E N D
1. 2004/4/16 1
2. 2004/4/16 2 ?? ??????????? –
??????????????????????????????????? .
????????????
?????2003??????,????(2003~2008)?????????????????????
???????:
??????(<30nm),?????????????????????,?????????????????????????,????????????????????????
??????????????
?????????????????????????????????,???????????????????????????????????????,??????????????
3. 2004/4/16 3 ???????
4. 2004/4/16 4 ??????? ?????
????????3C???????
??????????,???????????????
?????:
??????????????????????????????????????????????????????—??
5. 2004/4/16 5 ?????,????????????????????,?????.
?????????(???)
????????(????????????)????
6. 2004/4/16 6 ??????? ????? :??(Pb acid)?? (???????)
60????:??(Ni-Cd)????
1985??? :??(Ni-MH)????
????????????
?????????????(Ni-Cd)??????
?????????????????????????(?????????1.)
7. 2004/4/16 7 ?1. ?????????????
??:
????:?????,?????????????,?????????????,???,????????????????,????-?????;????????,??????????????????????????????,??????????????,?????????
8. 2004/4/16 8
9. 2004/4/16 9 ?2. ?????????????(????:NEC)
10. 2004/4/16 10 ?1 ?????????
11. 2004/4/16 11 ?????
?????
12. 2004/4/16 12 1-2 ??????????(???????????) ???????? (???????)
?????(Li-ion) --??????????????
??:
1. ???????(??????)
2. ?????????????????
??????(LPB) --????????(sol gel)????
13. 2004/4/16 13 ????????(solid state polymer electrolyte, SPE) ??????????
????????????
?????? ,
?????????????
?????????,?????????:??/?????/??
???????????????????
(??????????60%,?????1????????)
(??????????60%,?????1????????)
??:
?????????????????,?????????????????????
75%????????????13%
??????????
14. 2004/4/16 14 ?3. ???????????
15. 2004/4/16 15
16. 2004/4/16 16 ????????? ????????????? ,???????
????????? :7.7?? (2002?)~9.9?? (2005? )
???????????2002????45.3%
??????????????
1997?:????3000??,????????
2003?:????????????
17. 2004/4/16 17 ?4: ?????????????? ????????:?????????????????,??????????????
18. 2004/4/16 18 ??????? ??????:?????????????…(???????????2)
????????????????
?????????????
??????????????
???????????,???????????
??????????(swing batteries)
19. 2004/4/16 19 ?2 ?????????
20. 2004/4/16 20 ???????? ??????????????????,????????????????????
?????????????(???)?????,???????????????
????????5
21. 2004/4/16 21 ?5. ?????????
22. 2004/4/16 22 ????????? ????
3C????????????????
????????????????,NB?????????
CPU???????
LCD?????
??????
??????
23. 2004/4/16 23 ????????? ????
????????????
???????? (???????? )
?????????????????
??????????????
????????????????????,???????,?????????????????
24. 2004/4/16 24 ??????????? ????
???????
???????????
????????????? :????
1998?????????????,???????????????????????????,?????????????????????,???????????????????
??????????????7%
?????70-80?????
??4?????????????????
?????????????????????
25. 2004/4/16 25 ???????????? ??:????????????
??????????? :????????
?????????????????
?????????,????????(320mAh/g)?????(>420 mAh/g)
????????????,??????? (?3 )
????????
26. 2004/4/16 26 ?3 ????????????
27. 2004/4/16 27 ????(carbon nanotubes) ?????????????
???? :
??????????????????
?????????????(Fullerenes)????
??:??????????
??:???????
???????????
??????(Multi-Walls Nano Tubes,MWNT,???2??????????)
??????(SWNT,??????????)
???????2.27%,
???????????????????????????
28. 2004/4/16 28 ??: 1998? , Prof. Otto Zhou (University of North Carolina )
???????,
??????????(caps)???????????????,???????,??????????????????????????,
????:?????????????
?????????????(NMR)????
??????????????????????,
??????????????????????????
??MWNT??????,??????1000 mAh/g??
????:
??????????????????????,
??????,????????????????????
29. 2004/4/16 29 ?6:?????????
30. 2004/4/16 30 ?7.???????????????????
31. 2004/4/16 31 ??????????:???? ?????????????4?
????????????
?????????????(LiCoO2)
????????3C????????????????????(>450 Wh/L)???
??????????????????? (??????,?8.9 )
????????????(LiNiCoO2)??????
???????
?????????
????????????(>180 mAh/kg)??????????(?140 mAh/kg)?????30%??
??????????80%
???????6??????,???8?
???????????????-??????,????????????,?????????
32. 2004/4/16 32 ?8. LiNiCoO2????????TEM???
33. 2004/4/16 33 ?9. LiNiCoO2???????????????DSC???
34. 2004/4/16 34 ?4. ?????????????
35. 2004/4/16 35 ?????????(Fuel cell)???? ????????
?????????????????
?????????
??????
????????
????
?????????
????????????????????
????:
2013?,??????????????186???
??????:??,????(Stationary)?????
????????350????
?????????????
???????????????
?????????????
???????
