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Ground/Excited States. Electrons in Atoms. Cathode Ray Tubes & Discovery of Electrons. Memory Jogger. Movie of cathode ray tube. Thomson ’ s Plum-Pudding Model. The positive charge is evenly smeared out. The negative charge is in bits – like chips. source. Rutherford ’ s Experiment - 1911.
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Ground/Excited States Electrons in Atoms
Cathode Ray Tubes & Discovery of Electrons Memory Jogger Movie of cathode ray tube
Thomson’s Plum-Pudding Model The positive charge is evenly smeared out. The negative charge is in bits – like chips. source
Problems with the Rutherford Model • Why don’t electrons crash into nucleus? • How are electrons arranged? • Why do different elements exhibit different chemical behavior?
Bohr Model • Bohr - electrons in atom can have only specific amounts of energy NEW idea! • Each specific energy is associated with specific orbit • --electrons are restricted to these orbits • Bohr assigned quantum number (n) to each orbit • the smallest orbit (n= 1) • is closest to nucleus • has lowest energy • larger the orbit, more energy it has
n=3 n=2 n=1 Bohr Diagram • Shows all the electrons in orbits or shells about the nucleus. Lowest energy (most stable) Highest energy (least stable)
Orbit Max # of Electrons 1 2 2 8 3 18 4 32 n 2n2 Max Capacity of Bohr Orbits
energy levels get closer together the farther away they arefrom nucleus Larger orbits can hold more electrons
Bohr Model • Energy absorbed when electron: • moves to higher orbit (farther from nucleus) • Endothermic process • Energy released when electron: • drops to lower orbit (closer to nucleus) • Exothermic process
Electron Transitions • If electron gains (absorbs) specific amount of energy • it can be excited to higher energy level • If electron loses specific amount of energy • it moves down to lower energy level
Ground State vs. Excited State • Ground state: • Lowest energy state of atom • electrons in lowest possible energy levels • Configurations in Reference Tables are ground state • Excited state: • Many possible excited states for each atom • One or more electrons excited to higher energy level
Ground State comes from the reference table Ar = 2-8-8 Total number of electrons = 18 Total number of protons = 18 Atomic Number = 18
Excited State comes from the reference table 2-8-7-1 Total number of electrons = 18 Total number of protons = 18 Atomic Number = 18 Look on the periodic table for the atomic number 18, what is the ground state electron configuration
Which principal energy level of an atom contains electron with the lowest energy? • A) n=1 • B) n=2 • C) n=3 • D) n=4
What is total # of occupied principal energy levels in atom of neon in ground state? • A) 1 • B) 2 • C) 3 • D) 4
Which atom in ground state has five electrons in its outer level and 10 electrons in its kernel? • A) C • B) Cl • C) Si • D) P Kernel electrons = inner electrons
Which electron configuration represents atom in excited state? A) 2-8-2 • B) 2-8-1 • C) 2-8 • D) 2-7-1
Which electron configuration represents atom of Li in an excited state? • A) 1-1 • B) 2-0-1 • C) 2-1 • D) 2-2