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Lecture 6. Adiabatic Processes. Definition. Process is adiabatic if there is no exchange of heat between system and environment, i.e., dq = 0. Work and Temperature (General). First law: dU = dQ – dW Adiabatic process: dU = -dW If system does work (dW > 0), dU < 0 system cools
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Lecture 6 Adiabatic Processes
Definition • Process is adiabatic if there is no exchange of heat between system and environment, i.e., dq = 0
Work and Temperature (General) • First law: dU = dQ – dW • Adiabatic process: dU = -dW • If system does work (dW > 0), dU < 0 system cools • If work is done on system (dW < 0), dU > 0 system warms
Work and Temperature (Ideal Gas) • Adiabatic process: cvdT = - pd • Expansion (d > 0) dT < 0 (cooling) • Contraction (d < 0) dT > 0 (warming)
Relationship between T and p [Eq. (4) from last lecture.] dq = 0 But,
Adiabatic Transition • Suppose system starts in state with thermodynamic “coordinates” (T0, p0) • System makes an adiabatic transition to state with coordinates (T1, p1)
Integrate (1)
Continue (1) (2)
Thus, (2)becomes (3)
Thus, • (3) becomes (4) Poisson’s Equation
Dry Air
Exercise • p0 = 989 hPa • T0 = 276 K • p1 = 742 hPa • T1 = ? • Answer: T1 = 254 K
Exercise • p0 = 503 hPa • T0 = 230 K • p1 = 1000 hPa • T1 = ? • Answer: 280 K
Potential Temperature • Let p0 = 1000 hPa • Remove the subscripts from p1 and T1 • Denote T0 by is called the potential temperature
Physical Meaning • Initial state: (T, p) • Suppose system makes an adiabatic transition to pressure of 1000 hPa • New temperature = • Potential temperature is the temperature a parcel would have if it were to expand or compress adiabatically from its present pressure and temperature to a reference pressure level. Po = 1000 mb.
Physical Meaning • Removes adiabatic temperature changes experienced during vertical motion • ºC and K are interchangeable; best to convert it to K when making calculations such as differences. • is invariant along an adiabatic path • adiabatic behavior of individual air parcels is a good approximation for many atmospheric applications…from small parcels to larger convection.
Adiabats • Let be given • Re-write last equation: In the T-p plane, this describes a curve. Curve is called a dry adiabat.
= 290 K Initial state: T = 290.0 K, p = 1000 hPa
Reduce pressure to 900 hPa New temperature: T 281 K
Exercise • Calculate T to nearest tenth of a degree
Reduce pressure to 700 hPa New temperature: T 262 K
Exercise • Calculate new T to nearest tenth of a degree • Answer: 261.9 K
Adiabatic Processes • In the T-p plane, an adiabatic process can be thought of as a point moving along an adiabat.
The Parcel Model • An air parcel is a hypothetical volume of air that does not mix with its surroundings • Parcel is a closed system. • Parcel moves adiabatically if there is no exchange of heat with surroundings. • 1 and 2 parcel is isolated • Parcel doesn’t interact with surroundings.
Rising & Sinking Parcels • If a parcel rises adiabatically, its pressure decreases parcel cools • If a parcel sinks adiabatically, its pressure increases parcel warms
Movie: “The Day After Tomorrow” • Premise: global warming produces gigantic storms • In these storms, cold air from upper troposphere is brought down to surface, causing sudden cooling • (People freeze in their tracks!)
Problem With Premise • As air sinks, it WARMS! • Suppose air at height of 10 km sinks rapidly to surface • Pressure at 10 km 260 hPa • Temperature 220 K • If surface pressure 1000 hPa, what is air temperature upon reaching surface?
Height Dependence of T Start with *
Parcel Temperature • Consider a parcel with pressure p and temperature T. • Assume the parcel rises adiabatically is constant • Goal: Determine dT/dz. • Method: logarithmic differentiation
Step 1 • Take log of both sides of * Constants
Step 3: Hydrostatic Equation Substitute into **
Step 4
Exercise • Simplify the expression for dT/dz.