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Accuracy & Precision. Two important points in measurement. THE BIG CONCEPT. Accuracy – indicates the closeness of the measurements to the true or accepted value. 2. Precision - The closeness of the results to others obtained in exactly the same way. High Accuracy High Precision.
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Accuracy & Precision Two important points in measurement
THE BIG CONCEPT • Accuracy –indicates the closeness of the measurements to the true or accepted value. 2. Precision - The closeness of the results to others obtained in exactly the same way.
High Accuracy High Precision High Precision Low Accuracy Accuracy vs. Precision
Can you hit the bull's-eye? Three targets with three arrows each to shoot. Accurate and precise Precise but not accurate Neither accurate nor precise How do they compare? Can you define accuracy vs. precision?
Example: Accuracy Who is more accurate when measuring a book that has a true length of 17.0 cm? Susan: 17.0 cm, 16.0 cm, 18.0 cm, 15.0 cm Amy: 15.5 cm, 15.0 cm, 15.2 cm, 15.3 cm
Example - Precision • Which set is more precise? A. 18.2 , 18.4 , 18.3 B. 17.9 , 18.3 , 18.8 C. 16.8 , 17.2 , 19.4
Precision and Instruments • Do all measuring devices have the same amount of precision?
You indicate the precision of the equipment by recording its Uncertainty • Ex: The scale on the left has an uncertainty of (+/- .1g) • Ex: The scale on the right has an uncertainty of (+/- .01g)
What is Percent Error ? • When an experiment is done, it is pretty much certain that the answer is not going to be exactly correct. • Many variables and actions go into an experiment. A change or a misstep in any one of them can result in an answer that is a bit different from the actual value. • Actions such as mismeasurement, lack of purity of reagents, and poor lab technique can all result in error.
How to Calculate Percent Error • We use the following formula. • Y Your observed result (what you got) • A Actual Result (what you should get) • I( Y – A) / A )I x 100 % • You will use this often in Lab.
Example • A Lab group was working in a Lab to determine the percent of Magnesium in a sample of Magnesium Oxide. They determined it to be 58.3g They looked up the actual value and found it to be 60.3g • What is their percent error ?
Solving for Percent Error • Let’s start with the formula • I( Y – A) / A )I x 100 % • Substituting in gives us the following: • I(58.3 – 60.3) / 60.3 )I x 100 % • I( - 2 / 60.3)I .00331 • .00331 x 100 % = 3.31 %
Significant Figures In Measurements
Sig Figs tell you what place to round your answers to. • Your final measurement (answer) can never be more precise than your starting measurement. • To understand that idea, we will discuss accuracy vs. precision
Significant Figures The numbers reported in a measurement are limited by the measuring tool.
How to Determine Significant Figures in a Problem Use the following rules:
Rule #1 • Every nonzero digit is significant in a measurement. Examples: 24m = 2 3.56m = 3 7m = 1
Rule #2 – Sandwiched 0’s • Zeros between non-zeros are significant Examples: 203,205 = 6 7003m = 4 40.9m = 3
Rule #3 – Leading 0’s • Zeros appearing in front of non-zero digits are not significant • Act as placeholders Examples: 0.0000000056 = 2 0. 24m = 2 0.453m = 3
Rule #4 – Trailing 0’s with Decimal Points • Zeros at the end of a number and to the right of a decimal point are significant. Examples: 1.0 = 2 43.00m = 4 1.010m = 4 1.50m = 3
Performing Calculations with Significant Figures • Rule: When adding or subtracting measured numbers, the answer can have no more places after the decimal than the LEAST of the measured numbers. • Only count the Sig Figs that come after the decimal.
Adding and Subtracting • 2.45cm + 1.2cm = 3.65cm, Round off to 3.7cm • 7.432cm + 2cm = 9.432 Round to 9.4cm
Multiplication and Division • Rule: When multiplying or dividing, the result can have no more significant figures than the least reliable measurement. • Count all of the Sig figs in the entire number.
Examples • 56.78 cm x 2.45cm = 139.111 cm2 Round to 139cm2 • 75.8cm x 9.6cm = ?
State the number of significant figures in each of the following: A. 0.030 m 1 2 3 B. 4.050 L 2 3 4 C. 0.0008 g 1 2 4 D. 3.00 m 1 2 3 E. 2,080,000 bees 3 5 7 Learning Check
Learning Check A. Which answer(s) contain 3 significant figures? 1) 0.4760 2) 0.00476 3) 4760 B. All the zeros are significant in 1) 0.00307 2) 25.300 3) 2.050 x 103 C. 534,675 rounded to 3 significant figures is 1) 535 2) 535,000 3) 5.35 x 105
Learning Check In which set(s) do both numbers contain the samenumber of significant figures? 1) 22.0 m and 22.00 m 2) 400.0 m and 40 m 3) 0.000015 m and 150,000 m