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Lecture 8. Grain Moisture: Importance and Measurement (continued). Moisture Transfer. Diffusion-particle to particle contact Leakage Exchange via surface Diffusion via intergranular spaces Convection currents. Pixton and Griffiths (1971).
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Lecture 8 Grain Moisture: Importance and Measurement (continued)
Moisture Transfer • Diffusion-particle to particle contact • Leakage • Exchange via surface • Diffusion via intergranular spaces • Convection currents
Pixton and Griffiths (1971) • 120 g lots of 22.1% mc placed in 500 g lots at 13.7% mc. Temperatures 5 and 22.5oC. • Moisture transfer stopped after 65 d at 22.5oC, but continued for 140 d at 5oC. • Moistures of wet and dry grain were never equal (why??).
Vapor diffusion • Diffusion coefficients: • 2.5 x 10-4 mm2/s at 5oC • 8 x 10 -4 mm2/s at 22.5oC • Normal air: 23.9 mm2/s at 8oC.
Convection Currents • More important in bulk-stored grain. • Movement varies with the type of structure, temperature differentials, moisture differentials, selective heating (from sun) on portions of the facility.
Direct Methods • Accurate • Karl Fischer method: reaction of iodine with water in the presence of sulfur dioxide and pyridine to form hydriodic acid and sulphuric acid. • Air oven: wt difference. Loss of volatile components. • Distillation with toluene. Boiling ground sample > 100C with toluene. • NIR, microwave methods: need calibration, vary from variety to variety, sample size is critical. • Single kernel testers.
Indirect Methods • Electronic meters • Capacitance – more accurate than resistance meters over a range of mc. 150-1250 g sample. Temp. correction. Chart. • Resistance measures electrical resistance. • RH meter: meausres RH of intergranular air. • Hair hygrometer • Wet bulb, dry bulb thermometer • Need to measure RH after 1-2 h of sample collection.
Reading • Chapter 2: Moisture and its measurement. In D. B. Sauer (ed.). In Storage of cereal grains and their products, AACC, St. Paul, MN.