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Do Now:. Complete the empirical formula worksheet. Ask someone that was in P5 Science yesterday for help if you don’t understand. . Flame Tests And Precipitation Reactions. . Flame Tests: . Describe flame tests to identify metal ions. . http:// www.youtube.com/watch?v=rEWLFH-QpWE Method:
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Do Now: • Complete the empirical formula worksheet. • Ask someone that was in P5 Science yesterday for help if you don’t understand.
Flame Tests: • Describe flame tests to identify metal ions. • http://www.youtube.com/watch?v=rEWLFH-QpWE • Method: • dip a clean flame test loop in the sample solution • hold the flame test loop at the edge of a Bunsen burner flame • observe the changed colour of the flame, and decide which metal it indicates • clean the loop in acid and rinse with water, then repeat steps 1 to 3 with a new sample
Flame Tests • Describe flame tests to identify metal ions.
Precipitation Reactions lead nitrate sodium chloride lead chloride sodium nitrate + + + + Pb(NO3)2(aq) 2NaCl (aq) PbCl2 (s) 2NaNO3 (aq) Sometimes when two solutions are mixed, they react to form an insoluble solid product. The insoluble solid product is called a precipitate. You can spot a precipitate because the mixture goes cloudy. For example, mixing solutions of lead nitrate and sodium chloride produces a yellow precipitate of lead chloride.
If you get a white precipitate: Add more sodium hydroxide solution, aluminium precipitate will dissolve.If the white precipitate does not dissolve then the metal ion is calcium or magnesium. These can be distinguished using a flame test(magnesium ions have no flame colour). What colour would we get for a flame test for Calcium ions?
aluminiumchloride + sodium hydroxide aluminiumhydroxide + sodiumchloridealuminiumchloride + sodium hydroxide aluminiumhydroxide + sodiumchloride AlCl3(aq) + 3NaOH(aq)Al(OH)3(s) + 3NaCl(aq) The ionicequation is Al3+(aq) + 3OH-(aq)Al(OH)3(s) Aluminiumhydroxide is white. calciumchloride + sodiumhydroxide calciumhydroxide + sodiumchloride. CaCl2(aq) + 2NaOH(aq)Ca(OH)2(s) + 2NaCl(aq) The ionicequation is Ca2+(aq) + 2OH-(aq)Ca(OH)2(s) Calciumhydroxide is white.
magnesium chloride + sodium hydroxide magnesium hydroxide + sodium chloridemagnesium chloride + sodium hydroxide magnesium hydroxide + sodium chloride MgCl2(aq) + 2NaOH(aq)Mg(OH)2(s) + 2NaCl(aq) The ionicequation is Mg2+(aq) + 2OH-(aq)Mg(OH)2(s) Magnesiumhydroxide is white. copper(II) chloride + sodium hydroxide copper(II) hydroxide + sodium chloride CuCl2(aq) + 2NaOH(aq)Cu(OH)2(s) + 2NaCl(aq) The ionicequation is Cu2+(aq) + 2OH-(aq)Cu(OH)2(s) Copper(II) hydroxide is blue.
iron(II) chloride + sodiumhydroxideiron(II) hydroxide + sodiumchloride.iron(II) chloride + sodiumhydroxideiron(II) hydroxide + sodiumchloride. FeCl2(aq) + 2NaOH(aq)Fe(OH)2(s) + 2NaCl(aq) The ionicequation is Fe2+(aq) + 2OH-(aq)Fe(OH)2(s) Iron(II) hydroxide is green. iron(III) chloride + sodiumhydroxideiron(III) hydroxide + sodiumchloride FeCl3(aq) + 3NaOH(aq)Fe(OH)3(s) + 3NaCl(aq) The ionicequation is Fe3+(aq) + 3OH-(aq)Fe(OH)3(s) Iron(III) hydroxide is brown.
Applications: Most precipitation reactions are very fast reactions that occur between ions. This makes them very useful for identifying specific ions based on the type of precipitate formed. • Precipitation reactions have a number of other uses: • production of coloured pigments for paints and dyes • removal of toxic chemicals from water • separation of reaction products. A lead iodide precipitate.
Reactions of Carbonates • All metal carbonates react with dilute hydrochloric acid to produce Carbon Dioxide. • Write the reactions of Calcium Carbonate, Sodium Carbonate and Magnesium carbonate with Hydrochloric acid: • Remember to write word then balanced symbol equations – check, the group numbers to help you to balance the equations. • Carbon dioxide precipitates Limewater: • Can you remember the reaction for this (C1 Limestone cycle).