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Chemistry 139. Davis. Chapter 1 – Goals. Chapter 2 - Goals. Measurements Understand Uncertainty in Measurement Know, understand, and be able to apply significant figures to calculations. Know, understand, and be able to apply scientific notation to calculations. Measurement….
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Chemistry 139 Davis
Chapter 2 - Goals • Measurements • Understand Uncertainty in Measurement • Know, understand, and be able to apply significant figures to calculations. • Know, understand, and be able to apply scientific notation to calculations.
Measurement… • Defined: determination of the quantities related to an object. • Dimensions • Volumes • Time • Etc… • Requires that someone actually
I’m certainly uncertain… • Two terms: • Exact numbers – • Exactly • Exactly • Exactly _____ desks in this room. • Inexact numbers – • Flaws in • Uncalibrated • User
Accuracy and Precision • Defined • Precision –
Accuracy – Volume measurements for a titration: Trial 1 = 25.5 mL Trial 2 = 25.6 mL Trial 3 = 25.5 mL
Sample data • Mass readings for a magnesium sample: Evaluate these measurements for precision and accuracy
From the book: • Two teams of three students count birds sitting on a power line. Team counts are: The actual count was 76 birds. Who was most accurate? Which team was most accurate? Which team’s count was most precise?
Uncertainty in Measurement • Why are digits in measurements uncertain? • Instruments • Differences • Always involves estimation • Choose the right instrument for the job • Volumetric vs ‘to hold’ glassware • May be estimated for you (electronic scales) • Scale is marked but you estimate the in-between
Measurements • MUST Which is correct?
Significant Figures (Digits)… • Method to deal with • All digits known
What Sig Figs mean… • All KNOWN numbers 15023.557
Significant Digits • The Rules – Memorize these. • All non-zeros are • A zero is significant when : • It is • It is • A zero is not significant when: • It is • It is at
Significant Digits - PRACTICE How many significant digits? • 54.23 • 23.00005 • 0.0004 • 35000 • 0.000504 • 45.623200 • 5,000,000 • 4,000,000.1
Calculations with Significant Figures • Add/subtract – • Multiply/divide – • Only round after problem is complete
Practice Add/Subtract 122.53 + 6.448 + 145.3 274.278
Significant Digits - Calculations • Addition and Subtraction • Round answer to have final digit in the SAME PLACE as the last digit in the LEAST ACCURATE MEASUREMENT • 1.21 + 5.002 + 10. = • 34.5 + 12.45 + 23.0505 = • 186.31 + 11.1 = • 12.0231 + 3.86 = • 0.100012 + 120. = • 1200 + 12 + 15 + 0.5 =
Significant Digits - Calculations • Multiplication and Division • The answer has as many sig figs as the number with the fewest sig figs • 14.8 x 3.1 = • 18.2 x 3.0 = • 52/1.5 = • 321.868783 x 1 = • 2400 x 2.123 = • 15000/12.354 =
Practice Multiply/Divde 452.11 x 78.5 = 35490.635
Practice 1524.57 / 32.15 = 47.4205287714
Significant Figures and Exact Numbers • Exact numbers are never used to determine the number of significant figures to report in your answer. 6.25 ft * 1 mile = 0.00118371212 mile 5280 ft
Scientific Notation • Convenient way of writing very large or very small numbers and showing only significant figures • Number between • 5120 becomes • Move decimal point in original number to make number 1-10 • Move left = • Move right =
Scientific Notation Practice • 123,000 = • 0.000045 = • 23.45 = • 0.0000000003 = • 1,000,000 =
Scientific Notation and Significant Figures • Express the number 275,364,145 with: • 4 sig fig: • 2 sig fig: • 6 sig fig:
Scientific Notation • Math with: • Use the EE or EXP button on your calculator. • For example: