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ENTHALPY. OBJECTIVES. Exothermic changes cause heat to be released to the surroundings Endothermic changes cause absorption of heat from the surroundings. A potential energy diagram can be used to show the energy pathway for a reaction.
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OBJECTIVES • Exothermic changes cause heat to be released to the surroundings • Endothermic changes cause absorption of heat from the surroundings. • A potential energy diagram can be used to show the energy pathway for a reaction. • The enthalpy change is the energy difference between products and reactants.
Enthalpy Diagrams Exothermic reactions energy course of reaction
Energy Level Diagrams Exothermic reactions energy reactants course of reaction
Energy Level Diagrams Exothermic reactions energy reactants products course of reaction
Energy Level Diagrams Exothermic reactions energy given out ∆H is negative energy reactants products course of reaction
Energy Level Diagrams Endothermic reactions energy course of reaction
Energy Level Diagrams Endothermic reactions energy reactants course of reaction
Energy Level Diagrams Endothermic reactions energy products reactants course of reaction
Energy Level Diagrams Endothermic reactions energy products energy taken in ∆H is positive reactants course of reaction
∆H How much energy is given out or taken in? • Energy is needed to break chemical bonds • Energy is given out when bonds are made ∆H is the differencebetween the energy needed to break the bonds in the reactants, and the energy given out when new bonds are made in the products
C H H H H O O O O
C H H H H O O O O Energy absorbed to break bonds
C H H H H O O O O
C H H H H O O O O Energy released when new bonds are made
Overall energy change = Energy released on making new bonds - Energy taken in to break old bonds
Energy Level Diagrams Exothermic reactions energy methane + oxygen carbon dioxide + water course of reaction
Test tube Reaction mixture
EXOTHERMIC Heat given out to surroundings
ENDOTHERMIC Heat taken in from surroundings
TASK • Draw energy level diagrams for the following reactions: • Photosynthesis • Calcium with sulphuric acid • Dissolving ammonium nitrate