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1. Chemistry 132 NT Instead of having “answers” on a math test, they should just call them “ impressions”, and if you got a different “impression”, so what, can’t we all be brothers?
Jack Handey
3. Acid-Base Equilibria Chapter 16
Module 3
Sections 16.5, 16.6, and 16.7
4. Review Calculating the concentration of a species in a weak base solution using Kb
5. The Common Ion Effect The common-ion effect is the shift in an ionic equilibrium caused by the addition of a solute that provides an ion common to the equilibrium.
6. The Common Ion Effect The common-ion effect is the shift in an ionic equilibrium caused by the addition of a solute that provides an ion common to the equilibrium.
7. The Common Ion Effect The common-ion effect is the shift in an ionic equilibrium caused by the addition of a solute that provides an ion common to the equilibrium.
8. The Common Ion Effect The common-ion effect is the shift in an ionic equilibrium caused by the addition of a solute that provides an ion common to the equilibrium.
9. A Problem To Consider An aqueous solution is 0.025 M in formic acid, HCH2O and 0.018 M in sodium formate, NaCH2O. What is the pH of the solution. The Ka for formic acid is 1.7 x 10-4.
10. A Problem To Consider An aqueous solution is 0.025 M in formic acid, HCH2O and 0.018 M in sodium formate, NaCH2O. What is the pH of the solution. The Ka for formic acid is 1.7 x 10-4.
11. A Problem To Consider An aqueous solution is 0.025 M in formic acid, HCH2O and 0.018 M in sodium formate, NaCH2O. What is the pH of the solution. The Ka for formic acid is 1.7 x 10-4.
12. A Problem To Consider An aqueous solution is 0.025 M in formic acid, HCH2O and 0.018 M in sodium formate, NaCH2O. What is the pH of the solution. The Ka for formic acid is 1.7 x 10-4.
13. A Problem To Consider An aqueous solution is 0.025 M in formic acid, HCH2O and 0.018 M in sodium formate, NaCH2O. What is the pH of the solution. The Ka for formic acid is 1.7 x 10-4.
14. A Problem To Consider An aqueous solution is 0.025 M in formic acid, HCH2O and 0.018 M in sodium formate, NaCH2O. What is the pH of the solution. The Ka for formic acid is 1.7 x 10-4.
15. A Problem To Consider An aqueous solution is 0.025 M in formic acid, HCH2O and 0.018 M in sodium formate, NaCH2O. What is the pH of the solution. The Ka for formic acid is 1.7 x 10-4.
16. A Problem To Consider An aqueous solution is 0.025 M in formic acid, HCH2O and 0.018 M in sodium formate, NaCH2O. What is the pH of the solution. The Ka for formic acid is 1.7 x 10-4.
17. Buffers A buffer is a solution characterized by the ability to resist changes in pH when limited amounts of acid or base are added to it.
18. Buffers A buffer is a solution characterized by the ability to resist changes in pH when limited amounts of acid or base are added to it.
19. Buffers A buffer is a solution characterized by the ability to resist changes in pH when limited amounts of acid or base are added to it.
20. Buffers A buffer is a solution characterized by the ability to resist changes in pH when limited amounts of acid or base are added to it.
21. The pH of a Buffer The solution described in Example 16.10 in your text is a buffer, because it is composed of a weak acid (0.10 M acetic acid) and its conjugate base (0.20 M acetate ion).
22. A Problem To Consider Instructions for making up a buffer say to mix 60.0 mL of 0.100 M NH3 with 40.0 mL of 0.100 M NH4Cl. What is the pH of this buffer?
23. A Problem To Consider Instructions for making up a buffer say to mix 60.0 mL of 0.100 M NH3 with 40.0 mL of 0.100 M NH4Cl. What is the pH of this buffer?
24. A Problem To Consider Instructions for making up a buffer say to mix 60.0 mL of 0.100 M NH3 with 40.0 mL of 0.100 M NH4Cl. What is the pH of this buffer?
25. A Problem To Consider Instructions for making up a buffer say to mix 60.0 mL of 0.100 M NH3 with 40.0 mL of 0.100 M NH4Cl. What is the pH of this buffer?
26. A Problem To Consider Instructions for making up a buffer say to mix 60.0 mL of 0.100 M NH3 with 40.0 mL of 0.100 M NH4Cl. What is the pH of this buffer?
27. A Problem To Consider Instructions for making up a buffer say to mix 60.0 mL of 0.100 M NH3 with 40.0 mL of 0.100 M NH4Cl. What is the pH of this buffer?
