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Methane and Landfills. Aren't we recycling most of the paper that we throw away?Why are Landfills anaerobic?Methane ExperimentMeasure the methane production from various landfill components under various conditionsCompare the energy value of the methane with the energy value of the original wast
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1. Biodegradation in Landfills:Methane Production
2. Methane and Landfills Arent we recycling most of the paper that we throw away?
Why are Landfills anaerobic?
Methane Experiment
Measure the methane production from various landfill components under various conditions
Compare the energy value of the methane with the energy value of the original waste
Issues... pH, pressure monitoring, inoculum
3. Solid Waste Composition in 1994as Generated (US averages)
4. Landfills... Will continue to be the disposal option of choice
Require long term monitoring
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Why does gas production continue long term?
Why is much organic matter preserved?
5. Why are Landfills anaerobic?
Why are landfills warm? (Average temperature of Fresh Kills Landfill is 29.4 °C)
Follow carbon flow... Methane Production
6. Cap System
7. Experiment Setup
8. pH control... High partial pressure of CO2 ? ____ pH
Anaerobes require a pH between 6.5 and 7.5
Remember ANC...
Volatile or Non-volatile system?
9. How much ANC do we need?
10. ANC Problem How much ANC is needed to maintain a neutral pH if the pressure is atmospheric and the CO2 fraction is 30%?
11. ANC Problem If serum bottles have that much ANC what will the pH be if the CO2 pressure doubles?
12. Inoculum We need a few good anaerobes...
Where could we recruit?
How do we choose inoculum size?
13. Sample Size What happens if you put ź of a graham cracker into a 120 mL serum bottle with 60 mL of water and some inoculum and seal it?
Estimate mass of carbohydrates at 4 grams
Moles of carbohydrates 30 g/mole _____
0.133 moles C
14. Samples for Analysis Bring 1 sample per person for methane production
Ideas
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15. Pressure Sensors Transduce pressure into a voltage!
Use Strain Gages
Design of piezoresistive strain gages
Sensor output
Signal Conditioning
Calibration
16. Strain gage What happens to the resistance thru the strain gage if it is stretched
in the y direction? ________________
In the x direction? ________________
Strain gage can be made of wire that is then bonded to the objected that is undergoing strain
Or diffused into a crystalline silicon diaphragm (___________)
17. Piezoresistive Diaphragms
18. Pressure Sensor Failure High pressures rupture crystal (beware of resulting leak!)
Water hammer
High speed pressure waves (speed of sound)
Result from flow transients such as rapidly shutting valves
Install pressure snubber!
Incompatible materials
19. Absolute vs. Gage vs. Differential Absolute
Port 2 sealed with vacuum on bottom side of silicon crystal
Gage
Port 2 open to atmosphere
Differential
Both ports connected to system
20. Pressure Sensor Applications Many!
Level monitoring of municipal water tanks
Gas tank gage
Various flow meter devices (orifice, Venturi)
Stream gage (USGS)
Instrumentation (Gas and Liquid Chromatographs)
21. Pressure Sensor Signal Conditioning Full scale voltage output from the bridge circuit may be in the range of 10 to 100 mV.
This low voltage may need amplification before being measured by a data acquisition system
Limit cable length and beware of noise from power cables!
Time average to reduce noise
22. Pressure Sensor Calibration Sensor output should be linear
Calibration involves determining the slope and intercept
Subtract the voltage obtained under conditions of zero pressure (offset) to get an intercept of zero
The slope can be determined by applying different pressures to the sensor and measuring the resulting voltages
Multiply the remaining voltage by the slope
23. Pressure Sensors Summary Based on a small change in resistance due to a change in dimension (strain gage)
Commonly used to monitor industrial and environmental processes
Easily monitored using data acquisition systems
24. Pressure Complications
Pressurized serum bottle
Placed in incubator and monitored
Why does pressure increase initially?________________
What are the short term fluctuations?_______________________________
What are the long term fluctuations? ____________