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Department of theoretical and applied chemistry

Department of theoretical and applied chemistry. Head of the department, professor Konstantin Bogolitsyn. Department of theoretical and applied chemistry Development conception . Aims. Development conception :

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Department of theoretical and applied chemistry

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  1. Department of theoretical and applied chemistry Head of the department, professor Konstantin Bogolitsyn

  2. Department of theoretical and applied chemistryDevelopment conception. Aims Development conception: Development of the department and its subdivisionsas commonresearch and educational complex Aims: • Providing forward-lookingstaff training and re-training, involvinghigher qualification staff • Increasing efficiency of research in priority scientific and technical areas (chemistry and raw plant chemical technology and environmental protection) by creating most favorable conditions for developing one’s artistic features and one’s abilities in achieving new knowledge, and integrating scientific results into education within the framework of research and educational complex

  3. Department of theoretical and applied chemistryDepartment structure Research and educational center “Chemistry of plant compounds” 2001 ASTU-MSU inter-university department 2001 Department of theoretical and applied chemistry Branch of the department at General Board on Natural Resources ASTU Analytical center 2003 Post-graduate studying (specialty 05.21.03 and 02.00.04) Institute of wood and wood chemical technology

  4. Department of theoretical and applied chemistryStructure of lectures given Lectures given

  5. Department of theoretical and applied chemistryStaff • 2 Doctors of Chemical Science • 1 Doctor of Geographical Science • 1 Doctor of Medical Science • 9 Candidates of Chemical Science • 6 Post-graduate students

  6. Department of theoretical and applied chemistryLaboratories • Gas chromatography • Liquid chromatography • Molecular spectroscopy • Atomic absorption spectroscopy • Electrical chemistry • Fractionating and concentrating • Supercritical fluid extraction

  7. Department of theoretical and applied chemistryAnalytical equipment

  8. Department of theoretical and applied chemistryResearch areas • Physical chemistry of plant polymers • carrying on fundamental and applied research in the area of chemistry and chemical technology of raw plants • Environmental technologies • Analytical chemistry of environmental objects

  9. Department of theoretical and applied chemistryTasks. Fundamental research. Physical chemistry of biopolymers • Researching properties and developing physical-chemical models of interreacting of biopolymers in water-organic medium, including ionic liquids. • Synthesizing and using selective catalysts of oxidative and reductive transformation of aromatic biopolymers • Supercritical fluid extraction of biological active substances • Developing new high-sensitive methods of environmental pollutants’ analysis under their transformation in natural ecosystems

  10. Department of theoretical and applied chemistryAnalytical tasks • chemical and physical-chemical analysis of waste water • chemical and physical-chemical analysis of natural water • chemical and physical-chemical analysis of drinking and underground water • chemical and physical-chemical analysis of soil • analysis of industrial air emissions, caused by stationary and mobile polluters • analysis of air emissions within sanitary protection zones and industrial areas • analysis of the working areas’ air • analysis, used during ecological certification and eco-mapping • analytical evaluation of the space rocket launches’ impact on the environment

  11. Department of theoretical and applied chemistryEducation.Aim. Proposals AIM:Carrying on specialists’ training according to modern and perspective requirements by increasing educational quality and integrating it into national and international educational programs, developing educational and methodical ware and technical equipment of the department PROPOSALS: • Student practice • Studying practice • Degree work practice • Joint summer schools • Studying methods of environment state control • Studying environmental objects, being controlled • Giving lectures by Finnish specialists at the department

  12. EducationOU cooperation experience • 2004-2006– 28 studentswere trained during studying practice in Finland (UO - TUT) • Environmental engineers • Researchers • 3 joint Degree works • «Ecological monitoring and soil recultivationin Barents region» • «Proposals on creating automatic ecological monitoring system at Arkhangelsk city landfill» • «Proposals on developing medical waste processing system in Arkhangelsk city (using Finnish experience)» • Graduators of the department are working at: • Regional and municipal environmental offices • Environmental offices of enterprises • Analytical laboratories

  13. EducationOU cooperation experience

  14. Department of theoretical and applied chemistryExperience. Student exchange. Germany • University of applied scienceFHO OW • 3 German students –Degree work at the department • Degree work «Informational and analyticalware for assessingthe state of the aquatic environment (Northern Dvina River)» • Degree work «Optimizing physical-chemical treatment system of metal processing industries (“Volkswagen” plant)» • Joint course work «Evaluating influence of chemical wood processing enterprises at natural aquatic environment (Northern Dvina River)»

