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Principles of Fire Behavior. Additional information for MINA. What is Fire?. An uncontrolled chemical reaction producing light and energy sufficient to damage skin Also identified as combustion – a chemical reaction involving fuel and an oxidizer in the air Think kilowatts.
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Principles of Fire Behavior Additional information for MINA
What is Fire? • An uncontrolled chemical reaction producing light and energy sufficient to damage skin • Also identified as combustion – a chemical reaction involving fuel and an oxidizer in the air • Think kilowatts
Natural Causes of Fire • Lightning • Extreme weather • Earthquake
Man Made Causes • Open flames • Explosive environments • Inattention • Chemical reactions
Types of Fires • Diffusion flames • Smoldering • Spontaneous combustion • Premixed flames
Diffusion Flames • A combustion process in which the fuel gas and oxygen are transported into the reaction zone due to concentration differences – Fick’s Law • Move from high to low concentration in the mixture • Natural flaming fires are diffusion flames • Match or candle
Diffusion Flames • Terms identifying diffusion flames • Pyrolysis – decomposition process as in wood • Laminar – pure molecular diffusion as in a candle • Buoyancy – gravity or lack of gravity with hotter or lighter gases • Jet flame – high pressure created by gaseous fuel sources
Smoldering • Slow combustion process • Charring - >1000 degrees • Solid fuel source • Produces deadly levels of carbon monoxide • Examples • Cigar • Upholstered chair • Charcoal grill
Spontaneous • Begins with a slow oxidations in a fuel exposed to air • Very little heat lost • Thermal runaway • Examples • Haystacks • Sawdust bin • Oily rags piled
Premixed Flames • Mixing of fuel gas and air or oxygen • Mixed before ignition and propagation • Controlled would be jet engines and oxyacetylene torch • Uncontrolled examples • Confined space • Methane leak
Premixed Flames • Concentration limits • Gaseous fuels will ignite within limits • Upper (UFL) • Lower (LFL) – temperature just before fuel condenses to a liquid at the LFL is call the flashpoint • Autoignition temp (AIT) – lowest temp to cause spontaneous ignition
Heat Transfer • Conduction – a molecular phenomenon • Convection – conduction in a moving fluid • Radiation – an electromagnetic phenomenon • Heat Flux – the flow rate of heat – key to assessing the potential damage by a fire
Ignition • Piloted – process of initiation and flame propagation in premixed fuel systems – e.g., welding, jet engines, gas stoves • Autoignition – no spark or flame source
Ignition • Evaporation – the process of gas molecules escaping from the surface of a liquid • Humidity – higher the humidity, less evaporation in the air – lower, more • Flashpoint – temp of a liquid fuels and the LFL – point of piloted ignition • Boiling point – temp that liquid can evaporate under normal atmospheric conditions
Flame Spread • The process in which the perimeter of the fire grows • Wind aided • Opposed flow • Pyrolysis or vaporization region • Burning rate
Flame Spread • Surface flame • Downward/lateral wall spread – opposed flow flame spread • Spread through porous solid arrays – brush/debris • Spread on liquids – viscous/surface tension
Burning Rate • The mass of solid or liquid fuel consumed per unit time • Mass loss rate – the mass of fuel vaporized but not necessarily burned per unit time
Fire Plumes • Turbulent fire plumes – the flame and gases emanating from a burning object • Buoyancy – effective force on fluid due to density or temperature differences in a gravitational field • Entrainment – the process of air or gases being drawn into a fire, plume or jet
Fire Plumes • Flame height – the vertical measure of the combustion region • Pool fires • Line fires • Eddies – rotating regions of a fluid • Vortex – a ring of eddies • Flame lengths – depends on energy released
Combustion Products • Products – chemical compounds produced by fire • Yield – the mass of product produced per unit mass of fuel supplied • Concentrations – the percentage of material per unit mass (or volume) of its mixture
Concentration • The primary hazard of fire is the composition and associated concentrations of the smoke • Hazards • Vitiation – reduction in oxygen • Narcotic gases – narcosis • Irritant gases – acid, hydrocarbon byproducts • Smoke visibility • Hyperthermia – heat stress
Compartment Fires • Stages of fire development • Developing fire • Flashover • Fully developed
Compartment Flow Dynamics • Layers and vent flows • Smoke filling • Smoke movement
Fire Analysis • Fire safety design • Detection and design • Mitigation of growth and suppression • Egress • Continuity of operations • Structural integrity • Refuge and rescue
Resources • Firedynamics.com • www.campusfire.org • www.campusfiresafety.com • www.pp.okstate.edu/esh/Fire.htm • www.fpemag.com • www.ul.com
Resources • American Fire Journal • Fire House • Fire Chief • Fire Engineering • Fire Technology • USFA – Fire Data Analysis Handbook