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Do Now : If one stick of Juicy Fruit gum weighs 3.0g, what percent of the total mass of the gum is sugar?. Hydrate Lab – for tomorrow. Pre-lab Title Purpose Materials Procedure Data table. Hydrate Anhydrous. Hydrates.
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Do Now: If one stick of Juicy Fruit gum weighs 3.0g, what percent of the total mass of the gum is sugar?
Hydrate Lab – for tomorrow • Pre-lab • Title • Purpose • Materials • Procedure • Data table Hydrate Anhydrous
Hydrates • Water molecules are incorporated into the crystalline structure. Methane hydrate • Hydrates, like zinc acetate dihydrate, Zn(C2H3O2)2 * 2H2O • are commonly found in skin care products such as moisturizer, shampoo and lip balm.
What is the % H2O in nickel chloride dihydrate, NiCl2* 2H2O? %H2O = = 21.76% H2O
part whole 24.31 g 95.21 g % = x100 % Mg = x100 24.305 35.453 Mg Cl 12 17 magnesium chlorine Percentage Composition (by mass...not atoms) 25.52% Mg Mg2+ Cl1- 74.48% Cl MgCl2 It is not 33% Mg and 66%Cl 1 Mg @ 24.31 g= 24.31 g 2 Cl @ 35.45 g= 70.90 g 95.21 g
g element x 100 % of element = molar mass of compound : : : : : : percentage composition: the mass % of each element in a compound (see calcs above) Find % composition. PbO2 207.2 g Pb = 86.6% Pb 239.2 g 32.0 g O = 13.4% O 239.2 g (NH4)3PO4 42.0 g N = 28.2% N 149.0 g 12.0 g H = 8.1% H 149.0 g 31.2 g P = 20.8% P 149.0 g 64.0 g O = 43.0% O 149.0 g
Empirical and Molecular Formulas A pure compound always consists of the same elements combined in the same proportions by weight. Therefore, we can express molecular composition as PERCENT BY WEIGHT. Ethanol, C2H6O 52.13% C 13.15% H 34.72% O
Different Types of Formulas C6H6 • Molecular Formula – shows the real # of atoms in one molecule or formula unit • Empirical Formula – shows smallest whole number mole ratio **Sometimes the empirical &molecular formula can be the same • Structural Formula- molecular formula info PLUS bonding electron and atomic arrangement CH
Calculating Empirical formula • Percent to mass (assume 100g) • Mass to mole (molar mass) • Divide by the smallest (ratio) • Multiply til’ whole*
/ 0.708 mol 32.38 g Na 22.65 g S 44.99 g O / 0.708 mol / 0.708 mol Empirical Formula Quantitative analysis shows that a compound contains 32.38% sodium, 22.65% sulfur, and 44.99% oxygen. Find the empirical formula of this compound. sodium sulfate = 2 Na 32.38% Na 22.65% S 44.99% O = 1.408 mol Na Na2SO4 Na2SO4 = 0.708 mol S = 1 S = 2.812 mol O = 4 O Step 1) % g Step 2) g mol Step 3) mol mol
/ 0.3500 mol 66.75g Cu 10.84g P 22.41g O / 0.3500 mol / 0.3500 mol Empirical Formula Quantitative analysis shows that a compound contains 66.75% copper, 10.84% phosphorus and 22.41% oxygen. Find the empirical formula of this compound. copper (I) phosphate =3 Cu 66.75% Cu 10.84 % P 22.41 % O = 1.050 mol Cu Cu3PO4 Cu3PO4 = 0.3500 mol P = 1 P = 1.401 mol O = 4 O Step 1) % g Step 2) g mol Step 3) mol mol