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5. You can do it. Chapter 1 Matter and Measurement. States of Matter. Solid. Liquid. Gas. Plasma. Matter. Pure substances (homogeneous composition). Mixtures of two or more substances. Elements. Compounds. Solutions (homogeneous composition – one phase).
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Matter Pure substances (homogeneous composition) Mixtures of two or more substances Elements Compounds Solutions (homogeneous composition – one phase) Heterogeneous mixtures (two or more phases) Figure 3.2 (page 48)
Mixtures • Homogeneous • Heterogeneous
Pure substance • A particular kind of matter with a definite, fixed composition • Elements • Compounds
Compounds • Two or more elements • New • Definite • Can be
Gatorade Caesar salad Water Coffee An iron nail Air Milk How would you classify?
Methods of Separation Do not cause chemical changes
Filtration • Used for • Gravity • Vacuum
Evaporation • Solutions…
Distillation • Relies on
Chromatography • Relies on
The Metric SystemThe International System of Units • Standards of measurement • Base units (7) – see Table 1.4 pg 14 • MASS: • LENGTH: • TIME: • COUNT, QUANTITY: • TEMPERATURE: • ELECTRIC CURRENT: • LUMINOUS INSTENSITY:
The Metric System • Derived Units: • AREA: • VOLUME: • ENERGY: • FORCE: • PRESSURE: • POWER: • VOLTAGE: • FREQUENCY: • ELECTRIC CHARGE:
Common ratio used in chemistry Physical property of a substance D = SI units: kg/m3 Solid g/cm3 Liquid g/mL Gas g/L Density Can change due to temperature and/or pressure changes
Density • Find the density of a piece of metal with a volume of 2.7 cm3 and a mass of 10.8 g. 2. Determine the mass of an object with a density of 0.24 g/cm3 and a volume of 2 cm3.
The Metric System • Metric Prefixes – make base unit larger or smaller • Table 1.5 – pg 14 • Based on 10 • Math method vs. “Stairs”
Conversion Practice • Convert a volume of 12 microliters into centiliters • Express a distance of 15 meters in kilometers • Convert 83 cm into meters • Which is the longer amount of time, 1351 ps or 1.2 ns? • Convert 16 dL into L
Uncertainty in Measurement • Why are digits in measurements uncertain? • Instruments never completely free of flaws • Always involves estimation • Choose the right instrument for the job • May be estimated for you (electronic scales) • Scale is marked but you estimate the in-between
Uncertainty in Measurement • Precision: getting the same result again and again under same conditions • Accuracy: close to accepted value
Significant Digits • All digits known with certainty plus one final digit which is uncertain (or estimated) • All non-zeros • A zero is significant when : • It is • It is • A zero is not significant when: • It is • It is
Significant Digits - PRACTICE How many significant digits? • 54.23 • 23.00005 • 0.0004 • 35000 • 0.000504 • 45.623200 • 5,000,000 • 4,000,000.1
Significant Digits - Calculations • Addition and Subtraction • Round answer to have final digit in the SAME PLACE as the last digit in the LEAST ACCURATE MEASUREMENT • 1.21 + 5.002 + 10. = • 34.5 + 12.45 + 23.0505 = • 186.31 + 11.1 = • 12.0231 + 3.86 = • 0.100012 + 120. = • 1200 + 12 + 15 + 0.5 =
Significant Digits - Calculations • Multiplication and Division • The answer has as many sig figs as the number with the fewest sig figs • 14.8 x 3.1 = • 18.2 x 3.0 = • 52/1.5 = • 321.868783 x 1 = • 2400 x 2.123 = • 15000/12.354 =
Scientific Notation • Convenient way of writing very large or very small numbers and showing only significant figures • Number between 1 & 10 with a power of ten • 5120 becomes 5.12 x 103 • Move decimal point in original number to make number 1-10 • Move left = +; move right = -
Scientific Notation Practice • 123,000 = • 0.000045 = • 23.45 = • 0.0000000003 = • 1,000,000 =
Scientific Notation • Math with: • Use the EE or EXP button on your calculator. • For example: • (1.25 x 105) (5.25 x 102) • Keystrokes are: • Or:
Types of Measurements • Mass – • Expressed in • Does • Weight – • Expressed in same units
Types of Measurements • Volume – • Cubic • Many instruments to measure • Temperature – • Kelvin • Degrees Celsius • Degress Farenheit
Conversion Factors • Enable movement between metric system and “English” system • See back cover of book and Appendix III • Common conversions you should memorize • 1 inch = 2.54 cm • 1 mile = 1.609 km • 1 kg = 2.20 pounds • 1 mL = 1 cm3 • 0 K = -273.15 0C • 0F = 1.8(0C) + 32
Dimensional Analysis(Problem Solving) • Remember: ALWAYS use UNITS OF MEASUREMENT in your work!!! • A technique of converting between units • Same system (metrics) • Different systems (inches to meters) • Chemical equations….later chapters…
Dimensional Analysis(Problem Solving) • Conversion Factors: ratio derived from the equality between 2 different units 3 feet = 1 1 dollar = 1 1 yard 4 quarters • CF can be written either way 1 minute = 1 60 seconds = 1 60 seconds 1 minute
The “t” method Dimensional Analysis(Problem Solving) unit given unit wanted = unit wanted unit given Conversion Factor Example: How many liters are in 125.6 gallons?
Dimensional Analysis(Problem Solving) Dimensional Analysis(Problem Solving) How many seconds are in 4.15 hours? If a student needs 1.5 mL of water, how many cups does he need?