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Acids & Bases . Important Aqueous Solutions. NC Essential Standards. 3.2.1 Classify substances using the hydronium and hydroxide concentrations Distinguish between acids and bases based on formula and chemical properties
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Acids & Bases Important Aqueous Solutions
NC Essential Standards • 3.2.1 Classify substances using the hydronium and hydroxide concentrations • Distinguish between acids and bases based on formula and chemical properties • Differentiate between concentration (molarity) and strength (degree of dissociation) • Use pH to identify acids and bases. • Interpret pH scale in terms of the exponential nature of pH values in terms of concentrations. • Relate the color of indicator to pH using ranges provided in a table. • Compute pH, pOH, [H⁺] and [OH⁻] • 3.2.2 Distinguish properties of acids and bases related to taste, touch, reaction with metals, electrical conductivity, and identification with indicators such as litmus paper and phenolphthalein.
Overview of Key Concepts • http://ed.ted.com/on/j4JlNr0Y#watch • Introduction 5 minutes
Properties of acids and bases • http://ed.ted.com/lessons/the-strengths-and-weaknesses-of-acids-and-bases-george-zaidan-and-charles-morton Notes: Make 4 columns to easily jot down notes from the video • Acid propertiesBase properties Examples: StrongWeak Distinguish properties of acids and bases related to taste, touch, reaction with metals, electrical conductivity, and identification with indicators such as litmus paper and phenolphthalein. Note: Think H+ ions when protons are used.
Review: Names and Formulas • Common acids that you must know • All are dissolved in water (aqueous solutions) • HCl • HBr • HF • HNO₃ • H₂SO₄ • HC₂H₃O₂ • H₂CO₃ • H₃PO₄
Review: Names and Formulas • Common bases that you must know: • NaOH • Mg(OH)₂ • NH₃
Acid & Base demonstrations • http://www.youtube.com/watch?v=ti_E2ZKZpC4 • Introduction - properties (5 minutes) • http://ed.ted.com/on/j4JlNr0Y
Arrenhius Definition of Acids and Bases • Acids release H⁺ ion • Also known as hydronium ions (H₃O⁺) • Bases release OH⁻¹ (hydroxide) ions • Other definitions: • Bronsted Lowery • Lewis
pH scale • pH values • pH = - log [H⁺]
pH Scale Neutral ⇓
Ions in Solutions Neutral [H⁺] [OH⁻] In water: [H⁺]= [ OH⁻] pH = 7 pOH = 7
pOH Scale Neutral ⇓ Chemistry Reference Tables pH + pOH = 14
pH Scale • http://www.johnkyrk.com/pH.html
pH indicators • What is the approximate pH of the solution tested in the picture? Is the solution an acid or a base? Is it strong or weak?
pH Indicators Litmus Paper Phenolphthalein Blue - indicates base Red - indicates acid
pH Indicators - different indicators for different purposesScientist choose indicators based on the solution and process to be monitored.
Universal Indicator Bromothymol Blue Acid = yellow Neutral = green Base = blue
Strength of Acids and Bases • http://ed.ted.com/lessons/the-strengths-and-weaknesses-of-acids-and-bases-george-zaidan-and-charles-morton • 4 minutes • Write notes:
Concentration⇎ Strength • Concentrated or dilute - Molarity • 6M vs. 0.6 M Strength or weak = degree to which acids or bases separate into ions
Strength vs. Concentration • Strength in acids • Based on degree H⁺ ions separate from the anion • Proportion of acid molecules in which H⁺ separate compared to how many acid molecules do not separate • Strong acids = most H⁺ separate • Examples: HCl, HNO₃ and H₂SO₄ • Weak acids = only some H⁺ separate • Examples: HF, HC₂H₃O₂ • Strength of Bases • Strong = most OH⁻ separate from the metal
Reacting acids and bases • HCl (aq) + Na(OH) (aq) → HOH + NaCl • Write the word formula • Identify the type of chemical reaction • What is happening with the reactants and products? • Ionic equation: • Solubility rules:
Neutralization reactions • Special double replacement reaction • Always: • Reactants: Acid + Base (any order) • Products: Salt (ionic compound) + Water • Practice: • sulfuric acid and calcium hydroxide
Neutralization reactions • Acid + Base → Salt + Water • sulfuric acid and calcium hydroxide • potassium hydroxide and nitric acid • carbonic acid and magnesium hydroxide • hydrobromic acid and lithium hydroxide
Salts formed in the previous problems sulfuric acid and calcium hydroxide salt name: calcium sulfate salt formula: CaSO4 potassium hydroxide and nitric acid salt name: potassium nitrate salt formula: KNO3 carbonic acid and magnesium hydroxide salt name: magnesium carbonate salt formula: MgCO3 hydrobromicacid and lithium hydroxide salt name: lithium bromide salt formula: LiBr