??????
????????
36. 2004/4/16 36 ???????????? ?????????????
????
??????????(PEMFC)
?????????(DMFC)
??:??????????????
???? :???????????????
37. 2004/4/16 37 ?10~11????????????????
38. 2004/4/16 38 ?12~13????????????????
39. 2004/4/16 39 ?????? ???????????????????
????(50~70%)????????????????????
??????????????
??????????????,????????????
??????,
??????????????????,
??????,
???????????(?80?),?????????????
????????????????,???????????????????????
40. 2004/4/16 40 ??(???????????????) ??????(Alkaline FC,AFC)
?????????(Proton Exchange Membrane FC,PEMFC)
?????????(Direct Methanol FC,DMFC)
??????(Phosphoric Acid FC,PAFC)
?????????(Molten Carbonate FC,MCFC)
?????????(Solid Oxide FC,SOFC)
41. 2004/4/16 41 ?5. ???????????
42. 2004/4/16 42 PEMFC?DMFC ?????????????????
???????3C??
?????????????
43. 2004/4/16 43 ?????????? (PEMFC) ????:?
????????
???????
?????????????????????
????(??????14 )
???????????????(proton)???
????????????
????????????????(proton exchange membrane)????
??????????,????????
44. 2004/4/16 44 ?14. ??????????(PEMFC)?????
45. 2004/4/16 45 ????????? (DMFC) ???????????????????????
???????????????????,?PEMFC?????????
???????????????
???????????,??????
??????
?????????????????
????????????
????????
??:
?????????????? ,???????,?????????
???? :??????????????????CO?????????????????????
46. 2004/4/16 46 ?15. ?????????(DMFC)?????
47. 2004/4/16 47 ????
???????
48. 2004/4/16 48 (?)???? ??
??:????????????????
????? :2005?
?????NEC??: ???2004???????????
??????DoCoMo: 2004?????3G?????????
??????????? (ABI) :??2004~2005??,????????????????????
???????????????????????????????????????????
49. 2004/4/16 49 ??”????????(DMFC)”??????? .
??????????????????CO?????????????????????
??DMFC?????????????
??????????????????????
????????????????????
?????????1/2
?????????1 ???
???????????,??????4??
50. 2004/4/16 50 ????????? ?? :
???????????????????(Pt/C)
?????Pt-Ru/C?????CO???
???????Pt???????(Pt??2004?2???NT 28,000/?),???????????????
51. 2004/4/16 51 ???(?????????)
?????????????????????????????
????
????????????????,
???????,
?????????????????
52. 2004/4/16 52 ????: ???Serp??
??????????????????100-300 nm?????
?BET????10 m2/g,??3-6 nm?Pt??????????
??NEC?Murata ?????????
??????????,????????(carbon nanohorn),????????????(2-3 nm)??????????????,???????????
??????nanohorn??????????????,?????intrinsic pores?interstitial pores,???????????????5?(?500 m2/g),?????Pt ??,????????
nanohorn :
????????????
?????????????????
????????????
NEC?????nanohorn????,?????????????????2???
53. 2004/4/16 53 ?16. ?????????(carbon nanohorn)?(a)SEM? (b)TEM?
54. 2004/4/16 54 (?)???? ????:
??????????
?????????????
?????????
???? :??Du Pont?Nafion®?
Nafion®?????????
??????(US$800-1000/m2)
????????????cross-over???
????DMFC
55. 2004/4/16 55 Du Pont?Nafion 112? :
??” Nafion®? “???.
????,????????????
????????????????????
??????????????????????
????Ballard?? :BAM 3G?
??:????????15,000??
??:??????
??Dow????: Dow?
?Nafion???,?????????
???????????
???????????????
??Gore???Asahi Glass?Asahi Chemical??? .
56. 2004/4/16 56 ???Toray?? :
???????????,??Nanoalloy??
???????,?????????
????????????????
?????????????(Pt)????????CO????(Ru)???
???????Pt,???????????
57. 2004/4/16 57 ????????
???????????????
??????????????(??H2O)
????????????????????
??????????????,????????~100???
58. 2004/4/16 58 ???????????? -Sony?? ??1990?
?? :??????Fullerene (C60,???)????????????
Fullerene?
??????,???-20?????????
??????????????
???H2,???????????????1-2? ?
?????:
????????,??????H2???????(H+),?????????????
???????????????(H3O+)???????,
??????????????????;
59. 2004/4/16 59 Sony??????????? ?????????Fullerene??
?Fullerene????????????????????,????????
??,Fullerene?????????????
???????????????????????
??????????????????????????
???????Fullerene???????????5???????
???????????????
60. 2004/4/16 60 (?)?? ??:
PEMFC?????
????
????????????????,?????????????(hydrogen-rich)?????
???? :?????????
????????
???????????
?????????
61. 2004/4/16 61 ?????????
????Pt?????????????
??:????????Pt???(agglomeration)
????:
?????????(Argonne National Laboratory)
????(cerium)???????Pt??????????
??????????????,????????
??????????
??????
??????????????????
?????????Pt?????????
???500??????????????Pt/Ceria???
