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Swager Lab explores novel applications of conjugated polymers as conductors, sensors, amplifiers, actuators, and catalysts. They focus on new sensory methods, self-organizing systems, and molecular architectures to enhance performance and functionality. Challenges such as stability, shape persistence, and functional group flexibility are addressed through innovative designs. The synthesis of conductive polymers within an iptycene scaffold shows promise for improved insulation and performance.
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N Conjugated Polymers as Conductors, Sensors, Amplifiers, Actuators, and CatalystsSwager Lab • New Sensory Methods: Signal • Amplification From Receptors • “Wired in Series” • Conducting Metallopolymers: New Sensors and Catalysts • Self-Organizing Systems:Liquid Crystal and Molecular Recognition Directed Assembly • New Molecular Architectures: Polymers Designed to Couple Volume or shape Changes and Chemical Potential
W Single Strand Conducting Molecular Wire • Challenges • Flexibility of Functional Groups Modification • Stability • Shape and Length Persistence
W Alternative : InsulatedWires with Switching Elements
Structure of Three-Strand Conducting Polymetallorotaxane Central Chain Is Isolated
Second Generation Polymetallorotaxane ( n ( • Improvement • Larger Stopper means Better Insulation • Rigid Structure, no De-threading • Solubility
Synthesis of Conductive Polymers within an Iptycene Scaffold •The rigid iptycene framework will serve to insulate the polymer