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Understanding Periodic Trends in Atomic Size, Ions, and Ionization Energy

Explore the relationships in atomic size, ion formation, and ionization energy among elements. Learn how properties vary across the periodic table, from atomic radius to ionization energy.

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Understanding Periodic Trends in Atomic Size, Ions, and Ionization Energy

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  1. Periodic Trends 6.3

  2. 6.3 Periodic Trends • Sodium chloride (table salt) produced the geometric pattern in the photograph. Such a pattern can be used to calculate the position of nuclei in a solid. You will learn how properties such as atomic size are related to the location of elements in the periodic table.

  3. 6.3 Trends in Atomic Size • Trends in Atomic Size • What are the trends among the elements for atomic size?

  4. 6.3 Trends in Atomic Size • The atomic radius is one half of the distance between the nuclei of two atoms of the same element when the atoms are joined.

  5. 6.3 Trends in Atomic Size • Group and Periodic Trends in Atomic Size • In general, atomic size increases from top to bottom within a group and decreases from left to right across a period.

  6. 6.3 Trends in Atomic Size

  7. 6.3 Trends in Atomic Size

  8. 6.3 Ions • Ions • How do ions form?

  9. 6.3 Ions • Positive and negative ions form when electrons are transferred between atoms.

  10. 6.3 Ions • Positive and negative ions form when electrons are transferred between atoms.

  11. 6.3 Ions • Some compounds are composed of particles called ions. • An ion is an atom or group of atoms that has a positive or negative charge. • A cation is an ion with a positive charge. • An anion is an ion with a negative charge.

  12. Ions • Animation 7 • Discover the ways that atoms of elements combine to form compounds.

  13. 6.3 Trends in Ionization Energy • Trends in Ionization Energy • What are the trends among the elements for first ionization energy, ionic size, and electronegativity?

  14. 6.3 Trends in Ionization Energy • The energy required to remove an electron from an atom is called ionization energy. • The energy required to remove the first electron from an atom is called the first ionization energy. • The energy required to remove an electron from an ion with a 1+ charge is called the second ionization energy.

  15. 6.3 Trends in Ionization Energy • Group and Periodic Trends in Ionization Energy • First ionization energy tends to decrease from top to bottom within a group and increase from left to right across a period.

  16. 6.3 Trends in Ionization Energy

  17. 6.3 Trends in Ionization Energy

  18. 6.3 Trends in Ionization Energy

  19. 6.3 Trends in Ionic Size • Trends in Ionic Size • During reactions between metals and nonmetals, metal atoms tend to lose electrons, and nonmetal atoms tend to gain electrons. The transfer has a predictable effect on the size of the ions that form.

  20. 6.3 Trends in Ionic Size • Cations are always smaller than the atoms from which they form. • Anions are always larger than the atoms from which they form.

  21. 6.3 Trends in Ionic Size • Relative Sizes of Some Atoms and Ions • Measured in Picometers

  22. 6.3 Trends in Ionic Size • Trends in Ionic Size Size generally increases

  23. 6.3 Trends in Electronegativity • Trends in Electronegativity • Electronegativity is the ability of an atom of an element to attract electrons when the atom is in a compound. • In general, electronegativity values decrease from top to bottom within a group. For representative elements, the values tend to increase from left to right across a period.

  24. 6.3 Trends in Electronegativity • Representative Elements in Groups 1A through 7A

  25. 6.3 Summary of Trends • Summary of Trends • What is the underlying cause of periodic trends?

  26. 6.3 Summary of Trends • The trends that exist among these properties can be explained by variations in atomic structure.

  27. 6.3 Summary of Trends Atomic Size Size of cations Shielding Electronegativity Size of anions Nuclear Charge Ionization energy Increases Decreases Constant Ionic size Decreases Increases

  28. Section Assessment • 6.3

  29. 6.3 Section Quiz • 1. Which of the following sequences is correct for atomic size? • Mg > Al > S • Li > Na > K • F > N > B • F > Cl > Br

  30. 6.3 Section Quiz • 2. Metals tend to • gain electrons to form cations. • gain electrons to form anions. • lose electrons to form anions. • lose electrons to form cations.

  31. 6.3 Section Quiz • 3. Which of the following is the most electronegative? • Cl • Se • Na • I

  32. END OF SHOW

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