62. 2004/4/16 62 (?)???? ???????????,?????????? :????
???????? :
??????
????
?????? (???? )
(1)???????
(2)???????????
(3)????,?????
(4)???????(99.9999 %)
?? :?????????
63. 2004/4/16 63 ???????????????? :
????????????
???????,????????
??????????? (??????(IEA) , 1998? )
???????5 wt%
??100??????
??:
????????????????????
??????????????
????????????????
64. 2004/4/16 64 ??????? ??????????
???????????
?????????????????
?????????????????
???????????????
65. 2004/4/16 65 ?? ??National Renewable Energy Laboratory?IBM
??????????????????
????????
??2 nm??????????????50 kg-H2/m3,
(???????????????????????????65 kg-H2/m3(????????))
?????????????
??????????????????????
????????????????????
????
????????????????????
????????????
????????????????
66. 2004/4/16 66 ?17. ???????????/???????
67. 2004/4/16 67 ?18. ?????????????????????????????
68. 2004/4/16 68 ????
???????
???
69. 2004/4/16 69 ????:
???????????
??????????????
??????????????????
????????????:
????????
????????
????????43?
??????????62?
??230?
???64?
?????,???????????
??????: ???CO2??????
????:??????
70. 2004/4/16 70 ???????? ??? (??? )
????
71. 2004/4/16 71 ????? 1954???
??????????????????????
?? :????????????? (????? )
????????????????
???????
??????????????????
???????
???????
?????????(??19)
?1997?? :
?????????????????30%?????(??6)
????????,??????????????????,
1980 ?????22??/W ?????4??
???2010?,???????????????????0.75??
?????1.5??,??????????????(????7),???????????,??21?
72. 2004/4/16 72
73. 2004/4/16 73 ?6. ??????????????
74. 2004/4/16 74 ?7 ??????(Solar Module)?????????
75. 2004/4/16 75 ?21. ????????????????
76. 2004/4/16 76 ?????(Solar cell)?? ????:
???????(??????????????)
?????????????
??????????????
??:????,??:?????
????? :???????
????????????????????????????
??????P????
??????N????
???????22??
77. 2004/4/16 77 ?22. ?????????
78. 2004/4/16 78 ???????? :
???? :?( silicon )
???????
????
?41%(?????)
????.
(????????????????????? )
45%??(????????)
?????
79. 2004/4/16 79 ?8?????????????
????????????????: ?=?????/????? × 100%
??????????????10-15%
??????????35%;
????:
?????????:???????18%
???????: ???????17%????
80. 2004/4/16 80 ?8 ?????????????
81. 2004/4/16 81 ??????????????? ??:
????????????,???????????
????????????
??????????????
??20??????????????
?????????????????????????
?????????? ,????????????
????????????:
??????
????????
?? :?????????
82. 2004/4/16 82 ???????,?????????:
????????(Thin Absorber Solar Cell)--????
??/?????????????--????
???(Quantum Well)????(Quantum Dots)????
???????????
83. 2004/4/16 83 ????????(Thin Absorber Solar Cell) ?????(Dye-Sensitized Solar Cell,DSC)?????
??????(Extra-Thin Absorber;ETA)????
84. 2004/4/16 84 ?????(Dye-Sensitized Solar Cell,DSC)????? ?????????10%
?????????????????
????????????????
??????????????????(TiO2?ZnO?SnO2)????????/??????,???????????
??????????????
????????,????????????
???????,???????????????1/5-1/10(?????????)
85. 2004/4/16 85 ??:
???,??????????
?????????(S?S*)
??????????????
??????????(S*?S+)
??????????????,????(S+?S)
????????,????,?????????????????,???????????????????
86. 2004/4/16 86 ?23???????????????????
87. 2004/4/16 87 ??????(Extra-Thin Absorber;ETA)???? ??:
?????????,???????????????,??????????,??????????????,??????-????????????????????p-n Junction???
?????????:
?????????????(RVPE)????????ZnO????ETA????(??24.)
?????????????????,????????,???????,??????
88. 2004/4/16 88 ?24.
89. 2004/4/16 89 ??/????????????? ??:
?1-D?????????????????
????: ?????????,????????????????
??:
??????????????,????????????(Electron Trap,?:?)???
?????????????????????,?????????(Bi-continuous,??????Donor??Acceptor?)???????-???????
??????:C60?CdS?CdSe?CuInS2?????…?
2000?? (Eckert?? )
??1,3-Dipolar Cycloaddition of Azomethine Ylides??????Oligo-PPV
????Pyrrolidine??C60??,
???????/?????????????,?????25???
90. 2004/4/16 90 ?25. ???????C60??????/??????????????
91. 2004/4/16 91 ????
???????
92. 2004/4/16 92 ???????
??????????????
??????????????,??????
??????????????
??????????????????
93. 2004/4/16 93 ??????? ??????????????
????,???????
???????????????
??????????????
????????? :
?????????
???????????????????
??????????
???????
94. 2004/4/16 94 ??????
??????????????
?????,???????????;
????????
????????
?????????
????????????????
????????
?????????????
??????????
???????????????????????????