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Chapter 7: Reactions in Aqueous Solutions. Will Learn About. (1) Driving forces behind chemical reactions (2) 3 Ways to write chemical reactions in aqueous solutions (3) Acid – bases Reactions (4) Oxidation – reduction reactions ( Redox ) (5) Classification of chemical reactions.
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Will Learn About (1) Driving forces behind chemical reactions (2) 3 Ways to write chemical reactions in aqueous solutions (3) Acid – bases Reactions (4) Oxidation – reduction reactions (Redox) (5) Classification of chemical reactions
Four Driving Forces Favor Chemical Change • Formation of a solid= precipitation • Formation of water = acid-base reaction • Transfer of electrons = oxidation-reduction reaction • Formation of a gas
Precipitation Reactions • Formation of solid product(s) from ions • solution with 100% ions = strong electrolyte (conduct electricity well) • solution with less than 100% but more than 0% ions = weak electrolyte (conduct electricity somewhat) • solution with 0% ions = nonelectrolyte (conduct no electricity)
Solubility Rules • Deciding if soluble or insoluble product will form • When the rules contradict, go with the soluble (Ex) Na2CO3 soluble b/c all Na+ soluble
Examples • Soluble or insoluble? 1) NaNO3 (aq) 2) CaSO4 (aq) 3) AgCl (aq) 4) KOH (aq) 5) Pb(OH)2 (aq)
Writing Chem Equations of Aqueous Reactions • Molecular equation: Write all reactants and products as insoluble formula units 2) Ionic equation: Write soluble compounds as ions and insoluble compounds as formula units 3) Net-ionic equation: Remove the spectator ions from the ionic equation
Molecular Equations (Ex) Mg(NO3)2+ 2NaOH 2NaNO3 + Mg(OH)2 (Ex) K2SO4 + 2HCl 2KCl + H2SO4
Ionic Equations Molecular: Mg(NO3)2 + 2NaOH 2NaNO3 + Mg(OH)2 Ionic: Mg2+ + 2NO3– + 2Na+ + 2OH– 2Na+ + 2NO3– + Mg(OH)2 Molecular: K2SO4 + 2HCl 2KCl + H2SO4 Ionic: 2K+ + SO42 + 2H+ + 2Cl– 2K+ + SO42 + 2H+ + 2Cl–
Net Ionic Equations Molecular: Mg(NO3)2 + 2NaOH 2NaNO3 + Mg(OH)2 Ionic: Mg2+ + 2NO3– + 2Na+ + 2OH– 2Na+ + 2NO3– + Mg(OH)2 Net ionic:Mg2++ 2OH– Mg(OH)2 Molecular: K2SO4 + 2HCl 2KCl + H2SO4 Ionic: 2K+ + SO42 + 2H+ + 2Cl– 2K+ + SO42 + 2H+ + 2Cl– Net ionic: 2K+ + SO42 + 2H+ + 2Cl– No reaction
Example A sodium phosphate solution reacts with a lead(II) nitrate solution. What precipitate, if any, will form? • Write the molecular equation. • Write the ionic equation. • Write the net ionic equation.
Acid-Base Reaction • Acids: contain H+ ions • Strong acids form strong electrolytes: HCl, HBr, HI, HNO3, H2SO4, HClO3, HClO4 • Weak acids form weak electrolytes • Nonmetal dissolved in water acidic solution (Ex) SO2 + H2O H2SO3 • Bases: contain OH–ions • Strong bases form strong electrolytes: 1A + OH, Ba(OH)2, Ca(OH)2, Sr(OH)2 • Acid-base reaction requires at least one strong • Weak acid and weak base don’t produce products • Always two products: water and salt • Metal dissolved in water basic solution (Ex) 2Na + 2H2O H2 + 2NaOH
Oxidation-Reduction Reaction(RedoxRxn) • A reaction that involves a transfer of electrons. • 2Mg(s) + O2(g) 2MgO(s)
Types of Reactions • Why need to know the type of reaction? • Help you figure out the products • Types of reactions • combustion • synthesis • decomposition • single displacement • double displacement • acid-base reaction • Oxidation-reduction
Types of Chemical Reaction 1. Combustion Reaction a) Called as burning b) Combining with oxygen gas c) Combustion of hydrocarbon compoundsproduce CO2 and H2O. (Ex) 2CH3OH + 3O2 2CO2 + 4H2O d) Combustion of elements form binary oxide compounds (Ex) 4Fe + 3O2 2Fe2O3 N2+ 2O2 2NO2
2. Synthesis (Combination) a) Two or more elements or compounds combine to form a single compound. b) Combustion of elements is also synthesis. (Ex) 4Al + 3O2 2Al2O3 (Ex) 2K + Cl2 2KCl
3. Decomposition a) The exact opposite process of synthesis b) A compound decomposes to elements or simpler compounds (Ex) 2NaCl 2Na + Cl2 (Ex) CaCO3 CaO + CO2
4. Single Displacement • An element displaces a similar element in a compound; metal replaces metal (cationic)and nonmetal replaces nonmetal (anionic). • The element displaces less reactive element in the compound. *If the element in the compound is more reactive, no reaction occurs (Ex) 2NaCl + F2 2NaF + Cl2
5. Double Displacement a) Two compounds react and produce two different compounds b) Swap the cationsOR the anions – Do not swap both cations and anions (Ex) 2KBr + CaO CaBr2 + K2O