  15. Department of theoretical and applied chemistryProposals. Student exchange • Maximal amount of students for degree work practice – 3 • (-) accommodation • (-) stipendium • (+) university library • (+) computer • (+) Russian language courses • 2nd term (February-March) • Working out individual working plan, approved by both tutors (Russian and Home university tutor) • Following items are mentioned at the individual working plan: aims and tasks, main results and indicators, terms • Upholding degree work – at home university, department representatives are entering degree work committee

  16. Department of theoretical and applied chemistryResearch areas. Proposals !!!►Ecological monitoring, ecological and analytical assessment of landfills/dumps state Decision of VI conference on environmental objects analysis “Analytical chemistry of environmental objects – 2006”: Implementing ecological and analytical methods of landfills’ environmental impact assessment within city agglomeration

  17. Solid communal waste. Problems • Insufficient attention, paid up to the problem of waste producing and utilizing • Constantincreasing of waste quantity • Producing solid communal waste, mainly within city agglomerations • Differentsolid communal waste composition • International problem, mainly within border territories • Annual solid communal waste producing in Russia is 30-40 million of tones (260-280 kg/yearper 1 person or 1,4-1,5 m3/year per 1 person)

  18. Solid communal waste . Problems • Administrative • Organizing solid communal waste collection • Legislation • (-) landfills; • (+) dumps. • Technical • (-) solid communal waste sorting→ (-) solid communal waste recycling → solid communal waste are coming to landfills • Recycling technology • Ecological and analytical • Evaluating impact on environmental objects • Recycling technology control • Control of and proposals on waste utilizing ►►Urgency for Northern and North-Western cities of Russia • Geographical position • Climate • Remotenesness • Social and economical conditions • (-) area for arranging landfills

  19. Specific properties of solid communal waste • Consolidation (ability to produce leachate without the impact from outside). !!!►200 liters of leachate are produced under the natural consolidation of 1 tone of solid communal waste . • Causing corrosion effect (caused by high humidity and presence of different salt solutions in the leachate) • Abrasive effect (Caused by hard fractions of solid communal waste cause) • High concentration ofcarbon-bearing materials (paper, polyethylene, plastic) • Differentchemical composition

  20. Landfills. Dangerous effects Landfills pollute following environmental objects: • Air • Soil • Plants • Surface water • Underground water

  21. Waste processing system Aim: Modernization ofwaste processing system Tasks: 1). Modernizing waste collecting, sorting and recycling systems 2). Changing waste processing legislation 3). Ecological and analytical monitoring landfills’ state and assessing their environmental impact !!!►Being added to modernizationof waste processing system, assessing and monitoring landfills’ state is one of the most important parts of the WASTE PROBLEM

  22. Баренц Евро-арктический регион • European North, 40 %of territory – behind Polar Circle • Standard for solid communal waste production is • 1,2 m3/yearper 1 person (Arkhangelsk)

  23. Условные обозначения • - landfill • - surface water monitoring points • - underground water monitoring points Underground water monitoring

  24. Chemical and analytical controlSurface and underground water

  25. ResultsPresenting research results 0,5 m 1,5 m 2,5 m

  26. Landfill’s underground water state. Conclusion • Arkhangelsk landfill is a powerful polluter of underground water • Significant polluters’ MPC exceeding has been discovered mercury (1,5 MPC), dry residue (4 MPC), COD (520 MPC), ammonium ion (263 MPC), potassium (7,5 MPC), магния (до 2,1 ПДК), кальция (до 20 ПДК), chloride ion (12 MPC), bromide ion (36 MPC), iron (50 MC), oil products (35MPC). !!!►Being taken further out of the landfill site, underground water samples contain less pollutants due to peat soil sorption ability • Probably, surface water is polluted due to migration of pollutants with underground water flow

  27. Параметры эколого-аналитического контроляFinnish experience. Russko

  28. Параметры эколого-аналитического контроляFinnish experience. Russko

  29. Параметры эколого-аналитического контроляFinnish experience. Russko

  30. Automatic ecological and analytical control system !!! ► Automaticsystem of ecological and analytical control of environmental objects is necessary for: • Effective control of the environment state • Operativecontrol of the environment state • Making decisionson-line • Improving situationon-line

  31. Department of theoretical and applied chemistryResearch. Proposals • Researching sorption and chemical properties of soils. Finding out the nature and ways of chemical interreacting • Neighboring territories • Commonclimatic and hydro-geological conditions • Peat soils • Comparing priority indicesof environmental objects’ state • Unifying methods of analytical control • Working out and implementing principles of ecological monitoring and peculiarities of creating such systems for every unique objects.

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