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Chapter 23. The Pesticide Dilemma. Perfect Pesticide. Easily biodegrade into safe elements Narrow Spectrum - kill target species only Remain put in applied location in environment. Prior to the 1940 ’ s. 1st generation Inorganic - lead, mercury, arsenic Persistent and stable
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Chapter 23 The Pesticide Dilemma
Perfect Pesticide Easily biodegrade into safe elements Narrow Spectrum - kill target species only Remain put in applied location in environment
Prior to the 1940’s 1st generation Inorganic - lead, mercury, arsenic Persistent and stable Toxic to animals 2. Organic (botanicals) - nicotine, pyrethrin, rotenone Easily biodegrade Do not persist Toxic to bees and fish 3. Synthetic Botanicals = second generation
Second-Generation Pesticides • Synthetic botanicals (DDT) - persistent & stable
Malaria Snapshot 247 million cases of malaria in 2006, causing about 880,000 deaths, mostly among African children. Approximately half of the world's population is at risk of malaria – most low income countries Economic toll Insecticide-treated nets Increasing mosquito resistance to insecticides
The Major Pesticide Groups • Chlorinated hydrocarbon (DDT) • Broad-Spectrum persistent – nonpolar • Organophosphates • Broad-spectrum: very toxic to mammals, birds, fish • Nerve agent • Degrades rapidly • More toxic than Chlorinated Hydrocarbons • Carbamates • Broad-spectrum similar function to organophosphates but reversible and less toxic to mammals - degrades rapidly
Bioaccumulation • Synthetic substances typically not metabolized - accumulate in fat Fat soluble (lipophilic) substances cannot be excreted in urine, a water-based medium, and so accumulate in fatty tissues.
Pull on a star and you find the universe attached • Problems: • Mobility • Persistence • Bioaccumulation • Biological Magnification
Biomagnification • Example: Effect of DDT on bald eagles
Major Herbicides • Selective herbicides - (2,4,5-T & 2,4-D – kills broad-leaved plants) • Nonselective herbicides • (glyphosate, aka: Round-UpTM)
Alternatives - GMO’s • Bacillus thuringiensis (Bt) • Corn & Cotton (roundup ready) • non-target species monarch butterfly • Soil accumulation of Bt • 1. Growers plant 80% corn acres with Bt corn - 20% planted with non-Bt corn (refuge area). • 2. Refuge area must be within 1/2 mile of Bt field.
Benefits - Initial Returns • Crop production • Savings of 3-5$ in crops for every $1 invested in pesticides
Big Business Kills most pests Resistant survive INCREASE Numbers increase EVEN MORE New population genetically resistant • Problem: Evolution of Genetic Resistance • Creates a pesticide treadmill Pesticide application
Benefits - Longterm? # of species exhibiting genetic resistance to pesticides 30 fold increase in insecticide use since 1940 • Problem: Evolution of Genetic Resistance
Problem: Imbalances in the Ecosystem • Creation of New Pests Lemons
Alternatives to Pesticides • Integrated Pest Management Management of pest not eradication Education of farmers
1. Using Cultivation Methods • Interplant mixtures of plants • Planting, fertilizing, and irrigating at proper time • Crop rotation • Refuge Planting • Strip or border cutting (see next slide)
Strip Cutting / Border Cutting • Lygus bugs love alfalfa like cotton and hay as well • Strips 250-300’ wide • Alfalfa harvested in two week intervals • Drawback - Complicated irrigation and harvesting due to mix
2. Resistant Crop Varieties • Plants have many natural mechanisms to keep insects at bay: repellent or toxic chemicals, thorns, hairs, and tough roots and stems. • 2. May reduce need for various “cides” • 3. Yields may drop since the plant puts its resources towards its defense. • 4. Evolutionary arms race continues and insects may counter plants defense.
3. Natural Enemies (Biological Controls) • Predators • Disease • Parasites Wasp Invaders 4 Min. http://www.youtube.com/watch?v=vMG-LWyNcAs
5. Other:Alternatives to Pesticides • Avoid repeated use of same pesticide • Reproductive Controls - Sterile-male technique • Quarantine - if foreign pest detected • Create a “refuge” (no pesticide applied) • Mechanically pull resistant weeds or vacuum bugs: non-chemical methods
Alternatives to Pesticides IPM introduced • Integrated Pest Management Rice Production in Indonesia
Laws Controlling Pesticide Use • Food, Drug, and Cosmetics Act (1938) - recognized need to regulate pesticides in food • Federal Insecticide, Fungicide, and Rodenticide Act (1947) - regulated effectiveness of pesticides • Pesticide Chemicals Amendment (1954) - set standards & testing for pesticides in food • Delaney Clause (1958) - no cancer causing agent may be used • Food Quality Protection Act (1996) - amended Delaney and reduced time to ban pesticide from 10 years to 14 months
Stockholm Convention • The Global Ban of Persistent Organic Pollutants