28. A Problem To Consider Instructions for making up a buffer say to mix 60.0 mL of 0.100 M NH3 with 40.0 mL of 0.100 M NH4Cl. What is the pH of this buffer?
29. A Problem To Consider Instructions for making up a buffer say to mix 60.0 mL of 0.100 M NH3 with 40.0 mL of 0.100 M NH4Cl. What is the pH of this buffer?
30. A Problem To Consider Instructions for making up a buffer say to mix 60.0 mL of 0.100 M NH3 with 40.0 mL of 0.100 M NH4Cl. What is the pH of this buffer?
31. Adding Acid or Base to a Buffer Example 16.10 in your text describes a buffer composed of acetic acid and sodium acetate. This buffer controls the equilibrium below.
32. Adding Acid or Base to a Buffer Example 16.10 in your text describes a buffer composed of acetic acid and sodium acetate. This buffer controls the equilibrium below.
33. A Problem To Consider Calculate the pH of 75 mL of the buffer described in Example 16.10 (0.10 M HC2H3O2 and 0.20 M NaC2H3O2) to which 9.5 mL of 0.10 M HCl is added.
34. A Problem To Consider Calculate the pH of 75 mL of the buffer described in Example 16.10 (0.10 M HC2H3O2 and 0.20 M NaC2H3O2) to which 9.5 mL of 0.10 M HCl is added.
35. A Problem To Consider Calculate the pH of 75 mL of the buffer described in Example 16.10 (0.10 M HC2H3O2 and 0.20 M NaC2H3O2) to which 9.5 mL of 0.10 M HCl is added.
36. A Problem To Consider Calculate the pH of 75 mL of the buffer described in Example 16.10 (0.10 M HC2H3O2 and 0.20 M NaC2H3O2) to which 9.5 mL of 0.10 M HCl is added.
37. A Problem To Consider Calculate the pH of 75 mL of the buffer described in Example 16.10 (0.10 M HC2H3O2 and 0.20 M NaC2H3O2) to which 9.5 mL of 0.10 M HCl is added.
38. A Problem To Consider Calculate the pH of 75 mL of the buffer described in Example 16.10 (0.10 M HC2H3O2 and 0.20 M NaC2H3O2) to which 9.5 mL of 0.10 M HCl is added.
39. A Problem To Consider Calculate the pH of 75 mL of the buffer described in Example 16.10 (0.10 M HC2H3O2 and 0.20 M NaC2H3O2) to which 9.5 mL of 0.10 M HCl is added.
40. A Problem To Consider Calculate the pH of 75 mL of the buffer described in Example 16.10 (0.10 M HC2H3O2 and 0.20 M NaC2H3O2) to which 9.5 mL of 0.10 M HCl is added.
41. A Problem To Consider Calculate the pH of 75 mL of the buffer described in Example 16.10 (0.10 M HC2H3O2 and 0.20 M NaC2H3O2) to which 9.5 mL of 0.10 M HCl is added.
42. A Problem To Consider Calculate the pH of 75 mL of the buffer described in Example 16.10 (0.10 M HC2H3O2 and 0.20 M NaC2H3O2) to which 9.5 mL of 0.10 M HCl is added.
43. A Problem To Consider Calculate the pH of 75 mL of the buffer described in Example 16.10 (0.10 M HC2H3O2 and 0.20 M NaC2H3O2) to which 9.5 mL of 0.10 M HCl is added.
44. A Problem To Consider Calculate the pH of 75 mL of the buffer described in Example 16.10 (0.10 M HC2H3O2 and 0.20 M NaC2H3O2) to which 9.5 mL of 0.10 M HCl is added.
45. A Problem To Consider Calculate the pH of 75 mL of the buffer described in Example 16.10 (0.10 M HC2H3O2 and 0.20 M NaC2H3O2) to which 9.5 mL of 0.10 M HCl is added.
46. A Problem To Consider Calculate the pH of 75 mL of the buffer described in Example 16.10 (0.10 M HC2H3O2 and 0.20 M NaC2H3O2) to which 9.5 mL of 0.10 M HCl is added.
47. A Problem To Consider Calculate the pH of 75 mL of the buffer described in Example 16.10 (0.10 M HC2H3O2 and 0.20 M NaC2H3O2) to which 9.5 mL of 0.10 M HCl is added.
