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由重排反应构建季碳. 魏强 2010.9.25. Claisen 重排. Claisen L. Chem. Ber. 1912 , 45 , 3157 Enders D. Tetrahedron Asym. 1996 , 7, 1847. Hajiwara H. J. Chem. Soc., Perkin Trans. 1 2002 , 583. Eschenmoser-Claisen 重排. Eschenmoser A. Helv. Chim. Acta 1964 , 47 , 2425. Johnson-Claisen 重排.
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由重排反应构建季碳 魏强 2010.9.25
Claisen 重排 Claisen L. Chem. Ber. 1912, 45, 3157 Enders D. Tetrahedron Asym. 1996, 7, 1847
Eschenmoser-Claisen 重排 Eschenmoser A. Helv. Chim. Acta 1964, 47, 2425 Johnson-Claisen 重排 Johnson W. S. J. Am. Chem. Soc.1970, 92, 741 Ireland-Claisen 重排 Ireland R. E. J. Am. Chem. Soc. 1972, 94, 5897
Loh T. P. Org. Lett.2001, 3, 279 Dethe D. H. Org. Lett.2003, 5, 2295 Corey E. J. J. Am. Chem. Soc.1999, 121, 6771
Corey E. J. J. Am. Chem. Soc.1995, 117, 193 Corey E. J. J. Am. Chem. Soc.1996, 118, 1229
Kozlowski M. C. J. Am. Chem. Soc. 2008, 130, 16162 Nelson S. G. J. Am. Chem. Soc. 2010, 132, 11875
Cope 重排 Cope A. C. J. Am. Chem. Soc. 1940, 62, 441 Cope A. C. J. Am. Chem. Soc. 1941, 63, 1843 Cope A. C. J. Am. Chem. Soc. 1941, 63, 1852 Cope A. C. J. Am. Chem. Soc. 1944, 66, 1684 Zalkow L. H. J. Org. Chem. 1965, 30, 4205 Evans D. A. J. Am. Chem. Soc. 1975, 97, 4765
Overman 重排 Overman L.E. J. Am. Chem. Soc. 1974, 96, 597
Wittig 重排 Hodgson D. M. et al, Top. Organomet. Chem.2003, 5, 217-250 Vogel C. Synthesis1997, 497
Semipinacol 重排 Fuji K. Chem. Rev. 1993, 93, 2037 Tu Y.-Q. Angew. Chem. Int. Ed. 2009, 48, 8572