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NO als 1e-Ligand (NO - isoelektronisch zu O 2 )

d) Metallnitrosyl-Komplexe. NO + als 2e-Ligand (isoelektronisch zu CO), z.B. über NO + PF 6 -. NO als 3e-Ligand. NO als 1e-Ligand (NO - isoelektronisch zu O 2 ). Koordinativ flexibler NO-Ligand in photochemischen Substitutionen.

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NO als 1e-Ligand (NO - isoelektronisch zu O 2 )

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  1. d) Metallnitrosyl-Komplexe NO+ als 2e-Ligand (isoelektronisch zu CO), z.B. über NO+PF6- NO als 3e-Ligand NO als 1e-Ligand (NO- isoelektronisch zu O2)

  2. Koordinativ flexibler NO-Ligand in photochemischen Substitutionen Intramolekularer 2-Elektronentransfer unter Schaffung einer freien Koordinationsstelle erleichtert assoziative CO-Substitution Nitrosylverschiebungssatz Cr(CO)6: 3 CO gegen 2 NO gibt Cr(NO)4 Mn(NO)3CO Fe(NO)2(CO)2 Co(NO)(CO)3 Ni(CO)4

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