48. The Henderson-Hasselbalch Equation How do you prepare a buffer of given pH?
49. The Henderson-Hasselbalch Equation How do you prepare a buffer of given pH?
50. The Henderson-Hasselbalch Equation How do you prepare a buffer of given pH?
51. The Henderson-Hasselbalch Equation How do you prepare a buffer of given pH?
52. A Problem To Consider A buffer is prepared by adding 45.0 mL of 0.15 M NaF to 35.0 mL of 0.10 M HF. What is the pH of this buffer? (The Ka for HF is 6.8 x 10-4)
53. A Problem To Consider A buffer is prepared by adding 45.0 mL of 0.15 M NaF to 35.0 mL of 0.10 M HF. What is the pH of this buffer? (The Ka for HF is 6.8 x 10-4)
54. A Problem To Consider A buffer is prepared by adding 45.0 mL of 0.15 M NaF to 35.0 mL of 0.10 M HF. What is the pH of this buffer? (The Ka for HF is 6.8 x 10-4)
55. A Problem To Consider A buffer is prepared by adding 45.0 mL of 0.15 M NaF to 35.0 mL of 0.10 M HF. What is the pH of this buffer? (The Ka for HF is 6.8 x 10-4)
56. A Problem To Consider A buffer is prepared by adding 45.0 mL of 0.15 M NaF to 35.0 mL of 0.10 M HF. What is the pH of this buffer? (The Ka for HF is 6.8 x 10-4)
57. The Henderson-Hasselbalch Equation How do you prepare a buffer of given pH?
58. Acid-Ionization Titration Curves An acid-base titration curve is a plot of the pH of a solution of acid (or base) against the volume of added base (or acid).
59. Titration of a Strong Acid by a Strong Base Figure 16.11 shows a curve for the titration of HCl with NaOH.
60. Figure 16.11
61. Titration of a Strong Acid by a Strong Base Figure 16.11 shows a curve for the titration of HCl with NaOH.
62. Titration of a Strong Acid by a Strong Base Figure 16.11 shows a curve for the titration of HCl with NaOH.
63. A Problem To Consider Calculate the pH of a solution in which 10.0 mL of 0.100 M NaOH is added to 25.0 mL of 0.100 M HCl.
64. A Problem To Consider Calculate the pH of a solution in which 10.0 mL of 0.100 M NaOH is added to 25.0 mL of 0.100 M HCl.
65. A Problem To Consider Calculate the pH of a solution in which 10.0 mL of 0.100 M NaOH is added to 25.0 mL of 0.100 M HCl.
66. A Problem To Consider Calculate the pH of a solution in which 10.0 mL of 0.100 M NaOH is added to 25.0 mL of 0.100 M HCl.
67. A Problem To Consider Calculate the pH of a solution in which 10.0 mL of 0.100 M NaOH is added to 25.0 mL of 0.100 M HCl.
68. Titration of a Weak Acid by a Strong Base The titration of a weak acid by a strong base gives a somewhat different curve.
69. Titration of a Weak Acid by a Strong Base The titration of a weak acid by a strong base gives a somewhat different curve.
70. Figure 16.12
71. A Problem To Consider Calculate the pH of the solution at the equivalence point when 25.0 mL of 0.10 M acetic acid is titrated with 0.10 M sodium hydroxide. The Ka for acetic acid is 1.7 x 10-5.
72. A Problem To Consider Calculate the pH of the solution at the equivalence point when 25.0 mL of 0.10 M acetic acid is titrated with 0.10 M sodium hydroxide. The Ka for acetic acid is 1.7 x 10-5.
73. A Problem To Consider Calculate the pH of the solution at the equivalence point when 25.0 mL of 0.10 M acetic acid is titrated with 0.10 M sodium hydroxide. The Ka for acetic acid is 1.7 x 10-5.
74. A Problem To Consider Calculate the pH of the solution at the equivalence point when 25.0 mL of 0.10 M acetic acid is titrated with 0.10 M sodium hydroxide. The Ka for acetic acid is 1.7 x 10-5.
75. A Problem To Consider Calculate the pH of the solution at the equivalence point when 25.0 mL of 0.10 M acetic acid is titrated with 0.10 M sodium hydroxide. The Ka for acetic acid is 1.7 x 10-5.
76. Titration of a Weak Base by a Strong Acid The titration of a weak base with a strong acid is a reflection of our previous example.
77. Figure 16.13
78. A Little “Trick” At the “half-way” point in the titration of a weak acid with a weak base, we can make a significant simplification.
79. A Little “Trick” At the “half-way” point in the titration of a weak acid with a weak base, we can make a significant simplification.
80. Operational Skills Calculating the common-ion effect on acid ionization
81. Homework Chapter 16 Homework: collected at the first exam.
Review Questions: none.
Problems: 37, 41, 45, 49.