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Resonant SERS and electronic excitation. Ordinary infrared Raman involves only excitations in the electronic ground state In order to get to the excited state one needs more energy. Resonant SERS. To go to the electronic excited states one will have to utilize resonant SERS, SERRS
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Resonant SERS and electronic excitation • Ordinary infrared Raman involves only excitations in the electronic ground state • In order to get to the excited state one needs more energy
Resonant SERS • To go to the electronic excited states one will have to utilize resonant SERS, SERRS • Else one will have to go to ultraviolet lasers
Altered SERS • An interesting possibility is to consider: • Charge transfer from the nano particles • Changing the structure of the nano particles • Apply fields to the nano particles • Polarization and fusion effects with microwaves
SERS-CT • Charge transfer enhancement mechanism of SERS (SERS-CT) is still controversial • The CT-mechanism is complicated • The mechanism consists of a charge transferred from excited states to radical anions