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Kinetics and mechanism of thermal degradation of Zn(II) complex with N - benzyloxycarbonyl glycinato ligand. Maja Šumar - Ristovi ć a , Vlada Blagojević b , Maja Gruden -Pavlović a , Katarina Anđelković a , Dejan Poleti c , Dragica M . Minić b a Faculty of Chemistry,
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Kinetics and mechanism of thermal degradation of Zn(II) complex with N-benzyloxycarbonylglycinatoligand MajaŠumar-Ristovića, VladaBlagojević b, MajaGruden-Pavlovića, Katarina Anđelkovića, Dejan Poletic, Dragica M.Minićb aFaculty of Chemistry, University of Belgrade, Serbia bFaculty of Physical Chemistry, University of Belgrade, Serbia cFacultyof Technology and Metallurgy, University of Belgrade, Serbia Thermal Stability Kinetics and Mechanism Changesof the activationenergies withconversion degree indicatecomplex processes involving more than one step First Principle Calculations The most stable conformation of starting complex (Ea = 714 kJ/mol) Calculated enthalpies changes indicate one step decomposition of intermediate. Calculated Ea of intermediate [Zn(OOCCH2NHC·O)2] is 458 kJ/mol.