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LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2

Nicolaou , K. C.; Tria , G. Scott; Edmonds, David J.; Kar , Moumita . Total Syntheses of ()- Platencin and (-)- Platencin . Journal of the American Chemical Society (2009), 131(43), 15909-15917. LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2. PMB = p-methoxybenzyl.

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LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2

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  1. Nicolaou, K. C.; Tria, G. Scott; Edmonds, David J.; Kar, Moumita. Total Syntheses of ()-Platencin and (-)-Platencin. Journal of the American Chemical Society (2009), 131(43), 15909-15917.

  2. LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe3)2

  3. PMB = p-methoxybenzyl

  4. NMO = N-methylmorpholine-N-Oxide TPAP = Tetrapropylammonium perruthenate

  5. Bn = Benzyl = CH2PH TBS = tert-butyldimethylsilyl Tf = Trifluoromethanesulfonyl

  6. SEM-Cl =

  7. TIPS = triisopropylsilyl

  8. TASF = Tris(dimethylamino)sulfonium difluorotrimethylsilicate

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