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Nutrient Pollution and Eutrophication. Eutrophication. Lecture Question What is eutrophication?. Eutrophication. Cultural Eutrophication. Lecture Question What causes cultural eutrophication?. Limiting Nutrients. Cultural Eutrophication. Lecture Question
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Eutrophication • Lecture Question • What is eutrophication?
Cultural Eutrophication • Lecture Question • What causes cultural eutrophication?
Cultural Eutrophication • Lecture Question • So what’s wrong with increased productivity?
HAB Effects on Humans • Amnesia Shellfish Poisoning • Toxin: domoic acid (can be fatal) • GI and neurological disorders • Symptoms: nausea, vomiting, abdominal cramps, diarrhea • Severe cases include neurological symptoms: headache, dizziness, seizures, disorientation, memory loss, respiratory difficulty, coma • Ciguatera Fish Poisoning • Toxins: ciguatoxin/maitotoxin (usually not fatal) • GI, neurological and CV symptoms • Diarrhetic Shellfish Poisoning • Toxin: okadaic acid (not fatal) • GI symptoms • Neurotoxic Shellfish Poisoning • Toxins: brevetoxins (not fatal) • Syndrome almost identical to ciguatera poisoning but slightly less severe • Paralytic Shellfish Poisoning • Toxins: saxitoxins (can be fatal) • Rapid neurological symptoms • Tingling, numbness, burning, drowsiness, etc • Respiratory arrest can occur within 24 hours • HAB events seems to be rising (may reflect better detection)
Dead Zones • Questions • What are dead zones? What are some famous dead zones?
Global Location of Dead Zones Source: NASA http://daac.gsfc.nasa.gov/oceancolor/scifocus/oceanColor/dead_zones.shtml
Nutrient Pollution from the Mississippi Satellite picture shows the effect of nutrient discharge on algae levels (the green color reflects chlorophyll-a concentration)
Formation of Gulf “Dead Zone” • Gulf of Mexico “Dead Zone” forms every summer • When the algae die they settle to the bottom and begin degrading (and consuming oxygen) • Oxygen is depleted (mostly below the pycnocline) creating the dead zone • The dead zone has grown in size from 3200 mi2 (1985-1991) to 6200 mi2 (1993-2001) • Currently about 7900 mi2 (approx size of New Jersey)
Hypoxia in Lakes • Question • How exactly does hypoxia (low oxygen conditions) develop in the bottoms of lakes in response to eutrophication?
Lake Stratification (Usually in Summer) • Inflection point in the thermal profile is called the thermocline. • Mixing across the thermocline is very slow.
Ocean Thermal Profile • 3 main temperature zones: • surface ocean: warm, 100-200 m • thermocline: down to ~1 km • deep ocean: cold, extends to floor
Lake Stratification • Question • How does lake stratification occur in the summer?
Development of Summer Stratification Lake Ontario in 1965
Development of Summer Stratification Lake Ontario in 1965
Observed Seasonal Stratification in a Lake Measurements from Lake Lawrence (MI)
Seasonal Stratification in Lakes • Question • Do all lakes mix completely twice a year?
Types of Holomictic Lakes mixed types (mainly varients of warm monomictic)
Oxygen Depletion in Eutrophic Lakes • Questions • So…about oxygen depletion in eutrophic lakes? And what’s the purpose of the aerators in Westhampton Lake?
Oxygen Depletion in Eutrophic Lakes • Question • Is the hypolimnion the only part of a stratified lake that ever becomes hypoxic?
Effects of Oxygen Depletion on Chemical Composition? • Low DO favors reduced species • Release of chemicals from sediment in reduced form • Reduced form of many chemicals are more mobile than their oxidized form • Release of gases: methane (CH4), hydrogen sulfide (H2S), ammonia (NH3) • smelly! • Release of some toxic metals • Release of nutrients from sediment • Increases effectiveness of nutrient recycling • Feedback loop leading to further algae blooms, eutrophication
Sediment Release: The Oxidized Microzone • How/why does the sediment release chemicals into the water under reducing (low DO) conditions?
Release of Phosphorus from the Sediment • Phosphate doesn’t have a reduced form under natural conditions. So why is it released from the sediment under reducing (low DO) conditions?