Al2O3
ex. 6NaOH + Fe2(SO4)3 3Na2SO4 + 2Fe(OH)3 How many moles of Fe(OH)3 are produced from reacting 8 moles of NaOH? How many moles of Fe2(SO4)3 are reacted to form 1.7 moles of Na2SO4? 8 moles NaOH x 2 moles Fe(OH)3 = 2.67 moles of 6 moles NaOH Fe(OH)3 1.7 moles Na2SO4 x 1 mole Fe2(SO4)3 = 0.57 moles of 3 moles Na2SO4 Fe2(SO4)3
C. Volume-Volume Stoichiometry: • 1 mole = 22.4 L of any gas at STP • Start with given (in L, in this case) • Convert given (L) to moles • Multiply by mole ratio (converts moles of given to moles of find – use coefficients from rxn.) • Convert moles of find back to L • Cancel out same units, substances, and numbers • Solve problem
ex. 2SO2 + O2 2SO3 How many liters of oxygen are needed to produce 19.8 L of sulfur trioxide? 19.8 L SO3 x 1 mol SO3 x 1 mol O2 x 22.4 L O2 22.4 L SO3 2 mol SO3 1 mol O2 19.8 L SO3 x 1 mol O2 2 mol SO3 Answer:9.9 L O2
ex. 2NO + O2 2NO2 How many liters of nitrogen monoxide are needed to react with 5.6 L of oxygen to produce nitrogen dioxide? 5.6 L O2 x 1 mol O2 x 2 mol NO x 22.4 L NO 22.4 L O2 1 mol O2 1 mol NO 5.6 L O2 x 2 mol NO 1 mol O2 Answer:11.2 L NO
D. Mass-Mass Stoichiometry: • 1 mole = molar mass (use masses from the P.T.) • Start with given (in grams, in this case) • Convert given (grams) to moles (calculate the molar mass) • Multiply by mole ratio • Convert moles of find back to grams • Cancel out same units and substances • Solve problem
ex. 2SO2 + O2 2SO3 How many grams of oxygen are needed to produce 19.8 g of sulfur trioxide? 19.8 g SO3 x 1 mol SO3 x 1 mol O2 x 32.0 g O2 80.1 g SO3 2 mol SO3 1 mol O2 SO3 = 80.1 g/mole O2 = 32.0 g/mole Answer:3.96 g O2
ex. 2NO + O2 2NO2 How many grams of nitrogen monoxide are needed to react with 5.6 g of oxygen to produce nitrogen dioxide? 5.6 g O2 x 1 mol O2 x 2 mol NO x 30.0 g NO 32.0 g O2 1 mol O2 1 mol NO Answer:10.5 g NO
E. Mixed Stoichiometry Problems: • Uses moles, liters, grams and/or molecules • Start with given • Convert given to moles (unless given is in moles) • Multiply by mole ratio • Convert moles of find to unit of find in problem (unless find is in moles) • Cancel out same units and substances • Solve problem
ex. 2NO + O2 2NO2 How many liters of nitrogen monoxide are needed to react with 8.2 g of oxygen to produce nitrogen dioxide? 8.2 g O2 x 1 mol O2 x 2 mol NO x 22.4 L NO 32.0 g O2 1 mol O2 1 mol NO Answer:11.48 L NO