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Nuclear Fuel, Uranium Enrichment, Fuel Fabrication, MOX. Seminar on Nuclear Science and Technology for Diplomats P. Adelfang (+)Division of Nuclear Fuel Cycle and Waste Technology (NEFW) Department of Nuclear Energy (NE) IAEA, Vienna, February 6-8, 2007. Ends of the Nuclear Fuel Cycle.
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Nuclear Fuel, Uranium Enrichment, Fuel Fabrication, MOX Seminar on Nuclear Science and Technology for Diplomats P. Adelfang (+)Division of Nuclear Fuel Cycle and Waste Technology (NEFW) Department of Nuclear Energy (NE) IAEA, Vienna, February 6-8, 2007
Yellow Cake Final Product of Milling Step – 70 to 80 % uranium
Natural Uranium 235U only fissile nuclide – only 1 atom of 235Uin 140 atoms of 238U
Enrichment • A number of enrichment processes have been demonstrated in the laboratory • Only two, the gaseous diffusion process and the centrifuge process, are operating on a commercial scale • In both of these, UF6 gas is used as the feed material • Molecules of UF6 with U-235 atoms are about one percent lighter than the rest, and this difference in mass is the basis of both processes • Large commercial enrichment plants are in operation in France, Germany, Netherlands, UK, USA, and Russia, with smaller plants elsewhere
Enrichment: Centrifuge Process • vacuum tubes, each containing a rotor one to two metres long and 15-20 cm diameter. • rotors are spun rapidly, at 50,000 to 70,000 rpm • heavier molecules with U-238 increase in concentration towards the cylinder's outer wall • there is a corresponding increase in concentration of U-235 molecules near the centre. • enriched gas forms part of the feed for the next stages, depleted UF6 gas goes back to the previous stage (cascade) • very high speeds:, outer wall spinning cylinder 400 and 500 metres per second= 1 million times the acceleration of gravity
Enrichment: Gaseous Diffusion Process • involves forcing UF6 under pressure through a porous membranes • as 235U molecules are lighter than the 238U molecules they move faster and have a slightly better chance of passing through the pores in the membrane • the UF6 which diffuses through the membrane is thus slightly enriched, while the gas which did not pass through is depleted in 235U • this process is repeated many times in a series of diffusion stages called a cascade • enriched UF6 is withdrawn from one end of the cascade and depleted UF6 is removed at the other end • the gas must be processed through some 1400 stages to obtain a product with a concentration of 3% to 4% 235U
Enrichment: Gaseous Diffusion Process The large Tricastin enrichment plant in France (beyond cooling towers). The nuclear reactors in the foreground provide power for it.
Conversion and Nuclear Fuel Fabrication • UF6, in solid form in containers, is heated to gaseous form, and the UF6 gas is chemically processed to form LEU uranium dioxide (UO2) powder • this powder is then pressed into pellets, sintered into ceramic form (fuel pellets) • pellets are then loaded into Zircaloy tubes that are afterwards hermetically closed (fuel rods) • rods are constructed into fuel assemblies • fuel assemblies are made with different dimensions and number of fuel rods, depending on the type reactor
MOX Fuel • Plutonium, made in power reactors and from dismantled nuclear weapons, is a valuable energy source when integrated in the nuclear fuel cycle • Over one third of the energy produced in most nuclear power plants comes from plutonium. It is created there as a by-product. • 'MOX' is derived from 'mixed oxides', and refers to reactor fuel made from a mixture of plutonium and uranium oxide • For use in a light water reactor, the proportion of plutonium is about 5%. This is a similar fissile content as low enriched uranium fuel • MOX is formed into ceramic fuel pellets, extremely stable and durable, and which are sealed in metal (usually zirconium) tubes, which in turn are assembled into fuel elements • In most cases a part of the reactor core can be loaded with MOX fuel elements without engineering or operational modifications to the reactor • Plutonium is radiologically hazardous, particularly if inhaled, so must be handled with appropriate precautions
IAEA Thank you for your attention …atoms for peace.